메뉴 건너뛰기




Volumn 32, Issue 6, 1999, Pages 2071-2074

More versatile route to block copolymers and other polymers of complex architecture by living radical polymerization: the RAFT process

Author keywords

[No Author keywords available]

Indexed keywords

ACRYLICS; FREE RADICAL POLYMERIZATION; MOLECULAR STRUCTURE; MOLECULAR WEIGHT; MONOMERS; POLYSTYRENES;

EID: 13044256394     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma981472p     Document Type: Article
Times cited : (934)

References (33)
  • 1
    • 13044285876 scopus 로고    scopus 로고
    • note
    • The use of the adjective "living" to describe a radical polymerization which displays the attributes of a living polymerization is preferred over other terms that have been advocated in this context (e.g., "controlled", "living/controlled", "pseudo living", or "living polymerization with reversible deactivation"), even though some side reactions (radical-radical termination) must inevitably complicate the process.
  • 2
    • 0031382036 scopus 로고    scopus 로고
    • Colombani, D. Prog. Polym. Sci. 1997, 22, 1649. Matyjaszewski, K. ACS Symp. Ser. 1998, 685, 2.
    • (1997) Prog. Polym. Sci. , vol.22 , pp. 1649
    • Colombani, D.1
  • 3
    • 0346350504 scopus 로고    scopus 로고
    • Colombani, D. Prog. Polym. Sci. 1997, 22, 1649. Matyjaszewski, K. ACS Symp. Ser. 1998, 685, 2.
    • (1998) ACS Symp. Ser. , vol.685 , pp. 2
    • Matyjaszewski, K.1
  • 4
    • 0030574965 scopus 로고    scopus 로고
    • Fukuda, T.; Terauchi, T.; Goto, A.; Tsujii, Y.; Miyamoto, T. Macromolecules 1996, 29, 3050. Li, I. Q.; Howell, B.; Koster, R. A.; Priddy, D. B. Polym. Bull. (Berlin) 1996, 37, 451. Bertin, D.; Boutevin, B. Polym. Bull. (Berlin) 1996, 37, 337. Schmidt-Naake, G.; Butz, S. Macromol. Rapid Commun. 1996, 17, 661. Kazmaier, P. M.; Daimon, K.; Georges, M. K.; Hamer, G. K.; Veregin, R. P. N. Macromolecules 1997, 30, 2228. Butz, S.; Baethge, H.; Schmidt-Naake, G. Macromol. Rapid Commun. 1997, 18, 1049.
    • (1996) Macromolecules , vol.29 , pp. 3050
    • Fukuda, T.1    Terauchi, T.2    Goto, A.3    Tsujii, Y.4    Miyamoto, T.5
  • 5
    • 0002596798 scopus 로고    scopus 로고
    • Fukuda, T.; Terauchi, T.; Goto, A.; Tsujii, Y.; Miyamoto, T. Macromolecules 1996, 29, 3050. Li, I. Q.; Howell, B.; Koster, R. A.; Priddy, D. B. Polym. Bull. (Berlin) 1996, 37, 451. Bertin, D.; Boutevin, B. Polym. Bull. (Berlin) 1996, 37, 337. Schmidt-Naake, G.; Butz, S. Macromol. Rapid Commun. 1996, 17, 661. Kazmaier, P. M.; Daimon, K.; Georges, M. K.; Hamer, G. K.; Veregin, R. P. N. Macromolecules 1997, 30, 2228. Butz, S.; Baethge, H.; Schmidt-Naake, G. Macromol. Rapid Commun. 1997, 18, 1049.
    • (1996) Polym. Bull. (Berlin) , vol.37 , pp. 451
    • Li, I.Q.1    Howell, B.2    Koster, R.A.3    Priddy, D.B.4
  • 6
    • 2742579254 scopus 로고    scopus 로고
    • Fukuda, T.; Terauchi, T.; Goto, A.; Tsujii, Y.; Miyamoto, T. Macromolecules 1996, 29, 3050. Li, I. Q.; Howell, B.; Koster, R. A.; Priddy, D. B. Polym. Bull. (Berlin) 1996, 37, 451. Bertin, D.; Boutevin, B. Polym. Bull. (Berlin) 1996, 37, 337. Schmidt-Naake, G.; Butz, S. Macromol. Rapid Commun. 1996, 17, 661. Kazmaier, P. M.; Daimon, K.; Georges, M. K.; Hamer, G. K.; Veregin, R. P. N. Macromolecules 1997, 30, 2228. Butz, S.; Baethge, H.; Schmidt-Naake, G. Macromol. Rapid Commun. 1997, 18, 1049.
    • (1996) Polym. Bull. (Berlin) , vol.37 , pp. 337
    • Bertin, D.1    Boutevin, B.2
  • 7
    • 0030517519 scopus 로고    scopus 로고
    • Fukuda, T.; Terauchi, T.; Goto, A.; Tsujii, Y.; Miyamoto, T. Macromolecules 1996, 29, 3050. Li, I. Q.; Howell, B.; Koster, R. A.; Priddy, D. B. Polym. Bull. (Berlin) 1996, 37, 451. Bertin, D.; Boutevin, B. Polym. Bull. (Berlin) 1996, 37, 337. Schmidt-Naake, G.; Butz, S. Macromol. Rapid Commun. 1996, 17, 661. Kazmaier, P. M.; Daimon, K.; Georges, M. K.; Hamer, G. K.; Veregin, R. P. N. Macromolecules 1997, 30, 2228. Butz, S.; Baethge, H.; Schmidt-Naake, G. Macromol. Rapid Commun. 1997, 18, 1049.
    • (1996) Macromol. Rapid Commun. , vol.17 , pp. 661
    • Schmidt-Naake, G.1    Butz, S.2
  • 8
    • 0031121169 scopus 로고    scopus 로고
    • Fukuda, T.; Terauchi, T.; Goto, A.; Tsujii, Y.; Miyamoto, T. Macromolecules 1996, 29, 3050. Li, I. Q.; Howell, B.; Koster, R. A.; Priddy, D. B. Polym. Bull. (Berlin) 1996, 37, 451. Bertin, D.; Boutevin, B. Polym. Bull. (Berlin) 1996, 37, 337. Schmidt-Naake, G.; Butz, S. Macromol. Rapid Commun. 1996, 17, 661. Kazmaier, P. M.; Daimon, K.; Georges, M. K.; Hamer, G. K.; Veregin, R. P. N. Macromolecules 1997, 30, 2228. Butz, S.; Baethge, H.; Schmidt-Naake, G. Macromol. Rapid Commun. 1997, 18, 1049.
    • (1997) Macromolecules , vol.30 , pp. 2228
    • Kazmaier, P.M.1    Daimon, K.2    Georges, M.K.3    Hamer, G.K.4    Veregin, R.P.N.5
  • 9
    • 0031327541 scopus 로고    scopus 로고
    • Fukuda, T.; Terauchi, T.; Goto, A.; Tsujii, Y.; Miyamoto, T. Macromolecules 1996, 29, 3050. Li, I. Q.; Howell, B.; Koster, R. A.; Priddy, D. B. Polym. Bull. (Berlin) 1996, 37, 451. Bertin, D.; Boutevin, B. Polym. Bull. (Berlin) 1996, 37, 337. Schmidt-Naake, G.; Butz, S. Macromol. Rapid Commun. 1996, 17, 661. Kazmaier, P. M.; Daimon, K.; Georges, M. K.; Hamer, G. K.; Veregin, R. P. N. Macromolecules 1997, 30, 2228. Butz, S.; Baethge, H.; Schmidt-Naake, G. Macromol. Rapid Commun. 1997, 18, 1049.
    • (1997) Macromol. Rapid Commun. , vol.18 , pp. 1049
    • Butz, S.1    Baethge, H.2    Schmidt-Naake, G.3
  • 10
    • 0028766626 scopus 로고
    • Yoshida, E.; Ishizone, T.; Hirao, A.; Nakahama, S.; Takata, T.; Endo, T. Macromolecules 1994, 27, 3119. Listigovers, N. A.; Georges, M. K.; Odell, P. G.; Keoshkerian, B. Macromolecules 1996, 29, 8992. Li, I. Q.; Howell, B. A.; Dineen, M. T.; Lyons, J. W.; Meunier, D. M.; Smith, P. B.; Priddy, D. B. Macromolecules 1997, 30, 5195.
    • (1994) Macromolecules , vol.27 , pp. 3119
    • Yoshida, E.1    Ishizone, T.2    Hirao, A.3    Nakahama, S.4    Takata, T.5    Endo, T.6
  • 11
    • 0030392794 scopus 로고    scopus 로고
    • Yoshida, E.; Ishizone, T.; Hirao, A.; Nakahama, S.; Takata, T.; Endo, T. Macromolecules 1994, 27, 3119. Listigovers, N. A.; Georges, M. K.; Odell, P. G.; Keoshkerian, B. Macromolecules 1996, 29, 8992. Li, I. Q.; Howell, B. A.; Dineen, M. T.; Lyons, J. W.; Meunier, D. M.; Smith, P. B.; Priddy, D. B. Macromolecules 1997, 30, 5195.
    • (1996) Macromolecules , vol.29 , pp. 8992
    • Listigovers, N.A.1    Georges, M.K.2    Odell, P.G.3    Keoshkerian, B.4
  • 12
    • 0031559847 scopus 로고    scopus 로고
    • Yoshida, E.; Ishizone, T.; Hirao, A.; Nakahama, S.; Takata, T.; Endo, T. Macromolecules 1994, 27, 3119. Listigovers, N. A.; Georges, M. K.; Odell, P. G.; Keoshkerian, B. Macromolecules 1996, 29, 8992. Li, I. Q.; Howell, B. A.; Dineen, M. T.; Lyons, J. W.; Meunier, D. M.; Smith, P. B.; Priddy, D. B. Macromolecules 1997, 30, 5195.
    • (1997) Macromolecules , vol.30 , pp. 5195
    • Li, I.Q.1    Howell, B.A.2    Dineen, M.T.3    Lyons, J.W.4    Meunier, D.M.5    Smith, P.B.6    Priddy, D.B.7
  • 14
    • 0029638116 scopus 로고
    • Wang, J.-S.; Matyjaszewski, K. Macromolecules 1995, 28, 7901. Percec, V.; Kim, H. J.; Barboiu, B. Macromolecules 1997, 30, 6702. Sawamoto, M.; Kamigaito, M. Trends Polym. Sci. 1996, 4, 371. Matyjaszewski, K. ACS Symp. Ser. 1998, 685, 258.
    • (1995) Macromolecules , vol.28 , pp. 7901
    • Wang, J.-S.1    Matyjaszewski, K.2
  • 15
    • 0031245940 scopus 로고    scopus 로고
    • Wang, J.-S.; Matyjaszewski, K. Macromolecules 1995, 28, 7901. Percec, V.; Kim, H. J.; Barboiu, B. Macromolecules 1997, 30, 6702. Sawamoto, M.; Kamigaito, M. Trends Polym. Sci. 1996, 4, 371. Matyjaszewski, K. ACS Symp. Ser. 1998, 685, 258.
    • (1997) Macromolecules , vol.30 , pp. 6702
    • Percec, V.1    Kim, H.J.2    Barboiu, B.3
  • 16
    • 0001367322 scopus 로고    scopus 로고
    • Wang, J.-S.; Matyjaszewski, K. Macromolecules 1995, 28, 7901. Percec, V.; Kim, H. J.; Barboiu, B. Macromolecules 1997, 30, 6702. Sawamoto, M.; Kamigaito, M. Trends Polym. Sci. 1996, 4, 371. Matyjaszewski, K. ACS Symp. Ser. 1998, 685, 258.
    • (1996) Trends Polym. Sci. , vol.4 , pp. 371
    • Sawamoto, M.1    Kamigaito, M.2
  • 17
    • 0348241177 scopus 로고    scopus 로고
    • Wang, J.-S.; Matyjaszewski, K. Macromolecules 1995, 28, 7901. Percec, V.; Kim, H. J.; Barboiu, B. Macromolecules 1997, 30, 6702. Sawamoto, M.; Kamigaito, M. Trends Polym. Sci. 1996, 4, 371. Matyjaszewski, K. ACS Symp. Ser. 1998, 685, 258.
    • (1998) ACS Symp. Ser. , vol.685 , pp. 258
    • Matyjaszewski, K.1
  • 22
    • 13044311925 scopus 로고    scopus 로고
    • note
    • Synthesis of poly(methyl methacrylate-block-butyl methacrylate-block-methyl methacrylate). B block: A solution of AIBN (2.5 mg), n-butyl methacrylate (3.8 mL), 1,4-bis-(dithiobenzoylprop-2-yl)benzene (7) (93.5 mg) in benzene (1.2 mL) was placed in an ampule, and the contents were degassed, sealed, and heated at 60 °C for 16 h to give poly-(n-butyl methacrylate) (conversion, 49%). A block: A solution of the above poly(n-butyl methacrylate) (300 mg; precipitated from methanol to remove residual initiator), AIBN (0.51 mg), and methyl methacrylate (0.75 mL) in benzene (0.25 mL) was degassed, sealed, and heated at 60 °C for 16 h to provide the triblock copolymer (conversion of methyl methacrylate, >95%). GPC data for these polymers are shown in Table 2 and Figure Ic.
  • 23
    • 13044285875 scopus 로고    scopus 로고
    • note
    • Synthesis of poly(benzyl methacrylate-block 2-(dimethylamino)ethyl methacrylate). A block: A solution of cumyl dithiobenzoate (1c) (2 g), azobis(isobutyronitrile) (101 mg) in benzyl methacrylate (15 mL), and benzene (5 mL) was degassed through three freeze-thaw-evacuate cycles, sealed under vacuum, and heated in a constant-temperature bath at 60 °C for 88 h. B block: A solution of dithiobenzoate-terminated poly(benzyl methacrylate) (0.4 g), azobisüsobu-tyronitrile) (4 mg), and 2-WV-dimethylamino)ethyl meth-acrylate (0.4 g) in ethyl acetate (2 mL) was degassed through three freeze-thaw-evacuate cycles, sealed under vacuum, and heated in a constant-temperature bath at 60 5C for 24 h. Removal of the solvent provided the diblock copolymer. Details of molecular weight are provide in Table 1 and Figure 1a.
  • 25
    • 13044250316 scopus 로고    scopus 로고
    • note
    • An amount of dead polymer impurity equating to the number of initiating radicals generated during the course of polymerization should be formed. In a diblock synthesis, this impurity may take the form of homopolymer, dibock copolymer, or triblock copolymer depending on the species involved and whether radical-radical termination occurs by combination or disproportionation.
  • 28
    • 0000272301 scopus 로고
    • Brandup, J., Immergut, E. H., Eds.; Wiley: New York
    • Greenley, R. Z. In Polymer Handbook, 3rd ed.; Brandup, J., Immergut, E. H., Eds.; Wiley: New York, 1989; p II/153.
    • (1989) Polymer Handbook, 3rd Ed.
    • Greenley, R.Z.1
  • 29
    • 13044313321 scopus 로고    scopus 로고
    • note
    • n = 1.21, and the cumulative [MMA]/[BA] = 1:0.8.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.