The reaction of Ru(CO)2(MeCO2)2(PR3)2 or Ru2(CO)4(MeCO2)2(PR 3)2 [R = Bu, Ph] with H2 in the presence of Na2CO3: A stoichiometric carbon dioxide activation

Inorganica Chimica Acta

Volumn 272, Issue 1-2, 1998, Pages 141-149

  Frediani, Piero ^a   Faggi, Cristina ^a   Salvini, Antonella ^a   Bianchi, Mario ^a   Piacenti, Franco ^a  

^a UNIVERSITY OF FLORENCE   (Italy)

Author keywords

Carbon dioxide activation; Carbonyl complexes; Carboxylate complexes; Ruthenium complexes

Indexed keywords

CARBON DIOXIDE; CARBOXYLATION; CATALYSIS; CHEMICAL ACTIVATION; CHEMICAL SHIFT; PHOSPHORUS COMPOUNDS; SODIUM CARBONATE; SODIUM COMPOUNDS; TEMPERATURE; WATER GAS SHIFT;

BINUCLEAR COMPLEXES; CARBON DIOXIDE ACTIVATION; CARBONYL COMPLEXES; CARBOXYLATE COMPLEXES; MONONUCLEAR COMPLEXES; REACTION TEMPERATURE; REVERSE WATER-GAS SHIFT REACTION; RUTHENIUM COMPLEXES;

RUTHENIUM COMPOUNDS;

EID: 0001213878     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0020-1693(97)05973-2     Document Type: Article

References (21)

1. A. Salvini, P. Frediani, D. Rovai, M. Bianchi and F. Piacenti, J. Mol. Catal., 89 (1994) 77.
2. (a) M. Bianchi, G. Menchi, F. Francalanci, F. Piacenti, U. Matteoli, P. Frediani and C. Botteghi, J. Organometal. Chem., 188 (1980) 109;
3. (b) U. Matteoli, G. Menchi, M. Bianchi, P. Frediani and F. Piacenti, Gazz. Chim. Ital. 115 (1985) 603.
4. P. Frediani, M. Bianchi, A. Salvini, F. Piacenti, S. Ianelli and M. Nardelli, J. Chem. Soc., Dalton Trans., (1990) 165.
5. (a) P. Frediani, C. Faggi, S. Papaleo, A. Salvini, M. Bianchi, F. Piacenti, S. Ianelli and M. Nardelli, J. Organometal. Chem., 536-537 (1997) 123;
6. (b) A. Beguin, G. Rheinwald, H. Stoeckly-Evans and G. Süss-Fink, Helv. Chim. Acta, 77 (1994) 525.
7. P. Frediani, M. Bianchi, A. Salvini, F. Piacenti, S. Ianelli and M. Nardelli, J. Chem. Soc., Dalton Trans., (1990) 1705.
8. M. Bianchi, P. Frediani, U. Matteoli, G. Menchi, F. Piacenti and G. Petrucci, J. Organometal. Chem., 259 (1983) 207.
9. (a) F. Porta, S. Cenini and M. Pizzotti, J. Organometal. Chem., 150 (1978) 261;
10. (b) C. Ungermann, V. Landis, S.A. Moya, H. Cohen, H. Walker, R.G. Pearson, R.G. Rinker and P.C. Ford, J. Am. Chem. Soc., 101 (1979) 5922;
11. (c) A.D. King, R.B. King and D.B. Yang, J. Chem. Soc., Chem. Commun., (1980) 529;
12. (d) D.J. Cole-Hamilton, J. Chem. Soc., Chem. Commun., (1980) 1213;
13. (e) M.A. Bennet and T.W. Matheson, in G. Wilkinson, F.G.A. Stone and E.W. Abel (eds.). Comprehensive Organometallic Chemistry, Vol. 4, Pergamon, Oxford, 1982, p. 941.
14. (a) H. Koinuma, Y. Yoshida and H. Hirai, Chem. Lett. Jpn., (1975) 1223;
15. (b) R.P.A. Sneeden, in G. Wilkinson, F.G.A. Stone and E.W. Abel (eds.), Comprehensive Organometallic Chemistry, Vol. 8, Pergamon, Oxford, 1982, p. 262.
16. G.R. Crooks, B.F.G. Johnson, J. Lewis, I.G. Williams and G. Gamlen, J. Chem. Soc. A, (1969) 2761.
17. M. Bianchi, P. Frediani, U. Matteoli, G. Menchi, F. Piacenti and G. Petrucci, J. Organometal. Chem., 259 (1983) 207.
18. (a) B.F.G. Johnson, R.D. Johnson, J. Lewis and I.G. Williams, J. Chem. Soc. A. (1971) 689;
19. (b) S.D. Robinson and M.F. Uttley, J. Chem. Soc., Dalton Trans., (1973) 1912;
20. (c) A. Dobson, S.D. Robinson and M.F. Uttley, J. Chem. Soc., Dalton Trans., (1975) 370.
21. F. Piacenti, M. Bianchi, P. Frediani and E. Benedetti, Inorg. Chem., 10 (1971) 2759.