Uncommon η 3-(N,C,C′)-1-azaallyl bonding mode for the Nacnac ligand: A bis(β-diketiminato)uranium(III) iodide complex

Organometallics

Volumn 23, Issue 21, 2004, Pages 4801-4803

  Wright, Robert J ^a,b   Power, Philip P ^a   Scott, Brian L ^b   Kiplinger, Jaqueline L ^b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b LOS ALAMOS NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTALLINE SOLIDS; CYCLOPENTADIENYL LIGANDS; MULTIHAPTICITY; STERIC BULK;

CATALYSTS; COMPLEXATION; CRYSTALLOGRAPHY; IODINE COMPOUNDS; POLYMERIZATION; RARE EARTH ELEMENTS; STEREOCHEMISTRY; THERMAL EFFECTS; UNSATURATED COMPOUNDS;

ORGANOMETALLICS;

EID: 6344257077     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om049342u     Document Type: Article

References (22)

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6. 4U (mol wt 1286.38): C, 59.76; H, 7.30; N, 4.36. Found: C, 59.68; H, 7.52; N, 4.14.
7. 3, T = 203(2) K, R(I > 2σ) = 0.0470, and GOF = 1.323.
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9. 3-(N,C,C′)-1-azaallyl bonding interaction between a barium metal center and a β-diketiminate ligand: Clegg, W.; Coles, S. J.; Cope, E. K.; Mair, P. S. Angew. Chem., Int. Ed. 1998, 37, 796-798.
10. Allen, F. H.; Kennard, O.; Watson, D. G.; Brammer, L.; Orpen, A. G.; Taylor, R. J. Chem. Soc., Perkin Trans. 2 1987, S1-819.
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12. 3(MeCN), U-I = 3.1632(10)-3.2637(10) Å: Mazzanti, M.; Wietzke, R.; Pécaut, J.; Latour, J. M.; Maldivi, P.; Remy, M. Inorg. Chem. 2002, 41, 2389-2399.
13. 3(MeCN), U-I = 3.1632(10)-3.2637(10) Å: Mazzanti, M.; Wietzke, R.; Pécaut, J.; Latour, J. M.; Maldivi, P.; Remy, M. Inorg. Chem. 2002, 41, 2389-2399.
14. 3(MeCN), U-I = 3.1632(10)-3.2637(10) Å: Mazzanti, M.; Wietzke, R.; Pécaut, J.; Latour, J. M.; Maldivi, P.; Remy, M. Inorg. Chem. 2002, 41, 2389-2399.
15. 3(MeCN), U-I = 3.1632(10)-3.2637(10) Å: Mazzanti, M.; Wietzke, R.; Pécaut, J.; Latour, J. M.; Maldivi, P.; Remy, M. Inorg. Chem. 2002, 41, 2389-2399.
16. For a Th(IV) example, see: Smith, G. M.; Suzuki, H.; Sonnenberger, D. C.; Day, V. W.; Marks, T. J. Organometallics 1986, 5, 549-561.
17. Van Der Sluys, W. G.; Burns, C. J.; Sattelberger, A. P. Organometallics 1989, 8, 855-857.
18. For example: (a) Cesari, M.; Pedretti, U.; Zazzetta, A.; Lugli, G.; Marconi, W. Inorg. Chim. Acta 1971, 5, 439-444. (b) Cotton, F. A.; Schwotzer, W. Organometallics 1987, 6, 1275-1280. (c) Baudry, D.; Bulot, E.; Charpin, P.; Ephritikhine, M.; Lance, M.; Nierlich, M.; Vigner, J. J. Organomet. Chem. 1989, 371, 155-162. (d) Odom, A. L.; Arnold, P. L.; Cummins, C. C. J. Am. Chem. Soc. 1998, 120, 5836-5837. (e) Evans, W. J.; Nyce, G. W.; Forrestal, K. J.; Ziller, J. W. Organometallics 2002, 21, 1050-1055.
19. For example: (a) Cesari, M.; Pedretti, U.; Zazzetta, A.; Lugli, G.; Marconi, W. Inorg. Chim. Acta 1971, 5, 439-444. (b) Cotton, F. A.; Schwotzer, W. Organometallics 1987, 6, 1275-1280. (c) Baudry, D.; Bulot, E.; Charpin, P.; Ephritikhine, M.; Lance, M.; Nierlich, M.; Vigner, J. J. Organomet. Chem. 1989, 371, 155-162. (d) Odom, A. L.; Arnold, P. L.; Cummins, C. C. J. Am. Chem. Soc. 1998, 120, 5836-5837. (e) Evans, W. J.; Nyce, G. W.; Forrestal, K. J.; Ziller, J. W. Organometallics 2002, 21, 1050-1055.
20. For example: (a) Cesari, M.; Pedretti, U.; Zazzetta, A.; Lugli, G.; Marconi, W. Inorg. Chim. Acta 1971, 5, 439-444. (b) Cotton, F. A.; Schwotzer, W. Organometallics 1987, 6, 1275-1280. (c) Baudry, D.; Bulot, E.; Charpin, P.; Ephritikhine, M.; Lance, M.; Nierlich, M.; Vigner, J. J. Organomet. Chem. 1989, 371, 155-162. (d) Odom, A. L.; Arnold, P. L.; Cummins, C. C. J. Am. Chem. Soc. 1998, 120, 5836-5837. (e) Evans, W. J.; Nyce, G. W.; Forrestal, K. J.; Ziller, J. W. Organometallics 2002, 21, 1050-1055.
21. For example: (a) Cesari, M.; Pedretti, U.; Zazzetta, A.; Lugli, G.; Marconi, W. Inorg. Chim. Acta 1971, 5, 439-444. (b) Cotton, F. A.; Schwotzer, W. Organometallics 1987, 6, 1275-1280. (c) Baudry, D.; Bulot, E.; Charpin, P.; Ephritikhine, M.; Lance, M.; Nierlich, M.; Vigner, J. J. Organomet. Chem. 1989, 371, 155-162. (d) Odom, A. L.; Arnold, P. L.; Cummins, C. C. J. Am. Chem. Soc. 1998, 120, 5836-5837. (e) Evans, W. J.; Nyce, G. W.; Forrestal, K. J.; Ziller, J. W. Organometallics 2002, 21, 1050-1055.
22. For example: (a) Cesari, M.; Pedretti, U.; Zazzetta, A.; Lugli, G.; Marconi, W. Inorg. Chim. Acta 1971, 5, 439-444. (b) Cotton, F. A.; Schwotzer, W. Organometallics 1987, 6, 1275-1280. (c) Baudry, D.; Bulot, E.; Charpin, P.; Ephritikhine, M.; Lance, M.; Nierlich, M.; Vigner, J. J. Organomet. Chem. 1989, 371, 155-162. (d) Odom, A. L.; Arnold, P. L.; Cummins, C. C. J. Am. Chem. Soc. 1998, 120, 5836-5837. (e) Evans, W. J.; Nyce, G. W.; Forrestal, K. J.; Ziller, J. W. Organometallics 2002, 21, 1050-1055.