Synthesis, structure and magnetic properties of the mixed metal oxide solids [{M(H 2O) 2}V 2O 6] (M=Co, Ni)

Journal of Molecular Structure

Volumn 707, Issue 1-3, 2004, Pages 217-222

  Khan, M Ishaque ^a   Deb, Sangita ^a   Golub, Vladimir O ^b   O'Connor, Charles J ^b   Doedens, Robert J ^c  

^a ILLINOIS INSTITUTE OF TECHNOLOGY   (United States)

^b UNIVERSITY OF NEW ORLEANS   (United States)

^c UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Crystal structure; Hydrothermal synthesis; Magnetic susceptibility; Mixed metal oxide

Indexed keywords

COBALT; METAL OXIDE; NICKEL; VANADIUM;

ARTICLE; CROSS LINKING; CRYSTAL STRUCTURE; INFRARED SPECTROSCOPY; MAGNETISM; SYNTHESIS; THERMOGRAVIMETRY; THERMOSTABILITY; TITRIMETRY; X RAY ANALYSIS;

EID: 6344228304     PISSN: 00222860     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molstruc.2004.07.030     Document Type: Article

References (49)

1. J.P. Jolivet Metal Oxide Chemistry and Synthesis 2000 Wiley England
2. W.P. Griffith Trans. Met. Chem. 16 1991 548
3. I.V. Kozhevnikov Russ. Chem. Rev. 56 1987 811
4. I.V. Kozhevnikov Russ. Chem. Rev. 62 1993 473
5. D. Linden Handbook of Batteries 1995 McGraw-Hill New York
6. T.A. Chirayil, P.Y. Zavalij, and M.S. Whittingham J. Electrochem. Soc. 143 1996 L193
7. F. Leroux, B.E. Koene, and L.F. Nazar J. Electrochem. Soc. 143 1996 L181
8. M. Zhang, and J.R. Dahn J. Electrochem. Soc. 143 1996 2730
9. J. Desilvestro, and O. Haas J. Electrochem. Soc. 137 1990 5C
10. H.T. Evans Jr., and J.A. Konnert Am. Mineral. 63 1978 863
11. E.S. Leonardsen, and O.V. Petersen Am. Mineral. 59 1974 372
12. A. Müller, J. Döring, M.I. Khan, and V. Wittneben Angew. Chem. Int. Ed. Engl. 30 1991 210 and references therein
13. A. Müller, F. Peters, M.T. Pope, and D. Gatteschi Chem. Rev. 98 1998 239
14. M.T. Pope, and A. Müller Angew. Chem. Int. Ed. Engl. 30 1991 34
15. W.G. Klemperer, T.A. Marquart, and O.M. Yaghi Angew. Chem. Int. Ed. Engl. 31 1992 49
16. M.T. Pope, and A. Müller Angew. Chem. Int. Ed. Engl. 30 1991 34
17. D. Gatteschi, L. Pardi, A.L. Barra, and A. Müller M.T. Pope A. Müller Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity 1994 Kluwer Dordrecht, Netherlands
18. E. Coronado, and C.J. Gomez-Garcia Inorg. Chem. 17 1995 255
19. P.J. Hagrman, R.C. Finn, and J. Zubieta Solid State Sci. 3 2001 1293
20. P.Y. Zavalij, and M.S. Wittingham Acta Cryst. B55 1999 627
21. A. Müller, F. Peters, M.T. Pope, and D. Gatteschi Chem. Rev. 98 1998 239
22. A. Müller, R. Sessoli, E. Krickemeyer, H. Boegge, J. Meyer, D. Gatteschi, L. Pardi, J. Westphal, K. Hovemeier, R. Rohlfing, J. Doring, F. Hellweg, C. Beugholt, and M. Schmidtmann Inorg. Chem. 36 1997 5239
23. D. Gatteschi, R. Sessoli, W. Plass, A. Müller, E. Krickemeyer, J. Meyer, D. Solter, and P. Adler Inorg. Chem. 35 1996 1926
24. See the special edition: polyoxometalates C.L. Hill Chemical Reviews vol. 98 1998 1 390
25. M.I. Khan, E. Yohannes, and R.J. Doedens Inorg. Chem. 42 2003 3125
26. M.I. Khan, E. Yohannes, and D. Powell J. Chem. Soc., Chem. Commun. 1999 23
27. M.I. Khan, E. Yohannes, R.J. Doedens, S. Tabussum, S. Cevik, L. Manno, and D. Powell Cryst. Eng. 2 1999 171
28. M.I. Khan, T. Hope, and S. Tabussum Solid State Sci. 1 1999 163
29. M.I. Khan Framework materials composed of transition metal oxide clusters M.T. Pope A. Müller Polyoxometalate Chemistry. From Topology via Self-Assembly to Applications 2001 Kluwer Dordrecht 255
30. M.I. Khan, E. Yohannes, and R.J. Doedens Angew. Chem. Int. Ed. Engl. 38 1999 1292
31. M.I. Khan J. Solid State Chem. 152 2000 105
32. M.I. Khan, T. Hope, S. Cevik, C. Zheng, and D. Powell J. Cluster Sci. 11 2000 433
33. M.I. Khan, S. Cevik, and R.J. Doedens Composite materials derived from oxovanadium sulfates T. Yamase M.T. Pope Polyoxometalate Chemistry for Nano-Composite Design 2002 Kluwer New York 27 38
34. M.I. Khan, S. Tabussum, and R.J. Doedens J. Chem. Soc., Chem. Commun. (2003) 532
35. M.I. Khan, S. Tabussum, R. Doedens, V. Golub, and C. O'Connor Inorg. Chem. Commun. 7 2003 54
36. M.I. Khan, E. Yohannes, S. Ayesh, and R.J. Doedens J. Mol. Struct. 656 2003 45
37. A 10 mg of the sample of 1 was taken in a 70 μl alumina pan and heated from 25 to 500°C at a rate of 5°C/min in nitrogen atmosphere with a flow rate of 60-90 ml/min. A 10.02 mg sample of 2 was taken in a 70 μl alumina pan and heated in a nitrogen atmosphere from 25 to 500°C under a flow rate of 60-90 ml/min.
38. Typically a 20.6 mg of sample was dissolved in a 1 M sulfuric acid and titrated with a permanganate solution that had been standardized with sodium oxalate solution.
39. C.J. O'Connor Prog. Inorg. Chem. 29 1979 203
40. 2=1.135.
41. SMART, version 4.210; Siemens Analytical X-ray Systems, Madison, WI, 1997.
42. SAINT, version 4.050; Siemens Analytical X-ray Systems, Madison, WI, 1995.
43. G.M. Sheldrick SHELXTL, version 5.03 1995 Siemens Industrial Automation, Inc Madison, WI
44. G.M. Sheldrick SADABS 1997 University of Gottingen Gottingen, Germany
45. 6] (2) are available on request from the Fachinformationszentrum (FIZ), Karlsruhe, Germany (http://icsd.fiz-karlsruhe.de) by providing CSD numbers for the compounds (CSD number 414007 and 414008, respectively).
46. 2O (1.87 mmol) was added with continuous stirring. The resulting red solution was treated with an aqueous solution (1.8 ml) of 4-aminopyridine (3.4 mmol) to give a reddish black color solution. After refluxing this solution for 48 h it was allowed to stay at room temperature for two days. The dark red crystals were filtered from the orange mother liquor, thoroughly washed with hot water, and dried in air at room temperature to yield ∼118 mg (∼64.48% based on vanadium) of 1.
47. 2O (1.87 mmol) was added with continuous stirring to give a light green solution. The green solution was treated with an aqueous solution (1.8 ml) of 4-aminopyridine (3.4 mmol), which resulted into the formation of a green precipitate. The reaction mixture was transferred to a 23 ml Teflon-lined Parr autoclave and heated at 145°C for 4 days. The autoclave was then slowly cooled to room temperature for one day. The light green crystals, which were mixed with yellowish green and orange impurities, were filtered from the light green mother liquor and dried in air at room temperature. The light green crystals of 2 were separated from the impurity to yield ∼69.9 mg (∼38.23% based on vanadium) of pure material.
48. M.J. Goldcamp, S.E. Edison, L.N. Squires, D.T. Rosa, N.K. Vowels, N.L. Coker, J.A. Krause Bauer, and M.J. Baldwin Inorg. Chem. 42 3 2003 717
49. F.E. Mabbs, and D.J. Machin Magnetism and Transition Metal Complexes 1973 Chapman and Hall London 99 100