Mechanistic study of novel oxidation of paracetamol by chloramine-T using micro-amount of chloro-complex of Ir(III) as a homogeneous catalyst in acidic medium

Journal of Molecular Catalysis A: Chemical

Volumn 302, Issue 1-2, 2009, Pages 36-42

  Singh, Ajaya Kumar ^a   Negi, Reena ^a   Katre, Yokraj ^b   Singh, Surya Prakash ^c  

^a GovtVYTPG Autonomous College Durg   (India)

^b Kalyan Post Graduate College   (India)

^c OSAKA UNIVERSITY   (Japan)

Author keywords

Chloramine T; Ir(III) chloride; Mechanistic study; Oxidation; Paracetamol

Indexed keywords

AMINATION; CHLORINE COMPOUNDS; INORGANIC ACIDS; IONIC STRENGTH; IRIDIUM; IRIDIUM COMPOUNDS; MECHANICS; OXIDATION; REACTION KINETICS; SODIUM; STOICHIOMETRY; TOLUENE;

ACID MEDIUMS; ACIDIC MEDIUMS; ACTIVATION PARAMETERS; CATALYZED OXIDATIONS; CHLORAMINE-T; DIELECTRIC CONSTANTS; FIRST-ORDER KINETICS; FIRST-ORDER RATE CONSTANTS; HOMOGENEOUS CATALYSTS; IR(III) CHLORIDE; KINETIC STUDIES; MECHANISTIC STUDY; PARACETAMOL; PERCHLORIC ACIDS; PLAUSIBLE MECHANISMS; PRODUCT ANALYSIS; RATE OF REACTIONS; REACTION STOICHIOMETRIES;

RATE CONSTANTS;

EID: 62949090111     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2008.11.041     Document Type: Article

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