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Volumn 694, Issue 9-10, 2009, Pages 1251-1253

Synthesis of Ph2LSn(μ-OH)Bu3SnCl. Trapping of monomeric triorganotin hydroxide Ph2LSnOH

Author keywords

Crystal structure; NMR spectroscopy; Organotin compounds; Pincer ligands

Indexed keywords

LIGANDS; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLICS; TIN; TIN COMPOUNDS; X RAY DIFFRACTION ANALYSIS;

EID: 62849121962     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2009.01.009     Document Type: Article
Times cited : (7)

References (38)
  • 22
    • 62849099469 scopus 로고    scopus 로고
    • note
    • -1) ν (OH) = 3468 vbr.
  • 23
    • 62849102749 scopus 로고    scopus 로고
    • Since the reaction of Me3 SnCl and (Me3Sn)2O resulted to the isolation of an unusual, Me3Sn)3O, Cl- compound with two dimensional, graphite like supramolecular structure based upon Sn⋯Cl secondary bonds [8b] similar compound, Bu3Sn)2 (Ph2 LSn)O, Cl- can be postulated as an intermediate of the reaction of 1 with (Bu3Sn)2O. The presence of O,C,O-chelating ligand L could caused high non-stability of the intermediate resulting thus to the immediate reaction with water yielding compound 2. Alternatively, the reaction of (Bu3Sn)2O with H2O yielded Bu3SnOH that reacted with Ph2LSnCl to form compound 2
    • 2LSnCl to form compound 2.
  • 30
    • 62849101073 scopus 로고    scopus 로고
    • note
    • 2 = 0.1215. The structure was solved by direct methods (Sheldrick G.M.: SHELX-97[17] program package, University of Goettingen 1997., Sheldrick G.M.: SHELXTL V 5.1[18], Bruker AXS GmbH.) Non-hydrogen atoms were refined anisotropically while hydrogen atoms were inserted in calculated positions and isotropically refined assuming a "ride-on" model.
  • 38
    • 62849111440 scopus 로고    scopus 로고
    • G.M. Sheldrick: SHELXTL V 510, Bruker AXS Inc., Madison, Wl, 1997.
    • G.M. Sheldrick: SHELXTL V 510, Bruker AXS Inc., Madison, Wl, 1997.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.