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62849099469
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note
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-1) ν (OH) = 3468 vbr.
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23
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62849102749
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Since the reaction of Me3 SnCl and (Me3Sn)2O resulted to the isolation of an unusual, Me3Sn)3O, Cl- compound with two dimensional, graphite like supramolecular structure based upon Sn⋯Cl secondary bonds [8b] similar compound, Bu3Sn)2 (Ph2 LSn)O, Cl- can be postulated as an intermediate of the reaction of 1 with (Bu3Sn)2O. The presence of O,C,O-chelating ligand L could caused high non-stability of the intermediate resulting thus to the immediate reaction with water yielding compound 2. Alternatively, the reaction of (Bu3Sn)2O with H2O yielded Bu3SnOH that reacted with Ph2LSnCl to form compound 2
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2LSnCl to form compound 2.
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28
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33745760026
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Lyčka A., Šnobl D., Handlíř K., Holeček J., and Nádvorník M. Collect. Czech. Chem. Commun. 46 (1981) 1383
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Lyčka, A.1
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Nádvorník, M.5
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30
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62849101073
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note
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2 = 0.1215. The structure was solved by direct methods (Sheldrick G.M.: SHELX-97[17] program package, University of Goettingen 1997., Sheldrick G.M.: SHELXTL V 5.1[18], Bruker AXS GmbH.) Non-hydrogen atoms were refined anisotropically while hydrogen atoms were inserted in calculated positions and isotropically refined assuming a "ride-on" model.
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34
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19444380979
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Lerner H.W., Ilkhechi A.H., Bolte M., and Wagner M. Z. Naturforsch., B: Chem. Sci. 60 (2005) 413
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38
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62849111440
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G.M. Sheldrick: SHELXTL V 510, Bruker AXS Inc., Madison, Wl, 1997.
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G.M. Sheldrick: SHELXTL V 510, Bruker AXS Inc., Madison, Wl, 1997.
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