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30344460821
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-
119Sn) NMR shift should be measured and compared with the chemical shift in solution to be unambiguously sure that compound 8 forms cation both in solution and in the solid state.
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27
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0000671403
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30344444137
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note
-
c = coalescence temperature (K), and Δv = chemical shift difference (Hz); the other symbols have their usual meanings.
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-
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29
-
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30344469530
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note
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119Sn spectra, due to the huge chemical shift differences.
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30
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0000035505
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30344463679
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(b) The correlation coefficient r = 0.997 for 4, 0.991 for 9, and 0.996 for 10 for the plot of In K vs 1/T in the equilibrium dissociation of 4, 9, and 10.
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32
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6344270299
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30344464234
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2Sn trigonal bipyramid is attacked by the second nitrogen donor atom from a pincer ligand.
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