A novel phosphorus polyurethane FOAM/montmorillonite nanocomposite: Preparation, characterization and thermal behaviour

Applied Clay Science

Volumn 44, Issue 1-2, 2009, Pages 35-42

  Semenzato, Simone ^a   Lorenzetti, Alessandra ^a   Modesti, Michele ^a   Ugel, Elisabetta ^a   Hrelja, Denis ^a   Besco, Stefano ^a   Michelin, Rino A ^a   Sassi, Alessandro ^b   Facchin, Giacomo ^b   Zorzi, Federico ^c   Bertani, Roberta ^a  

^a Dipartimento di Processi Chimici dell'Ingegneria   (Italy)

^b CNR Consiglio Nazionale delle Ricerche   (Italy)

^c Dipartimento di Geoscienze   (Italy)

Author keywords

Montmorillonite; Nanocomposite; Phosphonium salt; Polyurethane foam; Thermal behaviour

Indexed keywords

ALUMINUM; AMMONIUM COMPOUNDS; CLAY MINERALS; DYNAMIC POSITIONING; NANOCOMPOSITES; PERCOLATION (SOLID STATE); PHOSPHORUS; POLYMERS; RIGID FOAMED PLASTICS; SILICATE MINERALS; WATER;

BASAL SPACINGS; BI LAYERS; CLOISITE; HOT WATERS; MONTMORILLONITE; PHOSPHONIUM SALT; POLYURETHANE FOAM; POLYURETHANE RIGID FOAMS; TGA CURVES; THERMAL BEHAVIORS; THERMAL BEHAVIOUR; THERMAL STABILITIES; WEIGHT LOSS; X- RAY DIFFRACTIONS;

FOAMS;

COMPOSITE; MONTMORILLONITE; NUCLEAR MAGNETIC RESONANCE; POLYMER; THERMODYNAMIC PROPERTY; X-RAY DIFFRACTION;

EID: 62349121832     PISSN: 01691317     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.clay.2009.01.003     Document Type: Article

References (49)

1. In: Bergaya F., Theng B.K.G., and Lagaly G. (Eds). Handbook of Clay Science (2006), Elsevier, Amsterdam
2. Berta M., Lindsay C., Pans G., and Camino G. Effect of chemical structure on combustion and thermal behaviour of polyurethane elastomers layered silicate nanocomposites. Polym. Degrad. Stab. 91 (2006) 1179-1191
3. Calderon J.U., Lennox B., and Kamal M.R. Thermally stable phosphonium-montmorillonite organoclays. Appl. Clay Sci (2007) 10.1016/j.clay.2007.08.004
4. Cao X., Lee L.J., Widya T., and Macosko C. Polyurethane/clay nanocomposites foams: processing, structure and properties. Polymer 46 (2005) 775-783
5. Carrado K.A. Synthetic organo- and polymer-clays: preparation, characterization, and material applications. Appl. Clay Sci. 17 (2001) 1-23
6. Chen G., Yao K., and Zhao J. Montmorillonite clay/poly(methyl methacrylate)hybrid resin and its barrier property to the plasticizer within poly(vinyl chloride) composite. J. Appl. Polym. Sci. 73 (1999) 425-430
7. 31P NMR study of gel derived phosphosilicate glasses. J. Mater. Chem. 11 (2001) 936-943
8. Clayden N.J., Aronne A., Esposito S., and Pernice P. Solid state NMR study of phosphosilicate gels. J. Non-cryst. Solids 345 and 346 (2004) 601-604
9. 31P NMR and X-ray crystallographic studies of tertiary phosphines and their derivatives. Inorg. Chem. 30 (1991) 2380-2387
10. Dennis H.R., Hunter D.L., Chang D., Kim S., White J.L., Chow J.W., and Paul D.R. Effect of melt processing conditions on the extent of exfoliation in organoclay-based nanocomposites. Polymer 42 (2001) 9513-9522
11. Drachman S.R., Roch G.E., and Smith M.E. Solid state NMR characterization of the thermal transformation of Fuller's earth. Solid State Nucl. Magn. Reson. 9 (1997) 257-267
12. Duquesne S., Le Bras M., Bourbigot S., Delobel R., Camino G., Eling B., Lindsay C., and Roels T. Thermal degradation of polyurethane and polyurethane/expandable graphite coatings. Polym. Degrad. Stab. 74 (2001) 493-499
13. Fan X., Zhou Q., Xia C., Cristofoli W., Mays J., and Advincula R. Living anionic surface-initiated polymerization (LASIP) of styrene from clay nanoparticles using surface bound 1,1-diphenylethylene (DPE) initiators. Langmuir 18 (2002) 4511-4518
14. Garces J.M., Moll D.J., Bicerano J., Fibiger R., and McLeod D.G. polymeric nanocomposites for automotive applications. Adv. Mater. 12 (2000) 1835-1839
15. Harikrishnan G., Umasankar Patro T., and Khakhar D.V. Polyurethane foam-clay nanocomposites: nanoclays as cell openers. Ind. Eng. Chem. Res. 45 (2006) 7126-7134
16. Hedley C.B., Yuan G., and Theng B.K.G. Thermal analysis of montmorillonites modified with quaternary phosphonium and ammonium surfactants. Appl. Clay Sci. 35 (2007) 180-188
17. Huang J.C., Zhu Z., Yin J., Qian X., and Sun Y.Y. Poly(etherimide)/montmorillonite nanocomposites prepared by melt intercalation: morphology, solvent resistance properties and thermal properties. Polymer 42 (2001) 873-877
18. Johnson A.W. Ylides and Imines of Phosphorus (1993), Wiley, New York
19. Kandola B.K. Composites. In: Horrocks A.R., and Price D. (Eds). Fire Retardant Materials (2004), Woodhead Publishing Limited CRC, Press, Boca Raton 204-219
20. Kawasumi M., Hasegawa N., Kato M., Usuki A., and Okada A. Preparation and mechanical properties of polypropylene-clay hybrids. Macromolecules 30 (1997) 6333-6338
21. Kojima Y., Usuki A., Kawasumi M., Okada A., Kurauchi T., and Kamigaito O. Sorption of water in nylon 6-clay hybrid. J. Appl. Polym. Sci. 49 (1993) 1259-1264
22. Kojima Y., Usuki A., Kawasumi M., Okada A., Fukushima Y., Kurauchi T., and Kamigaito O. Mechanical properties of nylon 6-clay hybrid. J. Mater. Res. 8 (1993) 1185-1189
23. Krishnamoorti R., and Vaia R.A. Polymer nanocomposites. J. Polym. Sci. Part B: Polym. Phys. 45 (2007) 3252-3256
24. Lagaly G., Ogawa M., and Dekany I. Clay mineral organic interactions. In: Bergaya F., Theng B.K.G., and Lagaly G. (Eds). Handbook of Clay Science (2006), Elsevier, Amsterdam 309-377
25. LeBaron P.C., Wang Z., and Pinnavaia T.J. Polymer-layered silicate nanocomposites: an overview. Appl. Clay Sci. 15 (1999) 11-29
26. Lee L.J., Zeng C., Cao X., Han X., Shen J., and Xu G. Polymer nanocomposite foams. Compos. Sci. Technol. 65 (2005) 2344-2363
27. Leszczynska A., Njuguna J., Pielichowski K., and Banerjee J.R. Thermochim. Acta 453 (2007) 75-96
28. Li Y.Q., and Ishida H. a differential scanning calorimetry study of the assembly of hexadecylamine molecules in the nanoscale confined space of silicate galleries. Chem. Mater. 14 (2002) 1398-1404
29. 2PCCO to Pd and Pt complexes. Inorg. Chim. Acta (2008) 10.1016/j.ica.2007.10.055
30. Modesti M., Lorenzetti A., and Besco S. Influence of nanofillers on thermal insulating properties of polyurethane nanocomposites foams. Polym. Eng. Sci. 47 (2007) 1351-1358
31. Modesti M., Lorenzetti A., Besco S., Hrelja D., Semenzato S., Bertani R., and Michelin R.A. Synergism between flame retardant and modified layered silicate on thermal stability and fire behaviour of polyurethane nanocomposite foams. Polym. Degrad. Stab. 93 12 (2008) 2166-2171
32. Mondal P., and Khakhar D.V. Rigid polyurethane-clay nanocomposite foams: preparation and properties. J. Appl. Polym. Sci. 103 (2007) 2802-2809
33. Morgan A.B., and Harris J.D. Exfoliated polystyrene-clay nanocomposites synthesized by solvent blending with sonication. Polymer 45 (2004) 8695-8703
34. Ogawa M., and Kuroda K. Preparation of inorganic-organic nanocomposites through intercalation of organoammonium ions into layered silicates. Bull. Chem. Soc. Jpn. 70 (1997) 2593-2618
35. Patel H.A., Somani R.S., Bajai H.C., and Jasra R.V. Preparation and characterization of phosphonium montmorillonite with enhanced thermal stability. Appl. Clay Sci. 35 (2007) 194-200
36. Petit S. Fourier transform infrared spectroscopy. In: Bergaya F., Theng B.K.G., and Lagaly G. (Eds). Handbook of Clay Science (2006), Elsevier, Amsterdam 909-918
37. Rhoney I., Brown S., Hudson N.E., and Pethrick R.A. Influence of processing method on the exfoliation process for organically modified clay systems. I. Polyurethanes. J. Appl. Polym. Sci. 91 (2003) 1335-1343
38. Schmidt G., and Malwitz M.M. Properties of polymer-nanoparticle composites. Curr. Opin. Colloid Interface Sci. 8 (2003) 103-108
39. Seo W.J., Sung Y.T., Kim S.B., Lee Y.B., Choe K.H., Choe S.H., Sung J.Y., and Kim W.N. Effects of ultrasound on the synthesis and properties of polyurethane foam/clay nanocomposites. Appl. Polym. Sci. 102 (2006) 3764-3773
40. Takekoshi, T., Khouri, F.F., Campbell, J.R., Jordan, T.C., Dai, K.H. 1998. Layered minerals and compositions comprising the same. United States Patent, 5,707,439.
41. Wang J.Q., and Chow W.K. A brief review on fire retardants for polymeric foams. J. Appl. Polym. Sci. 97 (2005) 366-376
42. Widya T., and Macosko C.W. Nanoclay-modified rigid polyurethane foam 1. J. Macromol. Sci., Part B: Phys. 44 (2005) 897-908
43. Woo T., Halley P., Martin D., and Kim D.S. Effect of different preparation routes on the structure and properties of rigid polyurethane-layered silicate nanocomposites. J. Appl. Polym. Sci. 102 (2006) 2894-2903
44. Xie W., Xie R., Pan W.P., Hunter D., Koene B., Tan L.S., and Vaia R. Thermal stability of quaternary phopshonium modified montmorillonites. Chem. Mater. 14 (2002) 4837-4845
45. Xu Z., Tang X., Gu A., and Fang Z. Novel preparation and mechanical properties of rigid polyurethane foam/organoclay nanocomposites. J. Appl. Polym. Sci. 106 (2007) 439-447
46. Yeh J.M., and Chin C.P. Structure and properties of poly(o-methoxyaniline)-clay nanocomposite materials. J. Appl. Polym. Sci. 88 (2003) 1072-1080
47. Yoon P.S., Hunter D.L., and Paul D.R. Polycarbonate nanocomposites. Part 1. Effect of organoclay structure on morphology and properties. Polymer 44 (2003) 5323-5339
48. Zhou Q., Fan X., Xia C., Mays J., and Advincula R. Living anionic surface initiated polymerization (SIP) of styrene from clay surfaces. Chem. Mater. 13 (2001) 2465-2467
49. Zhu J., Morgan A.B., Lamelas F.J., and Wilkie C.A. Fire properties of polystyrene-clay nanocomposites. Chem. Mater. 13 (2001) 3774-3780