Phase behavior in self-assembly of inorganic/poly(4-vinylpyridine)-b- poly(ε-caprolactone) hybrid

Macromolecules

Volumn 42, Issue 3, 2009, Pages 742-751

  Lin, Tao ^a   Ho, Rong Ming ^a   Ho, Jia Chong ^b  

^a NATIONAL TSING HUA UNIVERSITY   (Taiwan)

^b INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

BLOCK COPOLYMERS; GOLD; MICROPHASE SEPARATION; POLYMERS; TRANSMISSION ELECTRON MICROSCOPY; X RAY SCATTERING;

4-VINYLPYRIDINE; BRIDGING MECHANISMS; CAPROLACTONE; CORRELATION FUNCTIONS; DIBLOCK COPOLYMERS; EXCLUDED VOLUMES; GOLD PRECURSORS; MICRO DOMAINS; MORPHOLOGICAL EVOLUTIONS; NANO-STRUCTURED; ORDERED PHASE; PHASE TRANSFORMATIONS; POLY(4VINYLPYRIDINE); SELF- ASSEMBLIES; SMALL - ANGLE X-RAY SCATTERINGS; THEORETICAL PREDICTIONS;

PHASE SEPARATION;

EID: 61849183141     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma8015618     Document Type: Article

References (37)

1. Spatz, J. P.; Roescher, A.; Moller, M. Adv. Mater. 1996, 8, 337.
2. Forster, S.; Antonietti, M. Adv. Mater. 1998, 10, 195.
3. Thurn-Albrecht, T.; Schotter, J.; Kastle, G. A.; Emley, N.; Shibauchi, T.; Krusin-Elbaum, L.; Guarini, K.; Black, C. T.; Tuominen, M. T.; Russell, T. P. Science 2000, 290, 2126.
4. Lopes, W. A.; Jaeger, M. Nature 2001, 414, 735.
5. Bockstaller, M. R.; Kolb, R.; Thomas, E. L. Adv. Mater. 2001, 13, 1783.
6. Ribbe, A. E.; Okumura, A.; Matsushige, K.; Hashimoto, T. Macromolecules 2001, 34, 8239.
7. Sohn, B. H.; Seo, B. H. Chem. Mater. 2001, 13, 1752.
8. Boontongkong, Y.; Cohen, R. E. Macromolecules 2002, 35, 3647.
9. Abes, J. I.; Cohen, R. E.; Ross, C. A. Chem. Mater. 2003, 15, 1125.
10. Yeh, S. W.; Wei, K. H.; Sun, Y. S.; Jeng, U. S.; Liang, K. S. Macromolecules 2005, 38, 6559.
11. Bockstaller, M. R.; Thomas, E. L. Phys. Rev. Lett. 2004, 93, 166106.
12. Li, H.; Eddaoudi, M.; O'Keeffe, M; Yaghi, O. M. Nature 1999, 402, 276.
13. He, Y.; Lodge, T. P. Macromolecules 2008, 41, 167.
14. Cho, J. H.; Lee, J.; He, Y.; Kim, B.; Lodge, T. P.; Frisbie, C. Adv. Mater. 2008, 20, 686.
15. Yaghi, O. M.; Li, G.; Li, H. Nature 1995, 378, 703.
16. Huh, J.; Ginzburg, V. V.; Balazs, A. C. Macromolecules 2000, 33, 8085.
17. Thompson, R. B.; Ginzburg, V. V.; Matsen, M. W.; Balazs, A. C. Science 2001, 292, 2469.
18. Matsen, M. W.; Thompson, R. B. Macromolecules 2008, 41, 1853.
19. Hashimoto, T.; Tanaka, H.; Hasegawa, H. Macromolecules 1990, 23, 4378.
20. Lodge, T. P.; Pudil, B.; Hanley, K. J. Macromolecules 2002, 35, 4707.
21. Bockstaller, M. R.; Lapetnikov, Y.; Margel, S.; Thomas, E. L. J. Am. Chem. Soc. 2003, 125, 5276.
22. Kim, B. J.; Chiu, J. J.; Yi, G.; Pine, D. J.; Kramer, E. J. Adv. Mater. 2005, 17, 2618.
23. Huang, C. M.; Wei, K. H.; Jeng, U. S.; Liang, K. S. Macromolecules 2007, 40, 5067.
24. Lo, C. T.; Lee, B.; Pol, V. G.; Rago, N. L. D.; Seifert, S.; Winans, R. E.; Thiyagarajan, P. Macromolecules 2007, 40, 8302.
25. Adachi, M.; Okumura, A.; Sivaniah, E.; Hashimoto, T. Macromolecules 2006, 39, 7352.
26. Ho, R. M.; Lin, T.; Jhong, M. R.; Chung, T. M.; Ko, B. T.; Chen, Y. C. Macromolecules 2005, 38, 8607.
27. Lee, D. H.; Kim, H. Y.; Kim, J. K.; Huh, J.; Ryu, D. Y. Macromolecules 2006, 39, 2027.
28. He, Y.; Li, Z.; Simore, P.; Lodge, T. P. J. Am. Chem. Soc. 2006, 128, 2745.
29. Simore, P.; Lodge, T. P. Macromolecules 2008, 41, 1753.
30. Lodge, T. P. Science 2008, 4, 50.
31. Wang, J. P.; Chen, W.; Roy, C.; Sievert, J. D.; Russell, T. P. Macromolecules 2008, 41, 963.
32. Wang, J. P.; Chen, W.; Russell, T. P. Macromolecules 2008, 41, 4904.
33. Ko, B. T.; Lin, C. C. Macromolecules 1999, 32, 8296.
34. Xia, J.; Zhang, X.; Matyjaszewski, K. Macromolecules 1999, 32, 3531.
35. pcl = 0.5) served to determine the temperature dependence of χ that is described by χ(T) = 103.48/T-0.062. The order-disorder-transition temperatures for P4VP-b-PCL samples tested here were determined from SAXS at various temperature ≥120 °C to avoid nonequilibrium effects below the glass transition of P4VP. The synthesized BCP is not expected to disorder up to their decomposition point (>200 °C) on the basis of the block chain length and in situ SAXS evidence.
36. Hunter, R. J. Foundations of Colloid Science; Oxford University Press: New York, 1987.
37. Sakurai, S.; Momii, T.; Taie, K.; Shibayama, M.; Nomura, S.; Hashimoto, T. Macromolecules 1993, 26, 485.