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Strictly speaking, this statement is applicable only if the system is in the strong segregation regime (which is the case in our study), so there are no B-blocks in the (A + P)-region. In this case, any local increase in the particle density would cause a corresponding decrease in the local density of A-block, and the two would be "out of phase". Conversely, the absence of "out of phase" modes indicates the random (uniform on average) distribution of particles within the (A + P)-region.
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6744221932
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We disregard the possibility of particle crystallization at high volume fractions. In principle, such an effect could affect the phase behavior of the composite. The role of crystallization will be considered in future studies.
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6744228597
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note
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x ≈ 10.5.
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42
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6744262937
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note
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We assume a uniform distribution of particles in the A-block. This approximation overstates the elastic (stretching) energy of the polymer chains, As a result, the order - disorder transitions are depressed toward lower values of ø, but the overall topology of the phase diagrams is not affected. Taking into account the inhomogeneous (parabolic) particle distribution is beyond the accuracy of this scaling approach, but will be the subject of future studies.
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43
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6744241195
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note
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39 However, these structures are either metastable or even unstable but dynamically "frozen" states. The equilibrium state is still the macrophase-separated one.
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