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Examples of more commonly observed nucleophilic reactivity between metal carbenes and heterocumulenes: (a) Schrock, R. R. J. Am. Chem. Soc. 1976, 98, 5399
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Examples of more commonly observed nucleophilic reactivity between metal carbenes and heterocumulenes: (a) Schrock, R. R. J. Am. Chem. Soc. 1976, 98, 5399.
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28
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29044433052
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This behavior is more closely related to what is observed for Sadighi's structurally and electronically similar Cu(I)-boryl complexes: (a) Laitar, D. S, Müller, P, Sadighi, J. P. J. Am. Chem. Soc. 2005, 127, 17196
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This behavior is more closely related to what is observed for Sadighi's structurally and electronically similar Cu(I)-boryl complexes: (a) Laitar, D. S.; Müller, P.; Sadighi, J. P. J. Am. Chem. Soc. 2005, 127, 17196.
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This binding motif for CS2 has been observed previously: (a) Werner, H, Kolb, O, Feser, R, Schubert, U. J. Organomet. Chem. 1980, 191, 283
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2 has been observed previously: (a) Werner, H.; Kolb, O.; Feser, R.; Schubert, U. J. Organomet. Chem. 1980, 191, 283.
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Though not observed for our system, an iridium-supported head-to-tail dimer of C02 has also been reported: Herskovitz, T, Guggenberger, L. J. J. Am. Chem. Soc. 1976, 98, 1615
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2 has also been reported: Herskovitz, T.; Guggenberger, L. J. J. Am. Chem. Soc. 1976, 98, 1615.
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40
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61849129425
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Similar behavior has been observed for phosphine-supported ruthenium carbenes: (a) Nguyen, S. T.; Johnson, L. K.; Grubbs, R. H.; Slier, J. W. J. Am. Chem. Soc. 1992, 113, 3974.
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Similar behavior has been observed for phosphine-supported ruthenium carbenes: (a) Nguyen, S. T.; Johnson, L. K.; Grubbs, R. H.; Slier, J. W. J. Am. Chem. Soc. 1992, 113, 3974.
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49
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84868905713
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2 adduct and dithiolactone shown in Scheme 2 are in equilibrium, but we currently have no evidence supporting this view.
-
2 adduct and dithiolactone shown in Scheme 2 are in equilibrium, but we currently have no evidence supporting this view.
-
-
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50
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33748245045
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The reactivity of metal-ligand multiple bonds with carbon disulfide is typically initiated by nucleophilic ligands: (a) Mayr, A, Lee, T.-Y. Angew. Chem, Int. Ed. 1993, 32, 1726
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The reactivity of metal-ligand multiple bonds with carbon disulfide is typically initiated by nucleophilic ligands: (a) Mayr, A.; Lee, T.-Y. Angew. Chem., Int. Ed. 1993, 32, 1726.
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52
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33947296498
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8 metal complexes is well-known and has been extensively investigated: (a) Shriver, D. F. Ace. Chem. Res. 1970, 3, 231.
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61849184016
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Further details regarding calculations on 1, 3, 5, and 6 are provided in the Supporting Information.
-
Further details regarding calculations on 1, 3, 5, and 6 are provided in the Supporting Information.
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59
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0001368552
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The electrophilicity of the metal center in many alkylidene complexes is so pronounced that the M=C-H bond angle is contracted to allow an a-agostic interaction with the electron-deficient metal center
-
(a) The electrophilicity of the metal center in many alkylidene complexes is so pronounced that the M=C-H bond angle is contracted to allow an a-agostic interaction with the electron-deficient metal center: Schultz, A. J.; Williams, J. M.; Schrock, R. R.; Rupprecht, G. A.; Fellmann, J. A. J. Am. Chem. Soc. 1979, 101, 1593.
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