-
1
-
-
61849149889
-
-
Comparison of Aqueous and Non-aqueous Soft-Chemical Syntheses of Lithium Niobate and Lithium Tantalate Powders May Nyman, Travis M. Anderson, Paula P. Provencio Sandia National Laboratories, P.O. Box 5800, Albuquerque, New Mexico 87185 mdnyman@ sandia.gov Lithium niobates and tantalates have a number of characteristics exploitable for optical and electrical devices that include ion conductivity, self-activating or dopant luminescence, piezoelectricity, pyroelectricity and ferroelectricity. To form these materials as nanometric powders or thin-film coatings, soft-chemical processing is required, and a limited number of procedures have been reported. We have explored two soft-chemical routes to lithium niobate and lithium tantalate materials: a non-aqueous procedure and an aqueous procedure. The non-aqueous procedure, which utilizes 1,4-butanediol and simple chemical precursors produces pure phase rhombohedral LiTaO3 and LiNbO3. For aqueous synthesis, we utilize the
-
4. Without LiOH, other phases are observed. The products are characterized by powder X-ray diffraction, scanning electron microscopy, transmission electron microscopy, compositional analysis, and thermogravimetry, and the two soft-chemical processes are compared. © 2009 American Chemical Society.
-
-
-
-
2
-
-
38649097850
-
-
Tsonev, L. Opt. Mater. 2008, 30, 892-899.
-
(2008)
Opt. Mater
, vol.30
, pp. 892-899
-
-
Tsonev, L.1
-
3
-
-
8344251719
-
-
McLaren, V. L.; Kirk, C. A.; Poisot, M.; Castellanos, M.; West, A. R. Dalton Trans. 2004, 3042-3047.
-
(2004)
Dalton Trans
, pp. 3042-3047
-
-
McLaren, V.L.1
Kirk, C.A.2
Poisot, M.3
Castellanos, M.4
West, A.R.5
-
5
-
-
0042376794
-
-
Shishido, T.; Suzuki, H.; Ukei, K.; Hibiya, T.; Fukuda, T. J. Alloys Compd. 1996, 234, 256-259.
-
(1996)
J. Alloys Compd
, vol.234
, pp. 256-259
-
-
Shishido, T.1
Suzuki, H.2
Ukei, K.3
Hibiya, T.4
Fukuda, T.5
-
6
-
-
34547270485
-
-
Zhang, D. L.; Kang, J.; Pun, E. Y. B. J. Mater. Sci. 2007, 42, 4731-4737.
-
(2007)
J. Mater. Sci
, vol.42
, pp. 4731-4737
-
-
Zhang, D.L.1
Kang, J.2
Pun, E.Y.B.3
-
9
-
-
0001039279
-
-
Hsu, R.; Maslen, E. N.; Boulay, D. D.; Ishizawa, N. Acta Crystallogr. 1997, B53, 420-428.
-
(1997)
Acta Crystallogr
, vol.B53
, pp. 420-428
-
-
Hsu, R.1
Maslen, E.N.2
Boulay, D.D.3
Ishizawa, N.4
-
10
-
-
10644292384
-
-
Pitcher, M. W.; He, Y.; Bianconi, P. A. Mater. Chem. Phys. 2005, 90, 57-61.
-
(2005)
Mater. Chem. Phys
, vol.90
, pp. 57-61
-
-
Pitcher, M.W.1
He, Y.2
Bianconi, P.A.3
-
11
-
-
36349013761
-
-
Liu, M.; Xue, D.; Li, K. J. Alloys Compd. 2008, 449, 28-31.
-
(2008)
J. Alloys Compd
, vol.449
, pp. 28-31
-
-
Liu, M.1
Xue, D.2
Li, K.3
-
12
-
-
40749126157
-
-
Van, C.; Zou, L.; Xue, D.; Xu, J.; Liu, M. J. Mater. Sci. 2008, 43, 2263-2269.
-
(2008)
J. Mater. Sci
, vol.43
, pp. 2263-2269
-
-
Van, C.1
Zou, L.2
Xue, D.3
Xu, J.4
Liu, M.5
-
18
-
-
3242767093
-
-
Niederberger, M.; Pinna, N.; Polleux, J.; Antonietti, M. Angew. Chem., Int. Ed. 2004, 43, 2270-2273.
-
(2004)
Angew. Chem., Int. Ed
, vol.43
, pp. 2270-2273
-
-
Niederberger, M.1
Pinna, N.2
Polleux, J.3
Antonietti, M.4
-
19
-
-
0042790512
-
-
Grenier, J. C.; Martin, C.; Durif, A. Bull. Soc. Fr. Mineral. Cristallogr. 1964, 87, 316-320.
-
(1964)
Bull. Soc. Fr. Mineral. Cristallogr
, vol.87
, pp. 316-320
-
-
Grenier, J.C.1
Martin, C.2
Durif, A.3
-
20
-
-
0007572770
-
-
Ukei, K.; Suzuki, H.; Shishido, T.; Fukuda, T. Acta Crystallogr. C 1994, 50, 655-656.
-
(1994)
Acta Crystallogr. C
, vol.50
, pp. 655-656
-
-
Ukei, K.1
Suzuki, H.2
Shishido, T.3
Fukuda, T.4
-
21
-
-
38949197398
-
-
Muthurajan, H.; Kumar, H. H.; Natarajan, N.; Ravi, V. Ceram. Int. 2008, 34, 669-670.
-
(2008)
Ceram. Int
, vol.34
, pp. 669-670
-
-
Muthurajan, H.1
Kumar, H.H.2
Natarajan, N.3
Ravi, V.4
-
23
-
-
34548118362
-
-
Satapathya, S.; Guptaa, P. K.; Srivastavab, H.; Srivastavab, A. K.; Wadhawanc, V. K.; Varmad, K. B. R.; Sathee, V. G. J. Cryst. Growth 2007, 307, 185-191.
-
(2007)
J. Cryst. Growth
, vol.307
, pp. 185-191
-
-
Satapathya, S.1
Guptaa, P.K.2
Srivastavab, H.3
Srivastavab, A.K.4
Wadhawanc, V.K.5
Varmad, K.B.R.6
Sathee, V.G.7
-
25
-
-
25844493142
-
-
Cheng, Z. X.; Kimura, H.; Ozawa, K.; Miyazaki, A.; Kanna, C. V. J. Alloys Compd. 2005, 402, 208-212.
-
(2005)
J. Alloys Compd
, vol.402
, pp. 208-212
-
-
Cheng, Z.X.1
Kimura, H.2
Ozawa, K.3
Miyazaki, A.4
Kanna, C.V.5
-
26
-
-
0030243087
-
-
Allemann, J. A.; Xia, Y.; Morriss, R. E.; Wilkinson, A. P.; Eckert, H.; Speck, J. S.; Levi, C. G.; Lange, F. F.; Anderson, S. J. Mater. Res. 1996, 11, 2376-2387.
-
(1996)
J. Mater. Res
, vol.11
, pp. 2376-2387
-
-
Allemann, J.A.1
Xia, Y.2
Morriss, R.E.3
Wilkinson, A.P.4
Eckert, H.5
Speck, J.S.6
Levi, C.G.7
Lange, F.F.8
Anderson, S.9
-
27
-
-
0022893460
-
-
Kumada, N.; Ozawa, N.; Kinomura, N.; Muto, F. J. Mater. Sci. 1986, 21, 4140-4142.
-
(1986)
J. Mater. Sci
, vol.21
, pp. 4140-4142
-
-
Kumada, N.1
Ozawa, N.2
Kinomura, N.3
Muto, F.4
-
28
-
-
34248362335
-
-
Anderson, T. M.; Rodriguez, M. A.; Bonhomme, F.; Bixler, J.; Alam, T. M.; Nyman, M. Dalton Trans. 2007, 4517-4522.
-
(2007)
Dalton Trans
, pp. 4517-4522
-
-
Anderson, T.M.1
Rodriguez, M.A.2
Bonhomme, F.3
Bixler, J.4
Alam, T.M.5
Nyman, M.6
-
29
-
-
34548206613
-
-
Balogh, E.; Anderson, T. M.; Rustad, J. R.; Nyman, M.; Casey, W. H. Inorg. Chem. 2007, 46, 7032-7039.
-
(2007)
Inorg. Chem
, vol.46
, pp. 7032-7039
-
-
Balogh, E.1
Anderson, T.M.2
Rustad, J.R.3
Nyman, M.4
Casey, W.H.5
-
30
-
-
33751000198
-
-
Black, J. R.; Nyman, M.; Casey, W. H. J. Am. Chem. Soc. 2006, 128, 14712-14720.
-
(2006)
J. Am. Chem. Soc
, vol.128
, pp. 14712-14720
-
-
Black, J.R.1
Nyman, M.2
Casey, W.H.3
-
31
-
-
44649182852
-
-
Wood, I. G.; Daniels, P.; Brown, R. H.; Glazer, A. M. J. Phys., Cond. Matter 2008, 20, 235-237.
-
(2008)
J. Phys., Cond. Matter
, vol.20
, pp. 235-237
-
-
Wood, I.G.1
Daniels, P.2
Brown, R.H.3
Glazer, A.M.4
-
32
-
-
0030230417
-
-
Kawaguchi, T.; Imaeda, M.; Minakata, M.; Taniuchi, T.; Fukuda, T. J. Cryst. Growth 1996, 166, 489-492.
-
(1996)
J. Cryst. Growth
, vol.166
, pp. 489-492
-
-
Kawaguchi, T.1
Imaeda, M.2
Minakata, M.3
Taniuchi, T.4
Fukuda, T.5
-
33
-
-
0032124228
-
-
Kaigawa, K.; Kawaguchi, T.; Imaeda, M.; Sakai, H.; Fukuda, T. J. Cryst. Growth 1998, 191, 119-124.
-
(1998)
J. Cryst. Growth
, vol.191
, pp. 119-124
-
-
Kaigawa, K.1
Kawaguchi, T.2
Imaeda, M.3
Sakai, H.4
Fukuda, T.5
-
34
-
-
33750145148
-
-
Nyman, M.; Alam, T. M.; Bonhomme, F.; Rodriguez, M. A.; Frazer, C. S.; Welk, M. E. J. Cluster Sci. 2006, 17, 197-219.
-
(2006)
J. Cluster Sci
, vol.17
, pp. 197-219
-
-
Nyman, M.1
Alam, T.M.2
Bonhomme, F.3
Rodriguez, M.A.4
Frazer, C.S.5
Welk, M.E.6
-
35
-
-
34247472693
-
-
Anderson, T. M.; Thoma, S. G.; Bonhomme, F.; Rodriguez, M. A.; Park, H.; Parise, J. B.; Alam, T. M.; Larentzos, J. P.; Nyman, M. Cryst. Growth Des. 2007, 7, 719-723.
-
(2007)
Cryst. Growth Des
, vol.7
, pp. 719-723
-
-
Anderson, T.M.1
Thoma, S.G.2
Bonhomme, F.3
Rodriguez, M.A.4
Park, H.5
Parise, J.B.6
Alam, T.M.7
Larentzos, J.P.8
Nyman, M.9
-
36
-
-
31344467216
-
-
Kasuya, R.; Isobe, T.; Kuma, H. J. Alloys Compd. 2006, 408, 820-823.
-
(2006)
J. Alloys Compd
, vol.408
, pp. 820-823
-
-
Kasuya, R.1
Isobe, T.2
Kuma, H.3
-
37
-
-
40849105197
-
-
Kubo, K.; Hosokawa, S.; Furukawa, S.; Iwamoto, S.; Inoue, M. J. Mater. Sci. 2008, 43, 2198-2205.
-
(2008)
J. Mater. Sci
, vol.43
, pp. 2198-2205
-
-
Kubo, K.1
Hosokawa, S.2
Furukawa, S.3
Iwamoto, S.4
Inoue, M.5
-
38
-
-
39749104673
-
-
Bell, N. S.; Tallant, D. R.; Raymond, R.; Boyle, T. J. J. Mater. Res. 2008, 23, 529-535.
-
(2008)
J. Mater. Res
, vol.23
, pp. 529-535
-
-
Bell, N.S.1
Tallant, D.R.2
Raymond, R.3
Boyle, T.J.4
-
39
-
-
34547350026
-
-
Cho, S. B.; Noh, J. S.; Park, S. J.; Lim, D. Y.; Choi, S. H. J. Mater. Sci. 2007, 42, 4877-4886.
-
(2007)
J. Mater. Sci
, vol.42
, pp. 4877-4886
-
-
Cho, S.B.1
Noh, J.S.2
Park, S.J.3
Lim, D.Y.4
Choi, S.H.5
-
40
-
-
0038900509
-
-
Archer, L.; Hampden-Smith, M. J.; Duesler, E. Polyhedron 1998, 17, 713-723.
-
(1998)
Polyhedron
, vol.17
, pp. 713-723
-
-
Archer, L.1
Hampden-Smith, M.J.2
Duesler, E.3
-
41
-
-
33644545994
-
-
Zhu, H. Y.; Zheng, Z. F.; Gao, X. P.; Huang, Y. N.; Yan, Z. M.; Zou, J.; Yin, H. M.; Zou, Q. D.; Kable, S. H.; Zhao, J. C.; Xi, Y. F.; Martens, W. N.; Frost, R. L. J. Am. Chem. Soc. 2006, 128, 2373-2384.
-
(2006)
J. Am. Chem. Soc
, vol.128
, pp. 2373-2384
-
-
Zhu, H.Y.1
Zheng, Z.F.2
Gao, X.P.3
Huang, Y.N.4
Yan, Z.M.5
Zou, J.6
Yin, H.M.7
Zou, Q.D.8
Kable, S.H.9
Zhao, J.C.10
Xi, Y.F.11
Martens, W.N.12
Frost, R.L.13
-
42
-
-
0038337733
-
-
Goh, G. K. L.; Lange, F. F.; Haile, S. M.; Levi, C. G. J. Mater. Res. 2003, 18, 338-345.
-
(2003)
J. Mater. Res
, vol.18
, pp. 338-345
-
-
Goh, G.K.L.1
Lange, F.F.2
Haile, S.M.3
Levi, C.G.4
-
43
-
-
0036715470
-
-
Santos, I. C.M.S.; Loureiro, L. H.; MFP, M. F. P. S.; Cavaleiro, A. M. V. Polyhedron 2002, 21, 2009-2015.
-
(2002)
Polyhedron
, vol.21
, pp. 2009-2015
-
-
Santos, I.C.M.S.1
Loureiro, L.H.2
MFP, M.F.P.S.3
Cavaleiro, A.M.V.4
-
44
-
-
0037047620
-
-
Nyman, M.; Bonhomme, F.; Alam, T. M.; Rodriguez, M. A.; Cherry, B. R.; Krumhansl, J. L.; Nenoff, T. M.; Sattler, A. M. Science 2002, 297, 996-998.
-
(2002)
Science
, vol.297
, pp. 996-998
-
-
Nyman, M.1
Bonhomme, F.2
Alam, T.M.3
Rodriguez, M.A.4
Cherry, B.R.5
Krumhansl, J.L.6
Nenoff, T.M.7
Sattler, A.M.8
-
45
-
-
2442713984
-
-
Xu, H.; Nyman, M.; Nenoff, T. M.; Navrotsky, A. Chem. Mater. 2004, 16, 2034-2040.
-
(2004)
Chem. Mater
, vol.16
, pp. 2034-2040
-
-
Xu, H.1
Nyman, M.2
Nenoff, T.M.3
Navrotsky, A.4
-
46
-
-
3242694308
-
-
Nyman, M.; Bonhomme, F.; Alam, T. M.; Parise, J. B.; Vaughan, G. M. B. Angew. Chem., Int. Ed. 2004, 43, 2787-2792.
-
(2004)
Angew. Chem., Int. Ed
, vol.43
, pp. 2787-2792
-
-
Nyman, M.1
Bonhomme, F.2
Alam, T.M.3
Parise, J.B.4
Vaughan, G.M.B.5
-
47
-
-
23944494435
-
-
Bonhomme, F.; Larentzos, J. P.; Alam, T. M.; Maginn, E. J.; Nyman, M. Inorg. Chem. 2005, 44, 1774-1785.
-
(2005)
Inorg. Chem
, vol.44
, pp. 1774-1785
-
-
Bonhomme, F.1
Larentzos, J.P.2
Alam, T.M.3
Maginn, E.J.4
Nyman, M.5
|