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Volumn 21, Issue 1, 2009, Pages 12-14

A polar and chiral indium telluride featuring supertetrahedral T2 clusters and nonlinear optical second harmonic generation

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION EDGES; ADAMANTANE; ADJACENT LAYERS; CHIRAL COMPOUNDS; INDIUM TELLURIDES; NOMINAL COMPOSITIONS; NON-LINEAR OPTICAL; SINGLE-CRYSTAL X-RAY DIFFRACTIONS; TE COMPOUNDS; TOTAL CHARGES; UV-VIS ABSORPTIONS; X-RAY DIFFRACTOMETERS; ZINTL PHASE;

EID: 61849109202     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm8027516     Document Type: Article
Times cited : (102)

References (76)
  • 7
  • 43
    • 0004173148 scopus 로고
    • Janz, G. J, Ed, Academic Press: New York
    • (b) Janz, G. J., Ed. Molten Salts Handbook; Academic Press: New York, 1967.
    • (1967) Molten Salts Handbook
  • 47
    • 61849121667 scopus 로고    scopus 로고
    • Smith, D. M.; Ibers, J. A Coord. Chem. Rev. 2000, 187, 200-202.
    • (b) Smith, D. M.; Ibers, J. A Coord. Chem. Rev. 2000, 187, 200-202.
  • 70
    • 84868908737 scopus 로고    scopus 로고
    • Single-crystal X-ray diffraction data were collected at 100 K using a STOE imaging-plate diffraction system (IPSD-2) with graphite-monochromatized Mo Kα radiation. A numerical absorption correction was applied using the X-RED program set. Direct methods and full-matrix least-squares refinements against F2 were performed with SHEIXΓL package. Crystal data for, In(en)3][In5Te9(en) 2].0.5en}n(1, Hexagonal P61, Z=6, a, b, 11.6147(2) A, c, 51.9135(15) Å, γ, 120°, V, 6064.9(2) Å3, 2θmax (Mo Kα, 46.58°, Dcalcd, 3.512 g/cm3, μ, 9.750 mm -3, total reflections, 3777, unique reflections [F ο2 > 2σ (Fο 2, 3399, parameters, 217, GOF, 1.169, R1, 7.72% and wR2, 17.35% for I > 2σI, Bec
    • 2)] = 3399, parameters = 217, GOF = 1.169, R1 = 7.72% and wR2 = 17.35% for I > 2σ(I). Because of the disorder of the free en molecules, it was impossible to locate them in the final structural refinement and this accounts for the relatively high R1 value.
  • 71
    • 61849087165 scopus 로고    scopus 로고
    • EDS analysis: the calculated ratio for In and Te is 2:3 and the result from EDS is 39.65:60.28.
    • EDS analysis: the calculated ratio for In and Te is 2:3 and the result from EDS is 39.65:60.28.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.