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-1): 3073(m), 2920(m), 2771(m), 1594(m) 1497(s), 1376(s), 1313(s), 761(s), 687(m), 566(m).
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-1): 3073(m), 2920(m), 2771(m), 1594(m) 1497(s), 1376(s), 1313(s), 761(s), 687(m), 566(m).
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27
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61849125444
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-1, S = 1.068, Rl = 0.0374, wR2 = 0.1053. Considering the long distance of Cul and II, ca. 3.12 Å, we infer that there is no interaction between them.
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-1, S = 1.068, Rl = 0.0374, wR2 = 0.1053. Considering the long distance of Cul and II, ca. 3.12 Å, we infer that there is no interaction between them.
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28
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61849115877
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It is distinct that there are two different coordination modes of the ligand in 1. As judged by the distance of C1, SI atoms [1.668 (4) Å, distinctly shorter in comparison to the C8-S2 single bond length 1.717(4) Å] and the conservation of electroneutrality of the component molecule, the CI-SI bond is a double covalent bond and proton transfer from SI to Nl has occurred. Thus, the monodentate ligand possessing a SI atom is electrically neutral, which is marked with Hptt, and the ptt anion ligand containing μ-S (S2) is represented as pit
-
It is distinct that there are two different coordination modes of the ligand in 1. As judged by the distance of C1...SI atoms [1.668 (4) Å, distinctly shorter in comparison to the C8-S2 single bond length 1.717(4) Å] and the conservation of electroneutrality of the component molecule, the CI-SI bond is a double covalent bond and proton transfer from SI to Nl has occurred. Thus, the monodentate ligand possessing a SI atom is electrically neutral, which is marked with Hptt, and the ptt anion ligand containing μ-S (S2) is represented as pit.
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