A practical method to access enantiopure β-perfluoroalkyl-β-amino acids: diastereoselective reduction of cyclic enamino-esters

Tetrahedron Letters

Volumn 50, Issue 17, 2009, Pages 1889-1892

  Ishida, Yasuhiro ^a   Iwahashi, Nobutaka ^a   Nishizono, Nao ^a   Saigo, Kazuhiko ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

2 AMINO 2 PHENYLETHANOL; 3 AMINO 4,4,4 TRIFLUOROBUTANOIC ACID; 4,4,4 TRIFLUORO 3 OXOBUTANOATE; AMINO ACID DERIVATIVE; BETA PERFLUOROALKY BETA AMINO ACID DERIVATIVE; BUTYRIC ACID; ESTER DERIVATIVE; PHENETHYL ALCOHOL; UNCLASSIFIED DRUG;

ARTICLE; CRYSTAL STRUCTURE; DRUG STRUCTURE; DRUG SYNTHESIS; STEREOCHEMISTRY; TRANSESTERIFICATION; X RAY CRYSTALLOGRAPHY;

TRIFLUORO;

EID: 61749093481     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2009.01.159     Document Type: Article

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38. As far as we know (S)-6 and (3S,5S)-7 have been deposited with the Cambridge Crystallographic Data Center as Supplementary Publication Numbers CCDC 709483 and CCDC 709484, respectively. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, by emailing data_request@ccdc.cam.ac.uk, or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.
39. The cyclic enamino-ester (S)-10 was prepared from an easily available fluorinated building block (ethyl 4,4,5,5,5-pentafluoroethylpent-1-ynoate). See Ref. 11.