Thiol-yne photopolymerizations: Novel mechanism, kinetics, and step-growth formation of highly cross-linked networks

Macromolecules

Volumn 42, Issue 1, 2009, Pages 211-217

  Fairbanks, Benjamin D ^a   Scott, Timothy F ^a   Kloxin, Christopher J ^a   Anseth, Kristi S ^a,b   Bowman, Christopher N ^a  

^a UCB 450   (United States)

^b UNIVERSITY OF COLORADO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIMOLECULAR REACTIONS; CHAIN TRANSFERS; CHAIN-GROWTH POLYMERIZATIONS; CONSECUTIVE REACTIONS; CROSS-LINK DENSITIES; CROSS-LINKED NETWORKS; CROSS-LINKED POLYMERS; DIFUNCTIONAL; FIRST-ORDER DEPENDENCES; GLASS TRANSITION TEMPERATURES; INITIATION RATES; PHYSICAL AND CHEMICAL PROPERTIES; POLYMERIZATION RATES; POST POLYMERIZATIONS; RATE-DETERMINING STEPS; REACTION MECHANISMS; REACTIVE GROUPS; SQUARE-ROOT DEPENDENCES; THIOL FUNCTIONAL GROUPS; THIOL-ENE; THIOL-ENE PHOTOPOLYMERIZATION; THIYL RADICALS; VINYL FUNCTIONALITIES;

ACETYLENE; CHEMICAL MODIFICATION; CHEMICAL PROPERTIES; CROSSLINKING; FORMING; FUNCTIONAL GROUPS; FUNCTIONAL POLYMERS; GLASS TRANSITION; GROWTH KINETICS; MONOMERS; PHOTOPOLYMERIZATION; POLYMERS; RESINS;

FREE RADICAL POLYMERIZATION;

EID: 61649106062     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma801903w     Document Type: Article

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