Thiol - Ene Photopolymerization Mechanism and Rate Limiting Step Changes for Various Vinyl Functional Group Chemistries

Macromolecules

Volumn 36, Issue 21, 2003, Pages 7964-7969

  Cramer, Neil B ^a   Reddy, Sirish K ^a   O'Brien, Allison K ^a   Bowman, Christopher N ^a,b  

^a UCB 450   (United States)

^b UNIVERSITY OF COLORADO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; CONCENTRATION (PROCESS); FREE RADICALS; MONOMERS; REACTION KINETICS;

FUNCTIONAL GROUP CHEMISTRIES;

PHOTOPOLYMERIZATION;

EID: 0142153882     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma034667s     Document Type: Article

References (36)

1. Morgan, C. R.; Magnotta, F.; Ketley, A. D. J. Polym. Sci., A, Polym. Chem 1977, 627.
2. Jacobine, A. F. In Radiation Curing in Polymer Science and Technology III, Polymerisation Mechanisms; Fouassier, J. D., Rabek, J. F., Eds.; Elsevier Applied Science: London, 1993; Vol. 3, p 219.
3. Bor-Sen, C.; Saad, A. K. Macromolecules 1997, 30, 7322.
4. Woods, J. G. In Radiation Curable Adhesives in Radiation Curing: Science and Technology; Pappas, S. P., Ed.; Plenum Press: New York, 1992; p 333.
5. Bor-Sen C.; Saad, A. K. In Photopolymerization Fundamentals and Applications; Scranton, A., Bowman, C., Peiffer, R., Ed.; ACS Symposium Series 673; American Chemical Society: Washington, DC, 1996; p 150.
6. Gush, D. P.; Ketley, A. D. Mod. Paint Coat 1978, 58.
7. Kharasch, M. S.; Nudenberg, W.; Mantell, G. J. J. Org. Chem. 1951, 16, 524.
8. Cramer, N. B.; Scott, J. P.; Bowman, C. N. Macromolecules 2002, 35, 5361.
9. Kharasch, M. S.; Read, J.; Mayo, F. R. Chem. Ind. (London) 1938, 57, 752.
10. Muller, U.; Kunze, A. J. Macromol. Sci. - Pure Appl. Chem. 1996, A35(4), 439.
11. Davis F. D.; Fettes, E. M. Polyethers, Part III; Gaylord, N. G.; Ed.; Interscience: New York, N. Y., 1962.
12. Oswald, A. A.; Noel, P.; Stephenson, A. J. J. Org. Chem. 1961, 26, 3969.
13. Cristol, S. J.; Brindell, G. D. In Organic Sulfur Compounds, Kharasch, N., Ed.; Pergamon Press: New York, 1961; Vol. 1, p627.
14. Marvel, C. S.; Chambers, R. R. J. Am. Chem. Soc. 1949, 70, 993.
15. Marvel, C. S.; Aldrich, P. H. J. Am. Chem. Soc. 1950, 72, 1978.
16. Marvel, C. S.; Caesar, P. D. J. Am. Chem. Soc. 1951, 73, 1097.
17. Hoyle, C. E.; Hensel, R. D.; Grubb, M. B. J. Polym. Sci., A, Polym. Chem 1984, 22, 1865.
18. D'Souza, V. T.; Nanjundiah, R.; Baeza, J.; Szmant, H. H. J. Org. Chem. 1987, 52, 1720.
19. Chung, M. I.; D'Souza, V. T.; Szmant, H. H. J. Org. Chem. 1987, 52, 1741.
20. D'Souza, V. T.; Iyer, V. K.; Szmant, H. H. J. Org. Chem. 1987, 52, 1725.
21. D'Souza, V. T.; Nanjundiah, R.; Baeza, J.; Szmant, H. H. J. Org. Chem. 1987, 52, 1729.
22. Cramer, N. B.; Bowman, C. N. J. Polym. Sci., A, Polym. Chem 2001, 39, 3311.
23. Lecamp, L.; Houllier, F.; Youssef, B.; Bunel, C. Polymer 2001, 42, 2727.
24. Hoyle, C.; Cole, M.; Bachemin, M.; Yoder, B.; Nguyen, C.; Kuang, W.; Bowman, C.; Cramer, N.; Jonsson, S.; Viswanathan, K. RadTech Japan 2000 Technical Proceedings; Tokyo, Japan, Dec. 2000, p 211.
25. Cramer, N. B.; Beckel, E. R.; Harant, A. W.; Davies, T.; Bowman, C. N. Liq. Cryst. 2002, 29, 1291.
26. Beckel, E. R.; Cramer, N. B.; Harant, A. W.; Bowman, C. N. Chem. Mater., in press.
27. Broer, D. J.; van Haaren, J. A. M. M.; van de Witte, P.; Bastiaansen, C. Macromol. Symp. 2000, 154, 1.
28. Wilderbeek, H. T. A.; Goossenst, J. G. P.; Bastiaansen, C. W. M.; Broer, D. J. Macromolecules 2002, 35, 8962.
29. Szmant, H. H.; Mata, A. J.; Namis, A. J.; Panthananickal, A. M. Tetrahedron 1976, 32, 2665.
30. Sensfuss, S.; Friedrich, M.; Klemm, E. Makromol. Chem. 1991, 192, 2895.
31. Cramer, N. B.; Davies, T.; O'Brien, A. K.; Bowman, C. N. Macromolecules, in press.
32. Lovestead, T. M.; Berchtold, K. A.; Bowman, C. N. Macromol. Theory Simul. 2002, 11, 729.
33. Odian, G. Principles of Polymerization; John Wiley & Sons: New York, 1991.
34. Lovell, L. G.; Berchtold, K. A.; Elliott, J. E.; Lu, H.; Bowman, C. N. Polym. Adv. Technol 2001, 12, 335.
35. Anseth, K. S.; Bowman, C. N. Polym. React. Eng. 1992-93, 1, 499.
36. Berchtold, K. A.; Hacioglu, B.: Lovell, L.; Nie, J.; Bowman, C. N. Macromolecules 2001, 34, 5103.