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For a recent summary, see
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For a recent summary, see: Walz, A. J.; Möllmann, U.; Miller, M. J. Org. Biomol. Chem. 2007, 5, 1621.
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Walz, A.J.1
Möllmann, U.2
Miller, M.J.3
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3
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0000185012
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Wittman, M. D.; Halcomb, R. L.; Danishefsky, S. J. J. Org. Chem. 1990, 55, 1981.
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J. Org. Chem
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Wittman, M.D.1
Halcomb, R.L.2
Danishefsky, S.J.3
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6
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84945052504
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Zhang, Y.; Xu, G. Z. Naturforsch., B: Chem. Sci. 1989, 44, 1475.
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Z. Naturforsch., B: Chem. Sci
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Zhang, Y.1
Xu, G.2
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7
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49549150547
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For an early example, see
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For an early example, see: Połoński, T.; Chimiak, A. Tetrahedron Lett. 1974, 28, 2453.
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(1974)
Tetrahedron Lett
, vol.28
, pp. 2453
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Połoński, T.1
Chimiak, A.2
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11
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0036859486
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For the description of a large-scale preparation of a nitrone via the oxidation of a secondary amine with m-CPBA, see: Stappers, F.; Broeckx, R.; Leurs, S.; Van Den Bergh, L.; Agten, J.; Lambrechts, A.; Van den Heuvel, D.; De Smaele, D. Org. Process. Res. Dev. 2002, 6, 911. It is interesting to note that this oxidation presumably goes via the intermediacy of a hydroxylamine.
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For the description of a large-scale preparation of a nitrone via the oxidation of a secondary amine with m-CPBA, see: Stappers, F.; Broeckx, R.; Leurs, S.; Van Den Bergh, L.; Agten, J.; Lambrechts, A.; Van den Heuvel, D.; De Smaele, D. Org. Process. Res. Dev. 2002, 6, 911. It is interesting to note that this oxidation presumably goes via the intermediacy of a hydroxylamine.
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14
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61449133435
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Amano, A.; Fukuyama, T.; Kuboyama, T.; Tokuyama, H.; Yamashita, T, Synthesis 2000, 1299.
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Synthesis
, pp. 1299
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Amano, A.1
Fukuyama, T.2
Kuboyama, T.3
Tokuyama, H.4
Yamashita, T.5
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85026878359
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Fukuyama, T.; Kuboyama, T.; Tokuyama, H. Org. Synlh. 2003, 80, 207.
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Org. Synlh
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Fukuyama, T.1
Kuboyama, T.2
Tokuyama, H.3
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16
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61449172302
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Urben, P. G, Ed, 6th ed; Butterworth-Heinemann: Oxford, UK
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Urben, P. G., Ed.; Bretherick's Handbook of Reactive Chemical Hazards, 6th ed; Butterworth-Heinemann: Oxford, UK, 1999; Vol. 1, pp 1662-1664.
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(1999)
Bretherick's Handbook of Reactive Chemical Hazards
, vol.1
, pp. 1662-1664
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17
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61449178186
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For an example of a process using m-CPBA in EtOAc for the oxidation of a sulfide to a sulfoxide, see: Milač, N. H, Jereb D, U.S. Patent 6,268,502, 2001
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For an example of a process using m-CPBA in EtOAc for the oxidation of a sulfide to a sulfoxide, see: Milač, N. H.; Jereb D, U.S. Patent 6,268,502, 2001.
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18
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0347996091
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For use of m-CPBA as a solution in EtOH and associated discussion, see: Prasad, J. S.; Vu, T.; Totleben, M. J.; Crispino, G. A.; Kacsur, D. J.; Swaminathan, S.; Thornton, J. E.; Fritz, A.; Singh, A. K. Org. Process Res. Dev. 2003, 7, 821.
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For use of m-CPBA as a solution in EtOH and associated discussion, see: Prasad, J. S.; Vu, T.; Totleben, M. J.; Crispino, G. A.; Kacsur, D. J.; Swaminathan, S.; Thornton, J. E.; Fritz, A.; Singh, A. K. Org. Process Res. Dev. 2003, 7, 821.
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20
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61449160461
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Proton and carbon NMR analysis after 5 years storage at room temperature showed no discernable degradation.
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Proton and carbon NMR analysis after 5 years storage at room temperature showed no discernable degradation.
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21
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61449245825
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Patel, I.; Smith, N.; Tyler, S. N. G. PCT Int. Appl. WO 2008/029090, 2008.
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Patel, I.; Smith, N.; Tyler, S. N. G. PCT Int. Appl. WO 2008/029090, 2008.
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