Oxygen diffusion in cross-linked, ethanol-swollen poly (vinyl alcohol) gels: Counter-intuitive results reflect microscopic heterogeneities

Langmuir

Volumn 25, Issue 2, 2009, Pages 1148-1153

  Schack, Nickolass Bitsch ^a,b   Oliveira, Cristiano L P ^b   Young, Niall W G ^c,d   Pedersen, Jan Skov ^b   Ogilby, Peter R ^a,b  

^a Center for Oxygen Microscopy and Imaging   (Denmark)

^b AARHUS UNIVERSITY   (Denmark)

^c DANISCO A S   (Denmark)

^d UNIVERSITY OF CHESTER   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDES; CELL DEATH; DIFFUSION IN GASES; ETHANOL; GELATION; GELS; REAL TIME SYSTEMS; SORPTION; X RAY SCATTERING;

BIOLOGICAL CELLS; CROSS-LINKING REACTIONS; DIFFUSION COEFFICIENTS; EXTENT OF CROSS-LINKING; FLUID DOMAINS; GLUTARALDEHYDE; OXYGEN DIFFUSION COEFFICIENTS; OXYGEN DIFFUSIONS; PHOTO-INDUCED; POLYVINYL ALCOHOL GELS; SEGMENTAL MOTIONS; SINGLET OXYGENS; SMALL - ANGLE X-RAY SCATTERINGS; SMALL MOLECULES;

OXYGEN;

ALCOHOL; GLUTARALDEHYDE; OXYGEN; POLYVINYL ALCOHOL;

ADSORPTION; ARTICLE; CHEMISTRY; DIFFUSION; FLOW KINETICS; GEL; SMALL ANGLE SCATTERING; SURFACE PROPERTY; X RAY DIFFRACTION;

ADSORPTION; DIFFUSION; ETHANOL; GELS; GLUTARAL; OXYGEN; POLYVINYL ALCOHOL; RHEOLOGY; SCATTERING, SMALL ANGLE; SURFACE PROPERTIES; X-RAY DIFFRACTION;

EID: 60849088589     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la803024h     Document Type: Article

References (43)

1. Korsmeyer, R. W.; Peppas, N. A. J. Membr. Sci. 1981, 9, 211-227.
2. Matsuyama, H.; Teramoto, M.; Urano, H. J. Membr. Sci. 1997, 126, 151-160.
3. van Stroe-Biezen, S. A. M.; Everaerts, F. M; Janssen, L. J. J.; Tacken, R. A. Anal. Chim. Acta 1993, 273, 553-560.
4. Kubin, M.; Spacek, P. Collect. Czech. Chem. Commun. 1965, 30, 3294-3302.
5. Higuchi, A.; Fushimi, H.; Iijima, T. J. Membr. Sci. 1985, 25, 171-180.
6. Manetti, C.; Casciani, L.; Pescosolido, N. Polymer 2002, 43, 87-92.
7. Parker, J. W.; Cox, M. E. J. Polym. Sci., Part A: Polym. Chem. 1988, 26, 1179-1188.
8. Simon-Lukasik, K. V.; Ludescher, R. D. Food Hydrocolloids 2004, 18, 621-630.
9. Compañ, V.; Tiemblo, P.; Garcia, F.; Garcia, J. M.; Guzman, J.; Riande, E. Biomaterials 2005, 26, 3783-3791.
10. Peppas, N. A.; Hilt, J. Z.; Khademhosseini, A.; Langer, R. Adv. Mater. 2006, 18, 1345-1360.
11. Drury, J. L.; Mooney, D. J. Biomaterials 2003, 24, 4337-4351.
12. Richter, A.; Paschew, G.; Klatt, S.; Lienig, J.; Arndt, K.-F.; Adler, H.-J. P. Sensors 2008, 8, 561-581.
13. Wolfbeis, O. S.; Oehme, I.; Papkovskaya, N.; Klimant, 1. Biosens. Bioelectron. 2000, 15, 69-76.
14. Neogi, P., Ed. Diffusion in Polymers; Marcel Dekker, Inc.: New York, 1996.
15. Paul, D. R., Yampol'skii, Y. P., Eds. Polymeric Gas Separation Membranes; CRC Press: Boca Raton, FL, 1994.
16. Lane, N. Oxygen: The molecule that made the world.; Oxford University Press: Oxford, 2002.
17. Sawyer, D. T. Oxygen Chemistry; Oxford University Press: New York, 1991.
18. Koros, W. J., Ed. Barrier Polymers and Structures; ACS Symposium Series; American Chemical Society: Washington, D.C., 1990; Vol. 423.
19. Breitenbach, T.; Kuimova, M. K.; Gbur, P.; Hatz, S.; Schack, N. B.; Pedersen, B. W.; Lambert, J. D. C; Poulsen, L.; Ogilby, P. R. Photochem. Photobiol. Sci., published online Sept 23, http://dx.doi.org/10.1039/ B809049A.
20. Hatz, S.; Poulsen, L.; Ogilby, P. R. Photochem. Photobiol. 2008, 84, 1284-1290.
21. Lukasik, K. V.; Ludescher, R. D. Food Hydrocolloids 2006, 20,96-105.
22. Gao, Y.; Ogilby, P. R. Macromolecules 1992, 25, 4962-4966.
23. Gao, Y.; Baca, A. M; Wang, B.; Ogilby, P. R. Macromolecules 1994, 27, 7041-7048.
24. Wang, B.; Ogilby, P. R. Can. J. Chem. 1995, 73, 1831-1840.
25. Poulsen, L.; Zebger, I.; Klinger, M.; Eldrup, M.; Sommer-Larsen, P.; Ogilby, P. R. Macromolecules 2003, 36, 7189-7198.
26. Poulsen, L.; Zebger, I.; Tofte, P.; Klinger, M.; Hassager, O.; Ogilby, P. R. J. Phys. Chem. B 2003, 107, 13885-13891.
27. Crank, J. The; Mathematics of Diffusion, 2nd ed.; Oxford Press: Oxford, 1975.
28. Frederiksen,P. K.; Mcllroy,S.P.; Nielsen,C.B.; Nikolajsen,L.; Skovsen, E.; Jørgensen, M.; Mikkelsen, K. V.; Ogilby, P. R. J. Am. Chem. Soc. 2005, 127, 255-269.
29. Pauly, S. In Polymer Handbook, 4th ed; Brandrup, J., Immergut, E. H., Grulke, E. A., Eds.; John Wiley and Sons: Hoboken, NJ, 1999; Vol. 2, pp 543-569.
30. Ware, W. R. J. Phys. Chem. 1962, 66, 455-458.
31. Sada, E.; Kito, S.; Oda, T.; Ito, Y. Chem. Eng. J. 1975, 10, 155-159.
32. Akgerman, A.; Gainer, J. L. Ind. Eng. Chem. Fundam. 1972, 11, 373-379.
33. Bird, R. B.; Stewart, W. E.; Lightfoot, E. N. Transport Phenomena; 2nd ed.; John Wiley and Sons: New York, 2002.
34. Munk, P. Introduction to Macromolecular Science; John Wiley and Sons: New York, 1989.
35. Almdal, K.; Dyre, J.; Hvidt, S.; Kramer, O. Polym. Gels Networks 1993, 1, 5-17.
36. Terech, P.; Weiss, R. G. Chem. Rev. 1997, 97, 3133-3159.
37. Müller-Plathe, F.; van Gunsteren, W. F. Polymer 1997, 38, 2259-2268.
38. Geissler, E.; Hecht, A. M.; Rochas, C; Horkay, F.; Basser, P. J. Macromol. Symp. 2005, 227, 27-37.
39. Falcao, A. N.; Pedersen, J. S.; Mortensen, K. Macromolecules 1993, 26, 5350-5364.
40. Falcao, A. N.; Pedersen, J. S.; Mortensen, K.; Boue, F. Macromolecules 1996, 29, 809-818.
41. Bunger, M. H.; Foss, M.; Erlacher, K.; Hovgaard, M. B.; Chevallier, J.; Langdahl, B.; Bunger, C; Birkedal, H.; Besenbacher, F.; Pedersen, J. S. Bone 2006, 39, 530-541.
42. Cañete, M.; Lapeña, M.; Juarranz, A.; Vendrell, V.; Borrell, J. I.; Teixidó, J.; Nonell, S.; Villanueva, A. Anti-Cancer Drug Des. 1997, 12, 543-554.
43. Pedersen, J. S. J. Appl. Crystallogr. 2004, 37, 369-380.