A five-coordinate homoleptic organotitanium(III) compound

Angewandte Chemie - International Edition

Volumn 43, Issue 39, 2004, Pages 5225-5228

  Alonso, Pablo J ^a   Falvello, Larry R ^a   Forniés, Juan ^a   García Monforte, M Angeles ^a   Menjón, Babil ^a  

^a UNIVERSITY OF ZARAGOZA   (Spain)

Author keywords

EPR spectroscopy; Fluorinated ligands; Homoleptic compounds; Metal carbon bonds; Titanium

Indexed keywords

COMPLEXATION; COORDINATION REACTIONS; LOW TEMPERATURE OPERATIONS; NEGATIVE IONS; PARAMAGNETISM; ROTATION; TITANIUM COMPOUNDS;

HOMOLEPTIC ORGANOTITANIUM(III) COMPOUNDS; LOW TEMPERATURE REACTIONS; REVERSED BERRY PSEUDOROTATION METHOD; TRIGONAL-BIPYRAMIDAL GEOMETRY;

ORGANOMETALLICS;

COORDINATION COMPOUND; ORGANOMETALLIC COMPOUND; TITANIUM DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; STEREOCHEMISTRY; STRUCTURE ANALYSIS;

EID: 6044276842     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200460111     Document Type: Article

References (43)

1. P. J. Davidson, M. F. Lappert, R. Pearce, Chem. Rev. 1976, 76, 219.
2. H. Rau, J. Müller, Z. Anorg. Allg. Chem. 1975, 415, 225; J. Müller, H. Rau, P. Zdunneck, K.-H. Thiele, Z. Anorg. Allg. Chem. 1973, 401, 113; K.-H. Thiele, K. Milowski, P. Zdunneck, J. Müller, H. Rau, Z. Chem. 1972, 12, 186.
3. H. Rau, J. Müller, Z. Anorg. Allg. Chem. 1975, 415, 225; J. Müller, H. Rau, P. Zdunneck, K.-H. Thiele, Z. Anorg. Allg. Chem. 1973, 401, 113; K.-H. Thiele, K. Milowski, P. Zdunneck, J. Müller, H. Rau, Z. Chem. 1972, 12, 186.
4. H. Rau, J. Müller, Z. Anorg. Allg. Chem. 1975, 415, 225; J. Müller, H. Rau, P. Zdunneck, K.-H. Thiele, Z. Anorg. Allg. Chem. 1973, 401, 113; K.-H. Thiele, K. Milowski, P. Zdunneck, J. Müller, H. Rau, Z. Chem. 1972, 12, 186.
5. S. Kleinhenz, K. Seppelt, Chem. Eur. J. 1999, 5, 3573.
6. M. W. Bouwkamp, J. de Wolf, I. del Hierro Morales, J. Gercama, A. Meetsma, S. I. Troyanov, B. Hessen, J. H. Teuben, J. Am. Chem. Soc. 2002, 124, 12956.
7. R. A. Forder, K. Prout, Acta Crystallogr. Sect. B 1974, 30, 491; F. W. Siegert, H. J. de Liefde Meijer, J. Organomet. Chem. 1969, 20, 141; E. O. Fischer, A. Löchner, Z. Naturforsch. B 1960, 15, 266.
8. R. A. Forder, K. Prout, Acta Crystallogr. Sect. B 1974, 30, 491; F. W. Siegert, H. J. de Liefde Meijer, J. Organomet. Chem. 1969, 20, 141; E. O. Fischer, A. Löchner, Z. Naturforsch. B 1960, 15, 266.
9. R. A. Forder, K. Prout, Acta Crystallogr. Sect. B 1974, 30, 491; F. W. Siegert, H. J. de Liefde Meijer, J. Organomet. Chem. 1969, 20, 141; E. O. Fischer, A. Löchner, Z. Naturforsch. B 1960, 15, 266.
10. G. K. Barker, M. F. Lappert, J. A. K. Howard, J. Chem. Soc. Dalton Trans. 1978, 734; G. K. Barker, M. F. Lappert, J. Organomet. Chem. 1974, 76, C45.
11. G. K. Barker, M. F. Lappert, J. A. K. Howard, J. Chem. Soc. Dalton Trans. 1978, 734; G. K. Barker, M. F. Lappert, J. Organomet. Chem. 1974, 76, C45.
12. a) I. Ara, J. Forniés, M. A. García-Monforte, A. Martín, B. Menjón, Chem. Eur. J. 2004, 10, 4186;
13. b) P. J. Alonso, J. Forniés, M. A. García-Monforte, A. Martín, B. Menjón, Chem. Commun. 2002, 728.
14. R. Usón, J. Forniés, Adv. Organomet. Chem. 1988, 28, 219; E. Maslowsky, Jr., Vibrational Spectra of Organometallic Compounds, Wiley, New York, 1977, pp. 437-442.
15. R. Usón, J. Forniés, Adv. Organomet. Chem. 1988, 28, 219; E. Maslowsky, Jr., Vibrational Spectra of Organometallic Compounds, Wiley, New York, 1977, pp. 437-442.
16. A. R. Rossi, R. Hoffmann, Inorg. Chem. 1975, 14, 365.
17. S. Alvarez, M. Llunell, J. Chem. Soc. Dalton Trans. 2000, 3288.
18. T. R. Ward, H.-B. Bürgi, F. Gilardoni, J. Weber, J. Am. Chem. Soc. 1997, 119, 11974.
19. R. R. Holmes, Prog. Inorg. Chem. 1984, 32, 119; see also ref. [10].
20. J. Zemann, Z. Anorg. Allg. Chem. 1963, 324, 241; see also H. K. McDowell, H. L. Chiu, J. F. Geldard, Inorg. Chem. 1988, 27, 1674.
21. J. Zemann, Z. Anorg. Allg. Chem. 1963, 324, 241; see also H. K. McDowell, H. L. Chiu, J. F. Geldard, Inorg. Chem. 1988, 27, 1674.
22. R. R. Holmes, J. Am. Chem. Soc. 1984, 106, 3745; see also ref. [9].
23. H. A. Jahn, E. Teller, Proc. R. Soc. London Ser. A 1937, 161, 220.
24. M. Kaupp, Angew. Chem. 2001, 113, 3642; Angew. Chem. Int. Ed. 2001, 40, 3535.
25. M. Kaupp, Angew. Chem. 2001, 113, 3642; Angew. Chem. Int. Ed. 2001, 40, 3535.
26. S. K. Kang, H. Tang, T. A. Albright, J. Am. Chem. Soc. 1993, 115, 1971; T. A. Albright, H. Tang, Angew. Chem. 1992, 104, 1532; Angew. Chem. Int. Ed. Engl. 1992, 31, 1462.
27. S. K. Kang, H. Tang, T. A. Albright, J. Am. Chem. Soc. 1993, 115, 1971; T. A. Albright, H. Tang, Angew. Chem. 1992, 104, 1532; Angew. Chem. Int. Ed. Engl. 1992, 31, 1462.
28. S. K. Kang, H. Tang, T. A. Albright, J. Am. Chem. Soc. 1993, 115, 1971; T. A. Albright, H. Tang, Angew. Chem. 1992, 104, 1532; Angew. Chem. Int. Ed. Engl. 1992, 31, 1462.
29. B. Roessler, S. Kleinhenz, K. Seppelt, Chem. Commun. 2000, 1039.
30. C. J. Piersol, R. D. Profilet, P. E. Fanwick, I. P. Rothwell, Polyhedron 1993, 12, 1779.
31. Gas-phase electron diffraction: C. Pulham, A. Haaland, A. Hammel, K. Rypdal, H. P. Verne, H. V. Volden, Angew. Chem. 1992, 104, 1534; Angew. Chem. Int. Ed. Engl. 1992, 31, 1464; for solid-state X-ray diffraction, see ref. [18].
32. Gas-phase electron diffraction: C. Pulham, A. Haaland, A. Hammel, K. Rypdal, H. P. Verne, H. V. Volden, Angew. Chem. 1992, 104, 1534; Angew. Chem. Int. Ed. Engl. 1992, 31, 1464; for solid-state X-ray diffraction, see ref. [18].
33. C. R. Landis, T. Cleveland,T. K. Firman, J. Am. Chem. Soc. 1998, 120, 2641; C. R. Landis, T. K. Firman, D. M. Root, T. Cleveland, J. Am. Chem. Soc. 1998, 120, 1842.
34. C. R. Landis, T. Cleveland,T. K. Firman, J. Am. Chem. Soc. 1998, 120, 2641; C. R. Landis, T. K. Firman, D. M. Root, T. Cleveland, J. Am. Chem. Soc. 1998, 120, 1842.
35. W. A. Sheppard, J. Am. Chem. Soc. 1970, 92, 5419; C. A. Tolman, J. Am. Chem. Soc. 1970, 92, 2953.
36. W. A. Sheppard, J. Am. Chem. Soc. 1970, 92, 5419; C. A. Tolman, J. Am. Chem. Soc. 1970, 92, 2953.
37. C. Furlani, Coord. Chem. Rev. 1968, 3, 141.
38. P. Ehrlich, G. Kupa, K. Blankenstein, Z. Anorg. Allg. Chem. 1959, 299, 213.
39. M. Dadachov, L. Eriksson, Acta Crystallogr. Sect. C 1999, 55, 1739.
40. R. Usón, A. Laguna, Inorg. Synth. 1982, 21, 71.
41. L. E. Manzer, Inorg. Synth. 1982, 21, 135.
42. G. M. Sheldrick, SADABS, program for correction of systematic errors in diffraction data, version 2.03, University of Göttingen, Göttingen, Germany, 1996.
43. G. M. Sheldrick, SHELXL-97, Program for the refinement of crystal structures from diffraction data, University of Göttingen, Göttingen, Germany, 1997.