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Volumn , Issue 4, 2009, Pages 524-532

Oligonucleotide duplexes with tethered photoreactive ruthenium(II) complexes: Influence of the ligands and their linker on the photoinduced electron transfer and crosslinking processes of the two strands

Author keywords

Conjugation; DNA damage; Electron transfer; Oligonucleotides; Ruthenium

Indexed keywords

ELECTRON TRANSITIONS; EMISSION SPECTROSCOPY; PHOTOREACTIVITY; RUTHENIUM COMPOUNDS; TAPS;

EID: 60149091366     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200801083     Document Type: Article
Times cited : (21)

References (35)
  • 20
    • 85163244642 scopus 로고    scopus 로고
    • 2+. This depends on the value of the oxidation potential chosen for G from the literature. The most exergonic process (-0.07 and -0.25 eV) is obtained with the oxidation potential determined from radiolysis experiments, that is, corresponding to a proton-coupled electron transfer (PCET). Therefore, it is probable, as shown by picosecond laser experiments, that the quenching corresponds to a PCET.
    • 2+. This depends on the value of the oxidation potential chosen for G from the literature. The most exergonic process (-0.07 and -0.25 eV) is obtained with the oxidation potential determined from radiolysis experiments, that is, corresponding to a proton-coupled electron transfer (PCET). Therefore, it is probable, as shown by picosecond laser experiments, that the quenching corresponds to a PCET.
  • 26
    • 85163250542 scopus 로고    scopus 로고
    • Thèse de doctorat, Université libre de Bruxelles
    • b) R. Blasius, Thèse de doctorat, Université libre de Bruxelles, 2003.
    • (2003)
    • Blasius, R.1
  • 28
    • 85163242876 scopus 로고    scopus 로고
    • For biexponential decays, if one of the lifetimes is not at least the double of the other one, a full confidence into the lifetime values cannot be given. If triexponential decay functions are needed for fitting the results, which is generally the case with such systems when a luminescence quenching is present, it is probable that only the extreme lifetimes (the longest and the shortest ones) are significant
    • For biexponential decays, if one of the lifetimes is not at least the double of the other one, a full confidence into the lifetime values cannot be given. If triexponential decay functions are needed for fitting the results, which is generally the case with such systems when a luminescence quenching is present, it is probable that only the extreme lifetimes (the longest and the shortest ones) are significant.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.