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Crystallographic data for 1: C15H22O 4; M= 266.2; orthorhombic, a, 6.4397 (2, b =15.3604 (4, c 31.2247 (7) Å, space group P2 12121, Z, 8, Dx= 1.223 Mg m-3, μ, 0.09 -1, F (000, 1232; colorless prismatic crystals, dimension 0.4 × 0.4 × 0.7 mm3. CCDC-683154 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via or from the Cambridge Crystallographic Data Center, 12 Union Road, Canbridge CB2 1EZ, UK, fax: +44 1223 336033; e-mail: deposit@ ccdc.cam.ac.uk
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3. CCDC-683154 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/ retrieving.html (or from the Cambridge Crystallographic Data Center, 12 Union Road, Canbridge CB2 1EZ, UK.; fax: +44 1223 336033; e-mail: deposit@ ccdc.cam.ac.uk).
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2O/pyridine (1:1) and reacted for overnight at room temperature.
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2O/pyridine (1:1) and reacted for overnight at room temperature.
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9
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64349088650
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A solution of Clavicorolide B (2) (5 mg) and 4- dimethylaminopyridine (1 mg) in 200 μL of anhydrous dichloromethane was stirred at 0 °C (in ice-water), and then the solution of p-bromobenzoyl chloride (9 mg) in 200 μL of anhydrous dichloromethane together with ca. 20 μL triethylamine were added dropwise. The mixture was stirred for 1 h at 0 °C (in ice-water) and quenched with cold brine.
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A solution of Clavicorolide B (2) (5 mg) and 4- dimethylaminopyridine (1 mg) in 200 μL of anhydrous dichloromethane was stirred at 0 °C (in ice-water), and then the solution of p-bromobenzoyl chloride (9 mg) in 200 μL of anhydrous dichloromethane together with ca. 20 μL triethylamine were added dropwise. The mixture was stirred for 1 h at 0 °C (in ice-water) and quenched with cold brine.
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3. CCDC-698197 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/ retrieving.html (or from the Cambridge Crystallographic Data Center, 12 Union Road, Canbridge CB2 1EZ, UK.; fax: +44 1223 336033; e-mail: deposit@ ccdc.cam.ac.uk).
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