Two new structure types: KFe3(AsO4) 2(HAsO4)2 and K(H2O)M 3+(H1.5AsO4)2(H2AsO 4)(M3+ = Fe, Ga, In) - Synthesis, crystal structure and spectroscopy

European Journal of Mineralogy

Volumn 19, Issue 3, 2007, Pages 399-409

  Schwendtner, Karolina ^a   Kolitsch, Uwe ^a  

^a UNIVERSITY OF VIENNA   (Austria)

Author keywords

Crystal structure; K(H 2O)M3+(H1.5AsO4)2 (H 2AsO4); KFe 3(AsO4)2(HAsO4)2; Potassium iron arsenate; Raman spectroscopy

Indexed keywords

CRYSTAL STRUCTURE; IRON METALLOGRAPHY; MOLECULES; RAMAN SPECTROSCOPY; SINGLE CRYSTALS;

ACIDIC ENVIRONMENT; ARSENATE COMPOUNDS; IRON ARSENATES; KFE3(ASO4)2(HASO4)2; RAMAN SPECTROSCOPIC; RELATED COMPOUNDS; STAINLESS STEEL AUTOCLAVES; STRUCTURAL RELATIONSHIP;

CRYSTAL ATOMIC STRUCTURE;

EID: 59249090073     PISSN: 09351221     EISSN: None     Source Type: Journal    
DOI: 10.1127/0935-1221/2007/0019-1726     Document Type: Article

References (44)

1. 2O), Z Anorg. Allg. Chem., 623, 1708-1714.
2. 2O, J. Raman Spectrosc, 37, 1453-1455.
3. Baran, E.J., Schwendtner, K., Kolitsch, U. (2006b): Vibrational spectra of three new diarsenates containing scandium (III). J. Raman Spectrosc, 37, 1335-1340.
4. Baur, W.H. (1981): Interatomic distance predictions for computer simulation of crystal structures. Academic Press, New York, 31-52.
5. Birch, W.D., Pring, A., Self, P.G., Gibbs, R.B., Keck, E., Jensen, M.C., Foord, E.E. (1996): Meurigite, a new fibrous iron phosphate resembling kidwellite. Mineral. Mag., 60, 787-793.
6. Brown, I.D. &Aldermatt, D. (1985): Bond-valence parameters obtained from a systematic analysis of the inorganic crystal structure database. Acta Crystallogr., B41, 244-247.
7. Brown, I.D. &Shannon, R.D. (1973): Empirical bond-strength- bond-length curves for oxides. Acta Crystallogr., A29, 266-282.
8. 2 (A = K, Rb). Inorg. Chem., 36, 3410-3413.
9. Ferraris, G. & Ivaldi, G. (1984): X-OH and O-H... O bond lengths in protonated oxyanions. Acta Crystallogr, B40, 1-6.
10. 4: synthesis, structural study, IR spectroscopy characterization and ionic behavior. J. Solid State Chem., 173, 273-279.
11. Kolitsch, U. (1999): Evidence for the identity of meurigite and phos- phofibrite by transmission electron microscopy and X-ray powder diffraction. Eur. J. Mineral, 11 Beih. 1, 132.
12. 7-type diarse- nate. Z. Krist. - New Cryst. Struct., 219, 207-208.
13. 2O (M = Rb, Cs). Eur. J. Mineral, 18, 471-482.
14. 2O-type arsenate. Z Krist. - New Cryst. Struct., 219, 347-348.
15. 3OH).Acta Crystallogr, C61, i86-i98.
16. 2O: an iron(III) phosphate with a layer structure. Eur. J. Sol. State Inorg. Chem., 32, 917-926.
17. 2O Am. Mineral, 57, 397-410.
18. Otwinowski, Z., Borek, D., Majewski, W., Minor, W. (2003): Multiparameter scaling of diffraction intensities. Acta Crystallogr, A59, 228-234.
19. Otwinowski, Z. & Minor, W. (1997): Processing of X-ray diffraction data collection in oscillation mode. Methods EnzymoL, 276, 307-326.
20. 4. Acta Crystallogr, E61, i67-i69.
21. 3. Acta Crystallogr, C39, 9-12.
22. Robinson, K., Gibbs, G.V., Ribbe, P.H. (1971): Quadratic elongation: A quantitative measure of distortion in coordination poly- hedra. Science, 172, 567-570.
23. 7: synthesis and crystal structure of three isotypic diarsenates - representatives of a novel microporous structure type. J. Alloy. Compd., 421, 57-63.
24. 7. Acta Crystallogr, C60, i79-i83.
25. 2. Acta Crystallogr, C60, i84-i88.
26. 3+ = Al, Ga, In, Sc, Cr, Fe): novel representatives and an overview. Mitt. Österr. Mineral. Ges., 151, 109.
27. 4): decorated kröhnkite-like chains in two unusual hydrogen arsenates. Acta Crystallogr, C61, i90-i93.
28. 3+ = Al, Ga, In, Sc, Cr, Fe) = Al, Ga, In, Sc, Cr, Fe) - an overview. Mitt. Österr. Mineral. Ges., 151, 110.
29. 4)- a new monoclinic protonated arsenate with decorated kröhnkite- like chains. Acta Crystallogr, C63, il7-i20.
30. 1+-arsenates - architecture and seven new members. Acta Crystallogr, B63, 205-215.
31. 7) - a novel strongly acidic structure type and the first structural characterization of a diprotonated diarsenate group. 19th General Meeting of the International Mineralogical Association, Kobe, Japan, p. 90387.
32. 3+ = In, Ga, Fe)- three members of a novel structure type. Z. Krist. Suppl, 24, 119.
33. th Slovenian - Croatian Crystallographic Meeting, Jezersko, Slovenia, p. 36.
34. Sheldrick, G.M. (1997a): SHELXL-97, a program for crystal structure refinement. University of Göttingen, Göttingen, Germany.
35. Sheldrick, G.M. (1997b): SHELXS-97, a program for the solution of crystal structures. University of Göttingen, Göttingen, Germany.
36. 2O). J. Phys. Soc. Jpn., 31, 298.
37. 2O. Powder Diffr., 2, 187-190.
38. Walenta, K. & Theye, T. (1999): Haigerachit, ein neues Phosphatmineral von der Grube Silberbrünnle bei Gengenbach im mittleren Schwarzwald. Aufschluss, 50, 1-7.
39. 2O, ein zweites neues Phosphatmineral von der Grube Silberbrünnle im mittleren Schwarzwald. Der Erzgräber, 18, 17-23.
40. 2O, ein zweites neues Phosphatmineral von der Grube Silberbrünnle im mittleren Schwarzwald. Am. Mineral., 90, 1228.
41. 0 values. Potassium-oxygen complexes. Inorg. Chem., 38, 1031-1034.
42. Zemann, J. (1947): The structure of pharmacosiderite. Experienlia, 3, 452.
43. Zemann, J. (1948): Formula and structural type of pharmacosiderite. Tscher. Miner. Petrogn, 1, 1-13.
44. Zemann, J. (1959): Isotypes between pharmacosiderite and zeolitic germanates. Acta Crystallogr, 12, 252.