Development of a rapid and confirmatory procedure to detect 17β-estradiol 3-benzoate treatments in bovine hair

Journal of Agricultural and Food Chemistry

Volumn 56, Issue 24, 2008, Pages 11607-11611

  Regal, Patricia ^a   Vázquez, Beatriz I ^a   Franco, Carlos M ^a   Cepeda, Alberto ^a   Fente, Cristina A ^a  

^a UNIVERSITY OF SANTIAGO DE COMPOSTELA   (Spain)

Author keywords

17 Estradiol 3 benzoate; Bovine hair; HPLC MS MS; Residues

Indexed keywords

ANIMALIA; BOVINAE;

DRUG DERIVATIVE; ESTRADIOL; ESTRADIOL 3-BENZOATE; ESTRADIOL BENZOATE; UNCLASSIFIED DRUG;

ANIMAL; ARTICLE; CATTLE; CHEMISTRY; EVALUATION; HAIR; LIQUID CHROMATOGRAPHY; METHODOLOGY; TANDEM MASS SPECTROMETRY;

ANIMALS; CATTLE; CHROMATOGRAPHY, LIQUID; ESTRADIOL; HAIR; TANDEM MASS SPECTROMETRY;

EID: 58849165816     PISSN: 00218561     EISSN: None     Source Type: Journal    
DOI: 10.1021/jf803044b     Document Type: Article

References (14)

1. Cavalieri, J.; Rabiee, A. R.; Hepworth, G.; Macmillan, K. L. Effect of artificial insemination on submission rates of lactating dairy cows synchronised and resynchronised with intravaginal progesterone releasing devices and oestradiol benzoate. Anim. Reprod. Sci. 2005, 90, 39-55.
2. Sabo, Y. G. Schemes for oestrus synchronization protocols and controlled breeding programs in cattle. J. Appl. Sci. 2008, 8, 241.
3. Council Directive 2003/74/EC amending Council Directive 96/22/EC concerning the prohibition on the use of certain substances having a hormonal or thyrostatic action and of beta-agonists in stockfarming. Off. J. Eur. Communities 2003, L262/17.
4. Council Directive 96/22/EC of 29 April 1996 concerning the prohibition on the use in stockfarming of certain substances having a hormonal or thyrostatic action and of β-agonists, and repealing Directives 81/602/EEC, 88/146/EEC and 88/299/EEC. Off. J. Eur. Communities 1996, L125/3.
5. European Parliament legislative resolution of 5 June 2008 on the proposal for a directive of the European Parliament and of the Council amending Council Directive 96/22/EC concerning the prohibition on the use in stockfarming of certain substances having a hormonal or thyreostatic action and of β-agonists. COM(2007)0292 - C6-0154/2007 - 2007/0102(COD).
6. Maume, D.; Le Bizec, B.; Pouponneau, K.; Deceuninck, Y.; Solere, V.; Paris, A.; Antignac, J.; Andre, F. Modification of 17β-estradiol metabolite profile in steer edible tissues after estradiol implant administration. Anal. Chim. Acta 2003, 483, 289-297.
7. Gratacós-Cubarsí, M.; Castellari, M.; Valero, A.; García-Regueiro, J. A. Hair analysis for veterinary drug monitoring in livestock production. J. Chromatogr., B 2006, 834, 14-25.
8. Rambaud, L.; Bichon, E; Cesbron, N.; André, F.; Le Bizec, B. Study of 17β-estradiol-3-benzoate, 17α-methyltestosterone and medroxyprogesterone acetate fixation in bovine hair. Anal. Chim. Acta 2005, 532, 165-176.
9. Hooijerink, H.; Lommen, A.; Mulder, P. P. J.; van Rhijn, J. A.; Nielen, M. W. F. Liquid chromatography-electrospray ionisation-mass spectrometry based method for the determination of estradiol benzoate in hair of cattle. Anal. Chim. Acta 2005, 529, 167172.5.
10. Pedreira, S.; Lolo, M.; Vazquez, B. I.; Franco, C. M.; Cepeda, A.; Fente, C. Liquid chromatography-electrospray ionization-mass spectrometry method in multiple reaction monitoring mode to determine 17α-ethynylestradiol residues in cattle hair without previous digestion. J. Agric. Food Chem. 2007, 55, 9325-9329.
11. 657/2002/EC Commission Decision of 12 August 2002 implementing Council Directive 96/23/ECconcerning the performance of analytical methods and the interpretationof results. Off. J. Eur. Communities 2002, L221, 8-36.
12. Durant, A. A.; Fente, C. A.; Franco, C. M.; Vazquez, B. I.; Cepeda, A. Gas chromatography-tandem mass spectrometry determination of 17α-ethinylestradiol residue in the hair of cattle. Application to treated animals. J. Agric. Food Chem. 2002, 50, 436-440.
13. Blokland, M.; Herbold, H. ResVal 2.2 validation program from CRL in hormones (RIVM, Bilthoven, The Netherlands); 2003-2005.
14. Gleixner, A.; Sauerwein, H.; Meyer, H. H. D. Accumulation of the xenobiotic anabolic steroids ethinyloestradiol and methyltestosterone in calf hair. Food Agric. Immunol. 1997, 9, 27-35.