Liquid chromatography-electrospray ionization-mass spectrometry method in multiple reaction monitoring mode to determine 17α-ethynylestradiol residues in cattle hair without previous digestion

Journal of Agricultural and Food Chemistry

Volumn 55, Issue 23, 2007, Pages 9325-9329

  Pedreira, S ^a   Lolo, M ^a   Vazquez B I ^a   Franco, C M ^a   Cepeda, A ^a   Fente, C ^a  

^a UNIVERSITY OF SANTIAGO DE COMPOSTELA   (Spain)

Author keywords

Cryogenic grinding; Hair; HPLC MS MS; Residues

Indexed keywords

DRUG RESIDUE; ETHINYLESTRADIOL;

ANIMAL; ARTICLE; CATTLE; CHEMISTRY; ELECTROSPRAY MASS SPECTROMETRY; HAIR; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; METHODOLOGY; REPRODUCIBILITY;

ANIMALS; CATTLE; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; DRUG RESIDUES; ETHINYL ESTRADIOL; HAIR; REPRODUCIBILITY OF RESULTS; SPECTROMETRY, MASS, ELECTROSPRAY IONIZATION;

BOS;

EID: 36749102554     PISSN: 00218561     EISSN: None     Source Type: Journal    
DOI: 10.1021/jf0715222     Document Type: Article

References (20)

1. Council Directive 96/22/EC. Off. J. Eur. Communities 1996, L 125/3.
2. Gaillard, Y.; Pepin, G. Testing hair for pharmaceuticals. J. Chromatogr. B. 1999, 733, 231-246.
3. Fente, C. A.; Vazquez, B. I.; Franco, C.; Cepeda, A.; Gigosos, P. G. Determination of clenbuterol residues in bovine hair by using diphasic dialysis and gas chromatography-mass spectrometry. J. Chromatogr. B. 1999, 726, 133-139.
4. Anielski, P.; Thieme, D.; Schlupp, A.; Grosse, J.; Ellendorff, F.; Mueller, R. K. Detection of testosterone, nandrolone and precursors in horse hair. Anal. Bioanal. Chem. 2005, 383, 903-908.
5. Durant, A. A.; Fente, C. A.; Franco, C. M.; Vazquez, B. I.; Cepeda, A. Gas chromatography-tandem mass spectrometry determination of 17α-ethinylestradiol residue in the hair of cattle. Application to treated animals. J. Agric. Food Chem. 2002, 50, 436-440.
6. Durant, A. A.; Fente, C. A.; Franco, C. M.; Vazquez, B. I.; Mayo, S.; Cepeda, A. Development of a diphasic dialysis method for the extraction/purification of residues of ethinylestradiol in hair of cattle, and determination by gas chromatography-tandem mass spectrometry. J. Chromatogr. B 2002, 766, 251-256.
7. Gambelunghe, C.; Sommavilla, M.; Ferranti, C.; Rossi, R.; Aroni, K.; Manes, N.; Bacci, M. Analysis of anabolic steroids in hair by GC/MS/MS. Biomed. Chromatogr. 2007, 21, 369-375.
8. Hooijerink, H.; Lommen, A.; Mulder, P. P. J.; van Rhijn, J. A.; Nielen, M. W. F. Liquid chromatography-electrospray ionisation-mass spectrometry based method for the determination of estradiol benzoate in hair of cattle. Anal. Chim. Acta 2005, 529, 167-172.
9. Nielen, M. W.; Lasaroms, J. J.; Mulder, P. P.; Van Hende, J.; van Rhijn, J. H.; Groot, M. J. Multi residue screening of intact testosterone esters and boldenone undecylenate in bovine hair using liquid chromatography electrospray tandem mass spectrometry. J. Chromatogr. B. 2006, 830, 126-134.
10. Iglesias, Y.; Mayo, S.; Fente, C.; Franco, C.; Cepeda, A. Detection of corticosteroids in hair by chemiluminescence. XXX Scientific Meeting of the Group of Chromatography and Related Techniques and I Meeting of the Spanish Society of Chromatography and Related Techniques, Valencia, Spain, 2001.
11. Lolo, M.; Pedreira, S.; Vazquez, B. I.; Franco, C. M.; Cepeda, A.; Fente, C. A. Cryogenic grinding pre-treatment improves extraction efficiency of fluoroquinolones for HPLC-MS/MS determination in animal tissue. Anal. Bioanal Chem. 2007, 387, 1933-1937.
12. Robb, D. B.; Covey, T. R.; Bruins, A. P. Atmospheric pressure photoionization: an ionization method for liquid chromatography-mass spectrometry. Anal. Chem. 2000, 72, 3563-3659.
13. Alary, J. F. Comparative study: LC-MS/MS analysis of four steroid compounds using a new photoionization source and a conventional APCI source. Proc. 49th ASMS Conf. Mass Spectrom. Allied Topics 2001, Chicago.
14. Li, W.; Li, Y. H.; Li, A. C.; Zhou, S.; Naidong, W. Simultaneous determination of norethindrone and ethinyl estradiol in human plasma by high performance liquid chromatography with tandem mass spectrometry-experiences on developing a highly selective method using derivatization reagent for enhancing sensitivity. J. Chromatogr. B 2005, 825, 223-232.
15. Nelson, R. E.; Grebe, S. K.; OKane, D. J.; Singh, R. J. Liquid chromatography-tandem mass spectrometry assay for simultaneous measurement of estradiol and estrone in human plasma. Clin. Chem. 2004, 50, 373-384.
16. Shou, W. Z.; Jiang, X.; Naidong, W. Development and validation of a high-sensitivity liquid chromatography/tandem mass spectrometry (LC/MS/MS) method with chemical derivatization for the determination of ethinyl estradiol in human plasma. Biomed. Chromatogr. 2004, 18, 414-421.
17. Tai, S. S.; Welch, M. J. Development and evaluation of a reference measurement procedure for the determination of estradiol-14β in human serum using isotope-dilution liquid chromatography-tandem mass spectrometry. Anal. Chem. 2005, 77, 6359-6363.
18. Zhang, F.; Bartels, M. J.; Brodeur, J. C.; McClymont, E. L.; Woodburn, K. B. Quantitation of 17α-ethinylestradiol in aquatic samples using liquid-liquid phase extraction, dansyl derivatization, and liquid chromatography/positive electrospray tandem mass spectrometry. Rapid Commun. Mass Spectrom. 2004, 18, 2739-2742.
19. Fente, C. A.; Gigosos, G. P.; Franco, C. M.; Vázquez, B. I.; Cepeda, A. Determination of clenbuterol residues in bovine hair by using diphasic dialysis and Gas chromatography-Mass spectrometry. J. Chromatogr. B 1999, 726, 133-139.
20. Commission Decision of 12 August 2002 implementing Council Directive 96/23/EC concerning the performance of analytical methods and the interpretation of results (2002/657/EC). Off. J. Eur. Communities 2002, L 221/8.