Comparison between analytical pyrolysis and nitrobenzene oxidation for determination of syringyl/guaiacyl ratio in Eucalyptus spp. Lignin

BioResources

Volumn 3, Issue 3, 2008, Pages 701-712

  Lima, Cláudio F ^a   Barbosa, Luiz C A ^a   Marcelo, Cristiana R ^a   Silvério, Flaviano O ^a   Colodette, Jorge L ^a  

^a FEDERAL UNIVERSITY OF VIÇOSA   (Brazil)

Author keywords

Analytical pyrolysis; Eucalyptus ssp.; Lignin; S G ratio

Indexed keywords

ACETOSYRINGONE; ALKALINE NITROBENZENE OXIDATION; ANALYSIS TIME; ANALYTICAL PYROLYSIS; EUCALYPTUS SSP; EUCALYPTUS WOOD; NITROBENZENE OXIDATION; PY-GC-MS; PYROLYSIS-GAS CHROMATOGRAPHY/MASS SPECTROMETRY; S/G RATIO; SYRINGYL; SYRINGYL/GUAIACYL RATIO; WOOD SAMPLES;

CARBOHYDRATES; GAS CHROMATOGRAPHY; MASS SPECTROMETRY; NITROBENZENE; OXIDATION;

LIGNIN;

EID: 58849151380     PISSN: None     EISSN: 19302126     Source Type: Journal    
DOI: None     Document Type: Article

References (36)

1. Alén, R., Kuoppala, E., and Oesch, P. (1996). "Formation of the main degradation compound groups from wood and its components during pyrolysis," Journal of Analytical and Applied Pyrolysis 36, 137-148.
2. Barbosa, L. C. A., Maltha, C. R. A., Silva, V. L., and Colodette, J. L. (2008). "Determination of the siringyl/guaiacyl ratio in eucalyptus wood by pyrolysis-gas chromato-graphy/mass spectrometry (Py-GC/MS)," Quim. Nova, 31 (in press).
3. Campbell, M. M., and Sederoff, R. R. (1996). "Variation in lignin content and composition. Mechanism of control and implications for the genetic improvement of plants," Plant Physiology 110, 3-13.
4. Collins, D. J., Pilotti, C. A., and Wallis, A. F. A. (1990). "Correlation of chemical composition and kraft pulping properties of some Papua New Guinea reforestation woods," Appita J. 43(3), 193-198.
5. Del Río, J. C., Gutiérrez, A., Hernando, M., Landín, P., Romero, J., and Martínez, A. T. (2005). "Determining the influence of eucalypt lignin composition in paper pulp yield using Py-GC/MS," Journal of Analytical and Applied Pyrolysis 74, 110-115.
6. Del Río, J. C., Gutiérrez, A., Martínez, M. J., and Martínez, A. T. (2001a). "Py-GC/MS study of Eucalyptys globulus wood treated with different fungi," Journal of Analytical and Applied Pyrolysis 58-59, 441-452.
7. Del Río, J. C., Gutiérrez, A., Romero, J., Martínez, M. J., and Martínez, A. T. (2001b). "Identification of residual lignin markers in eucalypt kraft pulps by Py-GC/MS," Journal of Analytical and Applied Pyrolysis 58-59, 425-439.
8. Del Río, J. C., Speranza, M., Gutiérrez, A., Martínez, M. J., and Martínez, A. T. (2002). "Lignin attack during eucalypt wood decay by selected basidiomycetes: A Py-GC/MS study," Journal of Analytical and Applied Pyrolysis 64, 421-431.
9. Del Río, J. C., Gutiérrez, A., Rodríguez, I. M., Ibarra D., and Marti{dotless}nez, A. T. (2007). "Composition of non-woody plant lignins and cinnamic acids by Py-GC/MS, Py/TMAH and FT-IR," J. Anal. Appl. Pyrolysis 79, 39-46.
10. Galletti, G. C., and Bocchini, P. (1995). "Pyrolysis/gas chromatography/mass spectrometry of lignocellulose," Rapid Communications in Mass Spectrometry 9, 815-826.
11. González-Vila, F. J., Almendros, G., Del Río, J. C., Martin, F., Gutiérrez, A., and Romero, J. (1999). "Ease of delignification assessment of wood from different Eucalyptus species by pyrolysis (TMAG)-GC/MS and CP/MAS 13C-NMR spectrometry," Journal of Analytical and Applied Pyrolysis 49, 295-305.
12. Gutiérrez, A., Rodríguez, I. M., and Del Río, J. C. (2006). "Chemical characterization of lignin fractions in industrial hemp bast fibers used for manufacturing high-quality paper pulps," Journal of Agricultural and Food Chemistry 54, 2138-2144.
13. Hatfield, R., and Vermerris, W. (2001). "Lignin formation in plants. The dilemma of linkage specificity," Plant Physiology 126, 1351-1357.
14. Ishida, Y., Goto, K., Hiroaki, Y., Tsuge, S., Ohtani, H., Sonoda, T., and Ona, T. (2007). "Direct analysis of phenolic extractives in wood by thermochemolysis-gas chromatography in the presence of tetrabutylammonium hydroxide," Journal of Analytical and Applied Pyrolysis 78, 200-206.
15. Ibarra, D., Del Río, J. C., Gutiérrez, A., Rodríguez, I. M., Romero, J., Martínez, M. J., and Martínez, A. T. (2005). "Chemical characterization of residual lignins from eucalypt paper pulps," Journal of Analytical and Applied Pyrolysis 74, 116-122.
16. Kuroda, K., Izumi, A., Mazumder, B. B., Ohtani, Y., and Sameshima, K. (2002a). "Characterization of kenaf (Hibiscus cannabinus) lignin by pyrolysis-gas chromatography-mass spectrometry in the presence of tetramethylammonium hydroxide," Journal of Analytical and Applied Pyrolysis 64, 453-463.
17. Kuroda, K., and Nakagawa-Izumi, A. (2005). "Tetramethylammonium hydroxide of guaiacyl-syringyl and guaiacyl dehydrogenation polymers," Organic Geochemistry 36, 53-61.
18. Kuroda, K., Nishimura, N., Izumi, A., and Dimmel, D. R. (2002b). "Pyrolysis of lignin in the presence of tetramethylammonium hydroxide: A convenient method for S/G ratio determination," Journal of Agricultural and Food Chemistry 50, 1022-1027.
19. Lin, S. Y., and Dence, C. W. (1992). Methods in Lignin Chemistry, Springer-Verlag, Berlin.
20. Morais, S. A. L., Nascimento, E. A., and Melo, D. C. (2005). "Análise da madeira do Pinus oocarpa. Parte II - caracterização estrutural da lignina de madeira moída," Revista Árvore 29(3), 471-478.
21. Nonier, M. F., Vivas, N., Gaulejac, N. V., Absalon, C., Soulié, P., and Fouquet, E. (2006). "Pyrolysys-gas chromatography/mass spectrometry of Quercus sp. woodApplication to structural elucidation of macromolecules and aromatic profiles of different species," Journal of Analytical and Applied Pyrolysis 75, 181-193.
22. Oudia, A., Mészáros, E., Simões, R., Queiroz, J. and Jakab, E. (2007). "Pyrolysis-GC/MS and TG/MS study of mediated laccase biodelignification of Eucalyptus globulus kraft pulp," Journal of Analytical and Applied Pyrolysis 78, 233-242.
23. Ralph, J., and Hatfield, R. D. (1991). "Pyrolysis-GC-MS characterization of forage materials," Journal of Agriculture and Food Chemistry 39, 1426-1437.
24. Rencoret, J., Gutiérrez, A. C., and Del Río, J. C. (2007). "Lipid and lignin composition of woods from different eucalypt species," Holzforschung 61, 165-174.
25. Rodrigues, J., Meier, D., Faix, O., and Pereira, H. (1999). "Determination of tree to tree variation in syringyl/guaiacyl ratio of Eucalyptus globulus wood lignin by analytical pyrolysis," Journal of Analytical and Applied Pyrolysis 48, 121-128.
26. Rowell, R. M. (2005). Handbook of Wood Chemistry and Wood Composites, CRC Press, Boca Raton, Florida.
27. Saliba, E. O. S., Rodriguez, N. M., Morais, S. A. L., and Piló-Veloso, D. (2001). "Ligninas - Métodos de obtenção e caracterização química," Ciência Rural 31(5), 917-928.
28. Salo, S., Niemelä, S., Elomaa, M., and Lindberg, J. J. (1989). "Identification of lignins by pyrolysis methods," Holzforschung 43(4), 257-260.
29. Silva, V. L. (2006). "Caracterização de ligninas de Eucalyptus spp. pela técnica de pirólise associada à cromatografia gasosa e à espectrometria de massas," Viçosa, 68p. Dissertação de Mestrado. Universidade Federal de Viçosa.
30. Silvério, F. O., Barbosa, L. C. A., and Veloso, D. P. (2008). "The pyrolysis as analytic technique," Quim. Nova 31, in press.
31. Takayama, M., Johjima, T., Yamanaka, T., Wariishi, H., and Tanaka, H. (1997). "Fourier transform Raman assignment of guaiacyl and syringyl marker bands for lignin determination," Spectrochimica Acta Part A 53, 1621-1628.
32. Tsutsumi, Y., Kondo, R., Sakai, K., and Imamura, H. (1995). "The difference of reactivity between syringyl lignin and guaiacyl lignin in alkaline systems," Holzforschung 49(5), 423-428.
33. Van Der Hage, E. R. E., Mulder, M. M., and Boon, J. J. (1993). "Structural characterization of lignin polymers by temperature-resolved in-source pyrolysis-mass spectrometry and Curie-point pyrolysis-gas chromatography/mass spectrometry," Journal of Analytical and Applied Pyrolysis 25, 149-183.
34. Wallis, A. F. A., Wearne, R. H., and Wright, P. J. (1996). "Analytical characteristics of plantation eucalypt woods relating to kraft pulp yields," Appita J. 49, 427-432.
35. Yokoi, H., Nakase, T., Ishida, Y., Ohtani, H., Tsuge, S., Sonoda, T., and Ona, T. (2001). "Discriminative analysis of Eucalyptus camaldulensis grown from seeds of various origins base don lignin components measured by pyrolysis-gas chromatography," Journal of Analytical and Applied Pyrolysis 57, 145-152.
36. Zier, N., Schiene, R. and Fischer, K. (1997). "Structural characterization of an organosolv lignin by analytical pyrolysis and wet chemical degradation methods," Journal of Analytical and Applied Pyrolysis 40-41, 525-551.