Reactive extraction of formic acid by amberlite LA-2 extractant

Journal of Chemical and Engineering Data

Volumn 54, Issue 1, 2009, Pages 48-53

  Uslu, Hasan ^a   Bayat, Cuma ^a   Gökmen, Selahattin ^a   Yorulmaz, Yavuz ^a  

^a BEYKENT UNIVERSITY   (Turkey)

Author keywords

[No Author keywords available]

Indexed keywords

ACIDS; DISSOLUTION; ESTERS; EXTRACTIVE METALLURGY; FORMIC ACID; KETONES; ORGANIC ACIDS; ORGANIC COMPOUNDS;

AMBERLITE; DIETHYL CARBONATES; DIMETHYL ADIPATE; DIMETHYL GLUTARATE; DIMETHYL PHTHALATE; DIMETHYL SUCCINATES; DISTRIBUTION COEFFICIENTS; EXTRACTANT; EXTRACTION CAPACITIES; EXTRACTION EFFICIENCIES; ISOAMYL ALCOHOLS; ISOTHERMAL CONDITIONS; LINEAR SOLVATION ENERGY RELATIONSHIPS; LOADING FACTORS; MODEL EQUATIONS; R SQUARES; REACTIVE EXTRACTIONS; SEPARATION FACTORS;

EXTRACTION;

EID: 58849141659     PISSN: 00219568     EISSN: None     Source Type: Journal    
DOI: 10.1021/je8005584     Document Type: Article

References (31)

1. Kertes, A. S.; King, C. J. Extraction chemistry of fermentation product carboxylic acids, Biotechnol. Bioeng. 1986, 28, 269-282.
2. Wardell, J. M.; King, C. J. Solvent equilibriums for extraction of carboxylic acids from water. J. Chem. Eng. Data 1978, 23, 144-153.
3. Cai, W.; Zhu, S.; Piao, X. Extraction equilibria of formic and acetic acids from aqueous solution by phosphate-containing extradants. J. Chem. Eng. Data 2001, 46, 1472-1475.
4. Senol, A. Extraction equilibria of formic, levulinic and acetic acids using (alamine 336/diluent) and conventional solvent systems: modeling considerations, J. Chem. Eng. Jpn. 1999, 32, 717-731.
5. Senol, A. Extraction equilibria of formic and levulinic acids using alamine 308/diluent and conventional solvent systems. Sep. Purif. Technol. 2000, 21, 165-179.
6. Senol, A. Liquid-liquid equilibria for ternary systems of (water + carboxylic acid + 1-octanol) at 293.15 K: modeling phase equilibria using a solvatochromic approach. Fluid Phase Equilib. 2005, 227, 87-96.
7. Malmary, G.; Faizal, M.; Albet, J.; Molinier, J. Liquid-liquid equilibria of acetic, formic, and oxalic acids between water and tributyl phosphate + dodecane. J. Chem. Eng. Data 1997, 42, 985-987.
8. Derawi, S. O.; Zeuthen, J.; Michelsen, M. L.; Stenby, E. H.; Kontogeorgis, G. M. Application of the CPA equation of state to organic acids. Fluid Phase Equilib. 2004, 225, 107-113.
9. Ince, E.; Kirbaslar, S. I.; Sahin, S. Liquid-Liquid Equilibria for Ternary Systems of Water + Formic Acid + Dibasic Esters. J. Chem. Eng. Data 2007, 52, 1889-1893.
10. Yang, S. T.; White, S. A.; Hsu, S. T. Extraction of carboxylic acids with tertiary and quaternary amines: effect of pH. Ind. Eng. Chem. Res. 1991, 30, 1335-1342.
11. Tamada, J. A.; Kertes, A. S.; King, C. J. Extraction of carboxylic acids with, amine extractants. 1. Equilibria and law of mass action modeling. Ind. Eng. Chem. Res. 1990, 29, 1319-1326.
12. Bízek, V.; Horácek, J.; Koušová, M. Amine extraction of citric acid: effect of diluent. Chem. Eng. Sci. 1993, 48, 1447-1457.
13. Tamada, J. A.; King, C. J. Extraction of carboxylic acids with amine extractants. 2. Chemical interaction and interpretation of data. Ind. Eng. Chem. Res. 1990, 29, 1327-1333.
14. Poposka, F. A.; Nikolovski, K.; Tomovska, R. Equilibrium and mathematical models of extraction of citric acid with isodecanol/n-paraffins solutions of trioctylamine. J. Chem. Eng. Jpn. 1997, 30, 111-785.
15. Heyberger, A.; Procházka, J.; Volaufova, E. Extraction of citric acid with tertiary amines-third phase formation. Chem. Eng. Sci. 1998, 53, 515-521.
16. Senol, A. Extraction equilibria of valeric acid using (Alamine 336/ diluent) and conventional solvent systems. Modeling considerations. Chem. Eng. Process. 2002, 41, 681-692.
17. Uslu, H.; Kirbaşlar, Ş. İ Equilibrium Studies of Extraction of Levulinic Acid by (Trioctylamine (AMBERLİTE LA-2) + Ester) Solvents. J. Chem. Eng. Data 2008, 53, 1557-1563.
18. Uslu, H.; Kirbaşlar, Ş. İ. Investigation of Levulinic Acid Distribution from Aqueous phase to Organic phase with TOA Extradant. Ind. Eng. Chem. Res. 2008, 47, 4598-4606.
19. Uslu, H. Liquid + liquid equilibria of the (water + tartaric acid + Alamine 336 + organic solvents) at 298.15 K. Fluid Phase Equilib. 2007, 253, 12-18.
20. Uslu, H.; tnci, L (Liquid + liquid) equilibria of the (water + propionic acid + Aliquat 336 + organic solvents) at T = 298.15. J. Chem. Thermodyn. 2007, 39, 804-809.
21. Inci, İ Uslu, H. Extraction, of glycolic acid from aqueous solutions by trioctyl methylammonium chloride and organic solvents, J. Chem. Eng. Data 2005, 50, 536-540.
22. Kyuchoukov, G.; Yankov, D.; Albet, J.; Molinier, J. Mechanism of Lactic Acid Extraction with Quaternary Ammonium Chloride (Aliquat 336). Ind. Chem. Res. 2005, 44, 5733-5739.
23. Wasewar, K. L.; Heesink, A. B. M.; Versteeg, G. F.; Pangarkar, V. G. Equilibria and kinetics for reactive extraction of lactic acid using Alamine 336 in decanol. J. Chem. Technol. Biotechnol. 2002, 77, 1068-1075.
24. Martak, J.; Schlosser, S. L/L equilibria of dimethylcyclopropanecarboxylic acid in water - Solvent systems with trioctylamine as an extractant. Chem. Paper-Chemicke Zvesti. 2000, 54, 413-422.
25. Keshav, A.; Chand, S.; Wasewar, K. L. Equilibrium. Studies for Extraction of Propionic Acid Using Tri-n-Butyl Phosphate in Different Solvents, J. Chem. Eng. Data 2008, 53, 1424-1430.
26. Yizhak, M. The properties of solvents. Wiley Series in Solution Chemistry, 1999.
27. Kosower, E. M. An Introduction to Physical Organic Chemistry; Wiley: New York, 1968.
28. Senol, A. Effect of Diluent on Amine Extraction of Acetic Acid: Modeling Considerations. Ind. Eng. Chem. Res. 2004, 43, 6496-6506.
29. Uslu, H. Linear solvation energy relationship (LSER) Modeling and kinetic studies on propionic acid reactive extraction using alamine 336 in a toluene solution. Ind. Eng. Chem. J. Eng. Chem. Res. 2006, 45, 5788-5795.
30. Kamlet, M. J.; Abboud, M.; Abraham, M. H.; Taft, R. W. Linear Solvation Energy Relationships, 23. A Comprehensive Collection of the Solvatochromic Parameters, II*, α, β, and some Methods for Simplifying the Generalized Solvatochromic Equation. J. Org. Chem. 1983, 48, 2877-2887.
31. Legget, D. N. Modeling solvent extraction using the solvatochromic parameters α, β, and II*. Anal. Chem. 1993, 65, 2907-2909.