Extraction equilibria of valeric acid using (Alamine 336/diluent) and conventional solvent systems. Modeling considerations

Chemical Engineering and Processing

Volumn 41, Issue 8, 2002, Pages 681-692

  Senol, Aynur ^a  

^a ISTANBUL UNIVERSITY   (Turkey)

Author keywords

Alamine 336; Extraction; Liquid liquid equilibria; Modeling; Valeric acid

Indexed keywords

AMINES; EXTRACTION; MIXTURES; PHASE EQUILIBRIA; SOLVENTS; STRUCTURE (COMPOSITION);

MASS ACTION LAW;

CHEMICAL ENGINEERING;

ACID; AMINE; LIQUID-LIQUID EXTRACTION; TERNARY MIXTURE;

EID: 0036707397     PISSN: 02552701     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0255-2701(01)00188-X     Document Type: Article

References (23)

1. Kertes A.S., King C.J. Extraction chemistry of fermentation product carboxylic acids. J. Biotechnol. Bioeng. 28:1986;269-282.
2. Yang S.T., White S.A., Hsu S.T. Extraction of carboxylic acids with tertiary and quaternary amines: effect of pH. Ind. Eng. Chem. Res. 30:1991;1335-1342.
3. Tamada J.A., Kertes A.S., King C.J. Extraction of carboxylic acids with amine extractants. 1. Equilibria and law of mass action modeling. Ind. Eng. Chem. Res. 29:1990;1319-1326.
4. Bízek V., Horácek J., Koušová M. Amine extraction of citric acid: effect of diluent. Chem. Eng. Sci. 48:1993;1447-1457.
5. Tamada J.A., King C.J. Extraction of carboxylic acids with amine extractants. 2. Chemical interaction and interpretation of data. Ind. Eng. Chem. Res. 29:1990;1327-1333.
6. Poposka F.A., Nikolovski K., Tomovska R. Equilibrium and mathematical models of extraction of citric acid with isodecanol/n-paraffins solutions of trioctylamine. J. Chem. Eng. Jpn. 30:1997;777-785.
7. Heyberger A., Procházka J., Volaufova E. Extraction of citric acid with tertiary amines - third phase formation. Chem. Eng. Sci. 53:1998;515-521.
8. Malmary G., Faizal M., Albet J., Molinier J. Liquid-liquid equilibria of acetic, formic, and oxalic acids between water and tributil phosfate+dodecane. J. Chem. Eng. Data. 42:1997;985-987.
9. Reinsel M.A., Borkowski J.J., Sears J.T. Partition coefficients for acetic, propionic, and butiric acids in a crude oil/water system. J. Chem. Eng. Data. 39:1994;513-516.
10. Kirsch T., Maurer G. Distribution of oxalic acid between water and organic solutions of tri-n-octylamine. Ind. Eng. Chem. Res. 35:1996;1722-1735.
11. Prausnitz J.M., Anderson T., Grens E., Eckert C., Hsieh R., O'Connell J.P. Computer Calculations for Multicomponent Vapor-Liquid and Liquid-Liquid Equilibria. 1980;Prentice-Hall Inc, Englewood Cliffs, NJ.
12. Kamlet M.J., Doherty R.M., Abraham M.H., Marcus Y., Taft R.W. Linear solvation energy relationships. 46. An improved equation for correlation and prediction of octanol/water partition coefficients of organic nonelectrolytes (including strong hydrogen bond donor solutes). J. Phys. Chem. 92:1988;5244-5255.
13. Marcus Y. Linear solvation energy relationships. Correlation and prediction of the distribution of organic solutes between water and immiscible organic solvents. J. Phys. Chem. 95:1991;8886-8891.
14. Gmehling J., Li J., Schiller M.A. Modified UNIFAC model 2. Present parameter matrix and results for different thermodynamic properties. Ind. Eng. Chem. Res. 32:1993;178-193.
15. Bauer U., Marr R., Ruckl W., Siebenhofer M. Reactive extraction of citric acid from aqueous fermentation broth. Ber. Bunsen-Ges. Phys. Chem. 93:1989;980-984.
16. Riddick J.A., Bunger W.B., Sakano T.K. Organic Solvents. Physical Properties and Methods of Purification. fourth ed:1986;Wiley-Interscience, New York.
17. Himmelblau D.M. Basic Principles and Calculations in Chemical Engineering. fifth ed:1989;Prentice-Hall Inc, Englewood Cliffs, NJ.
18. Senol A. Vapor-liquid equilibria of the systems ethyl ethanoate/2-methyl-2-butanol, 2-methyl-1-propanol/3-methyl-1-butanol, and cyclohexanol/benzyl alcohol at 101.32 kPa. J. Chem. Eng. Data. 43:1998;763-769.
19. Taylor R., Kooijman H. Composition derivatives of activity coefficient models (for the estimation of thermodynamic factors in diffusion). Chem. Eng. Comm. 102:1991;87-106.
20. Mori H., Oda A., Ito C., Aragaki T., Liu F.Z. Thermodynamic factors derived from group contribution activity coefficient models. J. Chem. Eng. Japan. 29:1996;396-398.
21. Bolles W.L., Fair J.R. Improved mass-transfer model enhances packed-column design. Chem. Eng. 89:1982;109-116.
22. Johnson N.L., Leone F.C. Statistics and Experimental Design in Engineering and the Physical Sciences. 1964;Wiley, New York.
23. Barton A.F.M. Solubility parameters. Chem. Rev. 75:1975;731-753.