Fe(III)-montmorillonite: Basic properties and diffusion of tracers relevant to alteration of bentonite in deep geological disposal

Applied Clay Science

Volumn 43, Issue 2, 2009, Pages 208-217

  Manjanna, Jayappa ^a   Kozaki, Tamotsu ^a   Sato, Seichi ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

Clay alteration; Deep geological disposal; Fe(III) montmorillonite; Magnetization; Swelling; Thermal stability; Tracer diffusion

Indexed keywords

ACTIVATION ENERGY; ADSORPTION; BEAMS AND GIRDERS; BENTONITE; CARBON STEEL; CHEMISORPTION; CLARIFICATION; CLAY; CLAY ALTERATION; DIFFUSION; INDUSTRIAL WASTE TREATMENT; IONIZATION OF LIQUIDS; IONS; IRON; IRON COMPOUNDS; MAGNETIZATION; MAGNETS; MINERALOGY; MINERALS; PHASE INTERFACES; POSITIVE IONS; RADIOACTIVE WASTE DISPOSAL; RADIOACTIVE WASTES; SILICA; SILICATE MINERALS; STEEL; SURFACE DIFFUSION; THEOREM PROVING; THERMODYNAMIC STABILITY; WASTE DISPOSAL; WATER; X RAY ANALYSIS; X RAY DIFFRACTION ANALYSIS;

ACID SITES; AMBIENT ATMOSPHERES; ANION EXCLUSIONS; BASIC PROPERTIES; BULK SAMPLES; CATION EXCHANGES; CONVENTIONAL TECHNIQUES; DEEP GEOLOGICAL DISPOSAL; DEEP GEOLOGICAL REPOSITORIES; DIFFUSION ACTIVATION ENERGIES; DIFFUSION COEFFICIENTS; DRY DENSITIES; ENGINEERED BARRIERS; FE(III)-MONTMORILLONITE; FREE WATERS; GRADUAL OXIDATIONS; INTER-LAYERS; INTERLAYER CATIONS; IONIC STATES; IRON OXY HYDROXIDES; MB ADSORPTIONS; METHYLENE BLUES; NUCLEAR WASTES; OSMOTIC SWELLINGS; OVERPACK; PARAMAGNETIC BEHAVIORS; PORE WATERS; THERMAL STABILITY; THERMOGRAVIMETRY; TRACER DIFFUSION; X-RAY DIFFRACTIONS;

CLAY MINERALS;

DIFFUSION; ION EXCHANGE; MAGNETIZATION; MINERAL ALTERATION; MONTMORILLONITE; REPOSITORY; SWELLING; TRACER;

EID: 58249126844     PISSN: 01691317     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.clay.2008.09.007     Document Type: Article

References (52)

1. Akcay M. The surface acidity and characterization of Fe-montmorillonite probed by in situ FT-IR spectroscopy of adsorbed pyridine. Appl. Catal. A-Gen., 294 (2005) 156-160
2. Bourg I.C., Sposito G., and Bourg A.C.M. Tracer diffusion in compacted water-saturated bentonite. Clays Clay Miner. 54 (2006) 363-374
3. Bourg I.C., Sposito G., and Bourg A.C.M. Modelling cation diffusion in compacted water-saturated sodium bentonite at low ionic strength. Environ. Sci. Technol. 41 (2007) 8118-8122
4. Callaway III W.-S., and McAtee Jr. J.-L. Magnetic susceptibility of representative smectites. Am. Mineral. 70 (1985) 996-1003
5. Carlson L., Karnland O., Oversby V.M., Rance A.P., Smart N.R., Snellman M., Vahanen M., and Werme L.O. Experimental studies of the interactions between anaerobically corroding iron and bentonite. Phys. Chem. Earth 32 1-7 (2007) 334-345
6. Cathelineau M., Guillaume D., Mosser-Ruck R., Dubessy J., Charpentier D., Villiéras F., and Michau N. Dissolution-crystallization processes affecting di-octahedral smectite in presence of iron metal: implication on mineral distribution in clay barriers. Int. Meeting on Clays in Natural and Engineered Barriers for Radioactive Waste Confinement. Tours, France (2005) 35
7. Cathelineau M., Mosser-Ruck R., Rousset D., Guillaume D., Charpentier D., Devineau K., Villieras F., and Michau N. Effects of temperature, pH, iron/clay ratio and liquid/clay ratio on the conversion of di-octahedral smectite into iron-rich clays: a review of experimental studies. Int. Meeting on Clays in Natural and Engineered Barriers for Radioactive Waste Confinement. Lille, France (2007) 103
8. Crank J. The Mathematics of Diffusion. 2nd edn. (1975), Clarendon Press, Oxford 11-21
9. Glaus M.A., Baeyens B., Bradbury M.H., Jakob A., Van Loon L.R., and Yaroshchuk A. Diffusion of Na and Sr in montmorillonite: evidence of interlayer diffusion being the dominant pathway at high compaction. Environ. Sci. Technol. 41 (2007) 478-485
10. Guillaume D., Neaman A., Cathelineau M., Mosser-Ruck R., Pfeiffert C., Abdeloula M., Dubessy J., Villéras F., Baronnet A., and Michau N. Experimental synthesis of chlorite from smectite at 300 °C in the presence of metallic Fe. Clay Miner. 38 (2003) 281-302
11. Guillaume D., Neaman A., Cathelineau M., Mosser-Ruck R., Pfeiffert C., Abdelmoula M., Dubessy J., Villiéras F., and Michau N. Experimental study of the transformation of smectite at 80 and 300 °C in the presence of Fe oxides. Clay Miner. 39 (2004) 17-34
12. Herrera R., and Peech M. Reaction of montmorillonite with iron (III). Proc. Soil Sci. Soc. Am. 34 (1970) 740-742
13. Ito, H., Manjanna, J., Kozaki, T., Sato, S., submitted for publication. A study on the hydraulic properties of compacted Fe(III)-montmorillonite. Appl. Clay Sci.
14. Izumi Y., Masih D., Aika K.I., and Seida Y. Characterization of intercalated iron(III) nanoparticles and oxidative adsorption of arsenite on them monitored by X-ray absorption fine structure combined with fluorescence spectrometry. J. Phys. Chem., B 109 8 (2005) 3227-3232
15. JNC (Japan Nuclear Cycle Development Institute) 2000. H12: safety assessment of the geological disposal system, Technical report TN1410, Japan Atomic Energy Agency.
16. Kamei G., Oda C., Mitsui S., Shibata M., and Shinozaki T. Fe(II)-Na ion exchange at interlayers of smectite: adsorption-desorption experiments and a natural analogue. Eng. Geol. 54 (1999) 15-20
17. Knight R.J., and Sylva R.N. Spectrophotometric investigation of iron(III) hydrolysis in light and heavy water at 25 °C. J. Inorg. Nucl. Chem. 37 3 (1975) 779-783
18. Komine H., and Ogata N. Prediction for swelling characteristics of compacted bentonite. Can. Geotech. J. 33 (1996) 11-22
19. Kozai N., Adachi Y., Kawamura S., Inada K., Kozaki T., Sato S., Ohashi H., Ohnuki T., and Banba T. Characterization of Fe(III)-montmorillonite: a simulant of buffer materials accommodating overpack corrosion product. J. Nucl. Sci. Technol. 38 (2001) 1141-1143
20. 2+-type montmorillonite: potential chemical species of iron contaminant. J. Solid State Chem. 180 (2007) 2279-2289
21. Kozaki T., Fujishima A., Sato S., and Ohashi H. Self-diffusion of sodium ions in compacted sodium montmorillonite. Nucl. Technol. 121 (1998) 63-69
22. Kozaki T., Sato Y., Nakajima M., Kato H., Sato S., and Ohashi H. Effect of particle size on the diffusion behavior of some radionuclides in compacted bentonite. J. Nucl. Mater. 270 (1999) 265-272
23. Kozaki T., Inada K., Sato S., and Ohashi H. Diffusion mechanism of chloride ions in sodium montmorillonite. J. Contam. Hydrol. 47 (2001) 159-170
24. Kraepiel A.-M.L., Keller K., and More F.-.M.M. A model for metal adsorption on montmorillonite. J. Colloid Interface Sci. 210 (1999) 43-54
25. Krishnamurti G.S.R., Violante A., and Huang P.M. Influence of montmorillonite on Fe(II) oxidation products. Clay Miner. 33 2 (1998) 205-212
26. Lantenois S., Lanson B., Muller F., Bauer A., Jullien M., and Plancon A. Experimental study of smectite interaction with metal Fe at low temperature: 1. Smectite destabilization. Clays Clay Miner. 53 6 (2005) 597-612
27. Lenoble V., Bouras O., Deluchat V., Serpaud B., and Bollinger J.-C. Arsenic adsorption onto pillared clays and iron oxides. J. Colloid Inter. Sci. 255 1 (2002) 52-58
28. Mackay K.M., Mackay R.A., and Henderson W. Introduction to Modern Inorganic Chemistry. 6th ed. (2002), Nelson Thornes Ltd., London 134
29. Manjanna J. Preparation of Fe(II)-montmorillonite by reduction of Fe(III)-montmorillonite with ascorbic acid. Appl. Clay Sci. (2008) 10.1016/j.clay.2008.02.005
30. Manjanna J., Kozaki T., Kozai N., and Sato S. A new method for Fe(II)-montmorillonite preparation using Fe(II)-nitrilotriacetate complex. J. Nucl. Sci. Technol. 44 7 (2007) 929-932
31. Martin F.A., Bataillon C., and Schegel M.L. Corrosion of iron and low alloyed steel within a water saturated brick of clay under anaerobic deep geological disposal conditions: an integrated experiment. J. Nucl. Mater. (2008) 10.1016/j.jnucmat.2008.06.021
32. McBride M.B. Environmental Chemistry of Soils (1994), Oxford press, New York 406
33. Nakazawa T., Takano M., Nobuhara A., Torikai Y., Sato S., and Ohashi H. Activation energies of diffusion of tritium and electrical conduction in water-saturated compacted sodium montmorillonite. 7th Int. Conf. on Radioactive Waste Management and Environmental Remediation, ASME International. Nagoya, Japan (1999)
34. Parsons R. Handbook of Electrochemical Constants (1959), Butterworth, London 79
35. Pusch R. Waste Disposal in Rock (1994), Elsevier, New York
36. Pusch R., Karnland O., and Muurinen A. Swedish nuclear fuel and waste management. SKB Tech. Rep. (1989) 34-89
37. Rowe R.K., Quigley R.M., and Booker J.R. Clayey Barrier System for Waste Disposal Facilities (1995), E & FN Spon, London
38. 3+ in dioctahedral smectites-III: oxidation of octahedral iron in montmorillonite. Clays Clay Miner. 26 2 (1978) 88-92
39. Santamarina J.C., Klein K.A., Wang Y.H., and Prencke E. Specific surface: determination and relevance. Can. Geotech. J. 39 1 (2002) 233-241
40. Sato H., Ashida T., Kohara Y., Yui M., and Sasaki N. Effect of dry density on diffusion of some radionuclides in compacted sodium bentonite. J. Nucl. Sci. Technol. 29 (1992) 873-882
41. Schlegel M.L., Bataillon C., Benhamida K., Blanc C., Menut D., and Lacour J.-L. Metal corrosion and argillite transformation at the water-saturated, high-temperature iron-clay interface: a microscopic-scale study. Appl. Geochem. 23 (2008) 2619-2633
42. Smith R.M., and Martell A.E. Critical stability constants. Other Organic Ligands vol. 3 (1976), Plenum Press, New York
43. 3+-montmorillonite as a cost-effective and recyclable solid acidic catalyst for the synthesis of xanthenediones. Catal. Commun. 8 (2007) 673-676
44. Suzuki S., Prayongphan S., Ichikawa Y., and Chae B.G. In-situ observations of the swelling of bentonite aggregates in NaCl solution. Appl. Clay Sci. 22 6 (2005) 89-98
45. Tabet D., Saidi M., Houari M., Pichat P., and Khalaf H. Fe-pillared clay as a Fenton-type heterogeneous catalyst for cinnamic acid degradation. J. Environ. Manag. 80 4 (2006) 342-346
46. - in a highly compacted argillaceous rock (Opalinus clay). Appl. Geochem. 20 5 (2005) 961-972
47. Watanabe T., and Sato T. Expansion characteristics of montmorillonite and saponite under various relative humidity conditions. Clay Sci. 7 (1998) 129-138
48. Wersin P., Johnson L.H., and Snellman M. Impact of iron released from steel components on the performance of the bentonite buffer: a preliminary assessment within the framework of the KBS-3H disposal concept. Mater. Res. Soc. Symp. Proc. 932 (2005) 95-102
49. Wilson J., Cressey G., Cressey B., Cuadros J., Ragnarsdottir K.V., Savage D., and Shibata M. The effect of iron on montmorillonite stability: (II) experimental investigation. Geochim. Cosmochim. Acta 70 (2006) 323-336
50. Wilson J., Savage D., Cuadros J., Shibata M., and Ragnarsdottir K.V. The effect of iron on bentonite stability: (I) background and thermodynamic considerations. Geochim. Cosmochim. Acta 70 2 (2006) 306-322
51. Xu D., Tan X.L., Chen C.L., and Wang X.K. Adsorption of Pb(II) from aqueous solution to MX-80 bentonite: effect of pH, ionic strength, foreign ions and temperature. Appl. Clay Sci. (2007) 10.1016/j.clay.2007.09.004
52. Yamanaka S., and Hattori M. Iron oxide pillared clay. Catal. Today 2 (1988) 261-270