Prediction of surface ocean pCO2 from observations of salinity temperature and nitrate: The Empirical model perspective

Ocean Science Journal

Volumn 43, Issue 4, 2008, Pages 195-208

  Lee, Hyun Woo ^a   Lee, Kitack ^a   Lee, Bang Yong ^b  

^a Pohang University of Science and Technology (POSTECH)   (South Korea)

^b Korea Research Institute of Ships and Ocean Engineering   (South Korea)

Author keywords

Global carbon cycle; PCO2; Remote sensing; Total alkalinity; Total inorganic carbon

Indexed keywords

ALKALINITY; CARBON CYCLE; EMPIRICAL ANALYSIS; GLOBAL CHANGE; PARTIAL PRESSURE; PREDICTION; REMOTE SENSING; SEA SURFACE TEMPERATURE; SEASONAL VARIATION; THERMODYNAMICS;

EID: 58149515800     PISSN: 17385261     EISSN: None     Source Type: Journal    
DOI: 10.1007/BF03029924     Document Type: Article

References (51)

1. Antonov, J.I., R.A. Locarnini, T.P. Boyer, A.V. Mishonov, and H.E. Garcia. 2006. World Ocean Atlas 2005, Volume 2: Salinity. S. Levitus, Ed. NOAA Atlas NESDIS 62, U.S. Government Printing Office, Washington, D.C. 182 p.
2. Bakker, D.C.E., H.J.W. De Baar, and E. De Jong. 1999. The dependence on temperature and salinity of dissolved inorganic carbon in East Atlantic surface waters. Mar. Chem., 65, 263-280.
3. 2 and biogeochemical properties in the Western North Atlantic subtropical gyre. Deep-Sea Res. II, 48, 1507-1528.
4. 2. Geophys. Res. Lett., 29(5). 1059, doi: 10.1029/2001GL013571.
5. 2 gas exchange, Global Biogeochem. Cycles, 20, GB3020, doi:10.1029/2005GB002491.
6. 2 on diel to seasonal timescales in the Sargasso Sea near Bermuda. J. Geophys. Res., 103, 15567-15595.
7. 2-SST relationships. J. Geophys. Res., 108(C8), 3278, doi:10.1029/2000JC000677.
8. Dickson, A.G. and F.J. Millero. 1987. A comparison of the equilibrium constants for the dissociation of carbonic acid in seawater media. Deep-Sea Res. I, 34, 1733-1743.
9. 2 sink in the subtropical North Pacific Ocean. Nature, 424, 754-757.
10. 2 accumulation. Nature, 398, 597-601.
11. 2 fluxes in the equatorial Pacific Ocean. J. Geophys. Res., 111, C08S90, doi:10.1029/2005JC003129.
12. Gabarró, C., J. Font, A. Camps, M. Vall-Ilossera, and A. Julia. 2004. A new empirical model of sea surface microwave emissivity for salinity remote sensing. Geophys. Res. Lett., 31, L01309, doi:10.1029/2003GL018964.
13. Garcia, H.E., R.A. Locarnini, T.P. Boyer, and J.I. Antonov. 2006. World Ocean Atlas 2005, Volume 4: Nutrients (phosphate, nitrate, silicate). S. Levitus, Ed. NOAA Atlas NESDIS 64, U.S. Government Printing Office, Washington, D.C. 396 p.
14. Gould, J. and the Argo Science Team. 2004. Argo profiling floats bring new era of in situ ocean observations. EOS, 85, 179, 190-191.
15. Gruber, N., C.D. Keeling, and N.R. Bates. 2002. Interannual variability in the North Atlantic Ocean carbon sink. Science, 298, 2374-2378.
16. 2) in surface waters of the western North Pacific, 1984-1993. Tellus, Ser. B, 47, 391-413.
17. 2 Parameters in the Western and Central Equatorial Pacific. p. 59-94. In: Global Environmental Change in the Ocean and on Land. ed. by M. Shiyomi, H. Kawahata, H. Koizumi, A. Tsuda, and Y. Awaya, TERRAPUB, Tokyo.
18. Keeling, C.D., H. Brix, and N. Gruber. 2004. Seasonal and longterm dynamics of the upper ocean carbon cycle at Station ALOHA near Hawaii, Global Biogeochem. Cycles, 18, GB4006, doi:10.1029/ 2004GB002227.
19. 2 concentration. Nature, 281, 218-221.
20. Kilpatrick, K.A., G.P. Podestá, and R. Evans. 2001. Overview of the NOAA/NASA advanced very high resolution radiometer Pathfinder algorithm for sea surface temperature and associated matchup database. J. Geophys. Res., 106, 9179-9198.
21. Koblinksky, C.J., P. Hildebrand, D. LeVine, F. Pellerano, Y. Chao, W. Willson, S. Yueh, and G. Lagerloef. 2003. Sea surface salinity from space: Science goals and measurement approach. Radio Sci., 38(4), 8064, doi: 10.1029/2001RS002584.
22. 2 disequilibrium for spring through summer, 1985-1989. J Geophys. Res., 101, 28539-28555.
23. Lee, K., F.J. Millero, and D.M. Campbell 1996. The reliability of the thermodynamic constants for the dissociation of carbonic acid in seawater. Mar Chem., 55, 233-245.
24. Lee, K., F.J. Millero, and R. Wanninkhof. 1997. The carbon dioxide system in the Atlantic Ocean. J. Geophys. Res. 102, 15693-15707.
25. Lee, K., R. Wanninkhof, T. Takahashi, S.C. Doney, and R.A. Feely. 1998. Low interannual variability in recent oceanic uptake of atmospheric carbon dioxide. Nature, 396, 155-159.
26. Lee, K., R. Wanninkhof, R.A. Feely, F.J. Millero, and T.-H. Peng. 2000a. Global relationships of total inorganic carbon with temperature and nitrate in surface seawater. Global Biogeochem. Cycles, 14(3), 979-994.
27. Lee, K., F.J. Millero, R.H. Byrne, R.A. Feely, and R. Wanninkhof. 2000b. The recommended dissociation constants for carbonic acid in seawater. Geophys. Res. Lett., 27(2), 229-232.
28. Lee, K., L. Tong, F.J. Millero, C.L. Sabine, A.G. Dickson, C. Goyet, G.-H. Park, R. Wanninkhof, R.A. Feely, and R.M. Key. 2006. Global relationships of total alkalinity with salinity and temperature in surface waters of the world's oceans. Geophys. Res. Lett., 33, L19605, doi: 10.1029/2006GL026994.
29. 2 from sea surface temperatures in the Atlantic gyres. Deep-Sea Res. I, 49, 539-554.
30. 2 fluxes estimated from temperature and salinity data. Geophys. Res. Lett., 27(12), 1735-1738.
31. 2 in gas and seawater at equilibrium. Mar. Chem, 70, 105-119.
32. McNeil, B.I., N. Metzl, R.M. Key, R.J. Matear, and A. Corbiere. 2007. An empirical estimate of the Southern Ocean air-sea CO2 flux. Global Biogeochem. Cycles, 21, GB3011, doi:10.1029/2007GB002991.
33. Mehrbach, C., C.H. Culberson, J.E. Hawley, and R.M. Pytkowicz. 1973. Measurement of the apparent dissociation constants of carbonic acid in seawater at an atmospheric pressure. Limnol. Oceanogr., 18, 897-907.
34. 2 fluxes in the Southern Ocean. Deep-Sea Res. I, 53, 1548-1563.
35. Millero, F.J., D. Pierrot, K. Lee, R. Wanninkhof, R. Feely, C.L. Sabine, R.M. Key, and T. Takahashi. 2002. Dissociation constants for carbonic acid determined from field measurements. Deep-Sea Res. I, 49, 1705-1723.
36. Millero, F.J., T.B. Graham, F. Huang, H. Bustos-Serrano, and D. Pierrot. 2006. Dissociation constants of carbonic acid in seawater as a function of salinity and temperature. Mar. Chem, 100, 80-94.
37. 2 for the dissociation of carbonic acid in seawater. Geochim. Cosmochim. Acta, 66, 2529-2540.
38. Olsen, A., R.G.J. Bellerby, T. Johannessen, A.M. Omar, and I. Skjelvan. 2003. Interannual variability in the wintertime airsea flux of carbon dioxide in the northern North Atlantic. 1981-2001, Deep-Sea Res. I, 50, 1323-1338.
39. 2 over the past 2 decades. J. Geophys. Res., 111, C07S07, doi:10.1029/2005JC003090.
40. 2 and in the western Indian and Southern Oceans during the year 1991. J. Geophys. Res., 98, 22759-22778.
41. 2: Carbon-13 evidence. Science, 256, 74-79.
42. 2. Science, 305, 367-371.
43. 2 distribution using satellite sea surface temperature, Chl a, and climatological salinity in the North Pacific in spring and summer. Global Biogeochem. Cycles, 20, GB3005, doi:10.1029/2005GB002594.
44. 2 in the North Pacific using shipboard and satellite data. J. Geophys. Res., 100, 13571-13583.
45. 2 difference. Proc. Natl. Acad. Sci., 94, 8292-8299.
46. 2, and seasonal biological and temperature effects. Deep-Sea Res. II, 49, 1601-1622.
47. 2 in the North Pacific: A synthesis of 35 years of observations. J. Geophys. Res., 111, C07S05, doi:10.1029/2005JC003074.
48. 2 budget. Science, 247, 1431-1438.
49. Tsurushima, N., Y. Nojiri, K. Imai, and S. Watanabe. 2002. Seasonal variations of carbon dioxide system and nutrients in the surface mixed layer at station KNOT (44°N, 155°E) in the subarctic western North Pacific. Deep-Sea Res. II, 49, 5377-5394.
50. 2 from alkalinity and total inorganic carbon. Mar. Chem., 65, 291-301.
51. 2 distributions in the northern North Pacific using results from a commercial vessel in 1995-1999. Deep-Sea Res. II, 49, 5303-5315.