The reliability of the thermodynamic constants for the dissociation of carbonic acid in seawater

Marine Chemistry

Volumn 55, Issue 3-4, 1996, Pages 233-245

  Lee, Kitack ^a   Millero, Frank J ^a   Campbell, Douglas M ^a  

^a UNIVERSITY OF MIAMI   (United States)

Author keywords

carbonic acid; fugacity of CO2; spectrophotometric pH; thermodynamic constants; total alkalinity; total inorganic carbon

Indexed keywords

CARBONIC ACID; DISSOCIATION; RELIABILITY; THERMODYNAMIC CONSTANTS;

EID: 0030302071     PISSN: 03044203     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0304-4203(96)00064-3     Document Type: Article

References (35)

1. Campbell, D.M., Millero, F.J., Roy, R., Roy, L., Lawson, M., Vogel, K.M. and Porter-Moore, C., 1993. The standard potential for the hydrogen-silver, silver chloride electrode in synthetic seawater. Mar. Chem., 44: 221-233.
2. 2-system characteristics in seawater. Deep-Sea Res., 40: 2115-2129.
3. 2-system characterizations: Precision and thermodynamic consistency. Deep-Sea Res., 42: 411-429.
4. 2 in seawater. Mar. Chem., 25: 29-37.
5. - in synthetic sea water from 273.15 to 318.15 K. Chem. Thermodyn., 22: 113-127.
6. Dickson, A.G., 1993. pH buffers for sea water media based on the total hydrogen ion concentration scale, Deep-Sea Res., 40: 107-118.
7. Dickson, A.G. and Millero, F.J., 1987. A comparison of the equilibrium constants for the dissociation of carbonic acid in seawater media. Deep-Sea Res., 34: 1733-1743.
8. Dickson, A.G. and Riley, J.P., 1978. The effect of analytical error on the evaluation of the components of the aquatic carbon-dioxide system. Mar. Chem., 6: 77-85.
9. w. Mar. Chem., 7: 89-99.
10. Gordon, L.I. and Jones, L.B., 1973. The effect of temperature on carbon dioxide partial pressure in seawater. Mar. Chem., 1: 317-322.
11. Goyet, C. and Poisson, A., 1989. New determination of carbonic acid dissociation constants in seawater as a function of temperature and salinity. Deep-Sea Res., 36: 1635-1654.
12. 2 fugacity in seawater. Mar. Chem., 44: 205-219.
13. Hansson, I., 1973. A new set of acidity constants for carbonic acid and boric acid in sea water. Deep-Sea Res., 20: 461-478.
14. Johnson, K.M., Sieburth, J., McNeal, Williams, P.J. LeB. and Brändström, L., 1987. Coulometric total carbon dioxide analysis for marine studies: automation and calibration. Mar. Chem., 21: 117-133.
15. Johnson, K.M., Wills, K.D., Butler, D.B., Johnson, W.K. and Wong, C.S., 1993. Coulometric total carbon dioxide analysis for marine studies: maximizing the performance of an automated gas extraction system and coulometric detector. Mar. Chem., 44: 167-187.
16. Lee, K. and Millero, F.J., 1995. The thermodynamic studies of the carbonate system in seawater. Deep-Sea Res., 42: 2035-2061.
17. Lee, K., Millero, F.J. and Wanninkhof, R., 1996. The carbon dioxide system in the Atlantic ocean. J. Geophys. Res., submitted.
18. Mehrbach, C., Culberson, C.H., Hawley, J.E. and Pytkowicz, R.M., 1973. Measurement of the apparent dissociation constants of carbonic acid in seawater at atmospheric pressure. Limnol. Oceanogr., 18: 897-907.
19. Millero, F.J., 1982. The thermodynamics of seawater at one atmosphere. Ocean Sci. Eng., 7: 403-460.
20. Millero, F.J., 1995. Thermodynamics of the carbon dioxide system in the oceans. Geochim. Cosmochim. Acta, 59: 661-677.
21. Millero, F.J. and Poisson, A., 1988. International one-atmosphere equation of state of seawater. Deep-Sea Res., 28: 625-629.
22. 2 measurements in the Equatorial Pacific. Mar. Chem., 44: 269-280.
23. Millero, F.J., Zhang, J.Z., Fiol, S., Sotolongo, S., Roy, R., Lee., K. and Mane, S., 1993b. The use of buffers to measure the pH of seawater. Mar. Chem., 44: 143-152.
24. Millero, F.J., Zhang, J.Z., Lee, K. and Campbell, D.M., 1993c. Titration alkalinity of seawater. Mar. Chem., 44: 153-165.
25. 2 system: an evaluation of ten methods of investigation. Limnol. Oceanogr., 14: 179-186.
26. Roy, R.N., Roy, L.N., Lawson, M., Vogel, K.M., Porter-Moore, C., Pearson, T., Good, C.E., Millero, F.J. and Campbell, D.M., 1993. Determination of the ionization constants of carbonic acid in seawater. Mar. Chem., 44: 249-259.
27. 2 measurements. Fin. Rep., SCOR Working Group 75, 37 pp.
28. 2 and nutrients in the high-latitude surface oceans: a comparative study. Global Biogeochem. Cycles, 7: 843-878.
29. UNESCO, 1987. Thermodynamics of the carbon dioxide system in seawater. Report by the Carbon Dioxide Sub-panel of the Joint Panel on Oceanographic Tables and Standards. UNESCO Techn. Pap. Mar. Sci., No. 51, 55 pp.
30. 2 Measurements of the Joint Panel on Oceanographic Tables and Standards. UNESCO Tech. Pap. Mar. Sci., No. 60, 41 pp.
31. Uppström, L.R., 1974. Boron/chlorinity ratio of deep-sea water from the Pacific Ocean. Deep-Sea Res., 21: 161-162.
32. 2 in surface water using continuous and discrete sampling methods. Mar. Chem., 44: 189-204.
33. Weiss, R.F., 1974. Carbon dioxide in water and seawater - The solubility of a non-ideal gas. Mar. Chem., 2: 203-215.
34. 2 and methane by dual catalyst flame ionization chromatography and nitrous oxide by electron capture chromatography. J. Chromatogr. Sci., 19: 611-616.
35. 2 in seawater. Nature (London), 300: 511-513.