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One alkene isomer was observed. We have assigned the product as the Z-alkene isomer because this configuration should minimize steric interactions. Spectroscopic experiments, however, showed no NOE between the vinyl hydrogen and the carboethoxy groups, so this assignment has not been established unambiguously
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One alkene isomer was observed. We have assigned the product as the Z-alkene isomer because this configuration should minimize steric interactions. Spectroscopic experiments, however, showed no NOE between the vinyl hydrogen and the carboethoxy groups, so this assignment has not been established unambiguously.
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24
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20544466457
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Copper salts have been employed in protodesilylation reactions: Trost, B. M.; Ball, Z. T.; Jöge, T. J. Am. Chem. Soc. 2002, 124, 7922-7923.
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Copper salts have been employed in protodesilylation reactions: Trost, B. M.; Ball, Z. T.; Jöge, T. J. Am. Chem. Soc. 2002, 124, 7922-7923.
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