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In principle, the aurachin intermediate III (Scheme 2) could also rearrange to the 2-farnesyl isomer. However, this appears to be disfavored by the 2-methyl and N-oxide groups.
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In principle, the aurachin intermediate III (Scheme 2) could also rearrange to the 2-farnesyl isomer. However, this appears to be disfavored by the 2-methyl and N-oxide groups.
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