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The magnetic susceptibility between 300 and 2 K of a large single-crystal specimen was measured using a Quantum Design physical properties measurement system. These susceptibility results showed that the material was paramagnetic over the entire range of the measurements and no magnetic transitions were found.
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The magnetic susceptibility between 300 and 2 K of a large single-crystal specimen was measured using a Quantum Design physical properties measurement system. These susceptibility results showed that the material was paramagnetic over the entire range of the measurements and no magnetic transitions were found.
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The X-ray single crystal structural refinement was carried out using Mo-Kα radiation (λ, 0.71073 Å) a T, 173K with a numerical absorption correction, μ(Mo-Kα, 4.24 cm-1 and a transmission of 0.362-0.652. The data were collected using a Bruker SMART APEX CCD diffractometer. The pertinent data collection information is 16040 measured reflections, 3110 unique reflections (Rint, 0.0183, 3053 observed reflections (I > 2.00 σI, 130 parameters, R, 0.014. wR, 0.034, refined against F2, and GOF, 1.091. The SHELXTL Version 5 series of programs was used for the solution and refinement of the crystal structure. The hydrogen positions of the methyl groups were fixed at ideal positions and the methyl group orientation was determined by a difference electron density synthesis. The hydroxyl hydrogen atoms were located and refined
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2, and GOF = 1.091. The SHELXTL Version 5 series of programs was used for the solution and refinement of the crystal structure. The hydrogen positions of the methyl groups were fixed at ideal positions and the methyl group orientation was determined by a difference electron density synthesis. The hydroxyl hydrogen atoms were located and refined.
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