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The recent paper of Cossy C., Helm L., Powell D. H., Merbach A. E. (New J. Chem., 1995, 19, 27) confirms this old concept very well: neutron diffraction studies of lanthanide perchlorates in heavy water suggest high coordination numbers for the cations (9-8) and the strong radial orientation of water molecules around the ions is interpreted in terms of high cation charge.
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0001337321
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The hydration numbers of light lanthanides perchlorates vary from 10 to 13 (Jeżowska-Trzebiatowska B., Ernst S., Legendziewicz J., Oczko G., Bull. Acad. Pol. Sci.: Chem., 1978, 26, 805), while those of heavy lanthanides are between 11.7 and 13
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0006286027
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These numbers are comparable to those obtained by the same method for aqueous lanthanide chlorides, which vary from 16.8 to 19.4 depending on the lanthanide (Oczko G., Legendziewicz J., Jeżowska-Trzebiatowska B., Ernst S., Bull. Acad. Pol. Sci.: Chem., 1980, 28, 793) (in the case of chlorides the authors suggest that the anion solvation number (≅ 6) should be subtracted from the above numbers to obtain those of the cations).
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