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Volumn 21, Issue 3, 1997, Pages 329-333

Solvation of lanthanide salts. Anhydrous neodymium perchlorate in methanol

Author keywords

Anhydrous neodymium perchlorate; Compressibility; Conductivity; Dielectric relaxation; Electrolytes; Electronic spectroscopy; Electrostriction; Ion pairs; Lanthanides; Methanol; Nonaqueous solutions; Solvation number; Sound velocity

Indexed keywords


EID: 0000618449     PISSN: 11440546     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article
Times cited : (10)

References (42)
  • 13
    • 0008927109 scopus 로고
    • World Scientific, Strek W., Ryba-Romanowski W., Legendziewicz J., Jeżowska-Trzebiatowska B., Eds.
    • Keller B., Legendziewicz J., Oczko G. In Excited States of Transition Elements, World Scientific, Strek W., Ryba-Romanowski W., Legendziewicz J., Jeżowska-Trzebiatowska B., Eds., 1992, 354.
    • (1992) Excited States of Transition Elements , pp. 354
    • Keller, B.1    Legendziewicz, J.2    Oczko, G.3
  • 21
    • 0002085716 scopus 로고
    • The recent paper of Cossy C., Helm L., Powell D. H., Merbach A. E. (New J. Chem., 1995, 19, 27) confirms this old concept very well: neutron diffraction studies of lanthanide perchlorates in heavy water suggest high coordination numbers for the cations (9-8) and the strong radial orientation of water molecules around the ions is interpreted in terms of high cation charge.
    • (1995) New J. Chem. , vol.19 , pp. 27
    • Cossy, C.1    Helm, L.2    Powell, D.H.3    Merbach, A.E.4
  • 27
    • 0006286027 scopus 로고
    • These numbers are comparable to those obtained by the same method for aqueous lanthanide chlorides, which vary from 16.8 to 19.4 depending on the lanthanide (Oczko G., Legendziewicz J., Jeżowska-Trzebiatowska B., Ernst S., Bull. Acad. Pol. Sci.: Chem., 1980, 28, 793) (in the case of chlorides the authors suggest that the anion solvation number (≅ 6) should be subtracted from the above numbers to obtain those of the cations).
    • (1980) Bull. Acad. Pol. Sci.: Chem. , vol.28 , pp. 793
    • Oczko, G.1    Legendziewicz, J.2    Jezowska-Trzebiatowska, B.3    Ernst, S.4
  • 42
    • 27844462109 scopus 로고
    • Ph. D. thesis, Wrocław University, Wrocław, Poland, See also ref 8
    • Keller B., Ph. D. thesis, Wrocław University, Wrocław, Poland, 1975. See also ref 8.
    • (1975)
    • Keller, B.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.