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Volumn , Issue 36, 2008, Pages 5609-5616

Isostructural potassium and thallium salts of sterically crowded thio- and selenophenols: A structural and computational study

Author keywords

Pi interactions; Potassium; S ligands; Se ligands; Terphenyl ligands; Thallium

Indexed keywords

CHEMICAL BONDS; COMPUTATION THEORY; DENSITY FUNCTIONAL THEORY; POTASSIUM COMPOUNDS; SALTS; SELENIUM;

EID: 57749085561     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200800756     Document Type: Article
Times cited : (6)

References (56)
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    • For example, M2SO4. The halides MX (X = Cl, Br, I) crystallize in the rock salt (most stable for M = K) and cesium chloride (most stable for M = Tl) structure. In addition, TlF and yellow TlI adopt distorted forms of the sodium chloride structure. See: A. F. Wells, Structural Inorganic Chemistry, 5th ed., Clarendon Press, Oxford, 1984.
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    • For other compounds that show interactions between potassium cations and arene rings of Trip substituents, see ref.[24] and the following examples. Herein, the K⋯centroid distances fall in the range 2.74-3.19 Å: a W. J. Grisby, P. P. Power, J. Am. Chem. Soc. 1996, 118, 7981-7988;
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    • Cambridge Structural Database, London, UK, 2008. For the search, the range of Tl⋯centroid-C angles was constrained to 85-95°, assuming only small ring slippage. For a larger ring slippage there appears to be no upper limit to the Tl⋯centroid distances.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.