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For other compounds that show interactions between potassium cations and arene rings of Trip substituents, see ref.[24] and the following examples. Herein, the K⋯centroid distances fall in the range 2.74-3.19 Å: a W. J. Grisby, P. P. Power, J. Am. Chem. Soc. 1996, 118, 7981-7988;
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Cambridge Structural Database, London, UK, 2008. For the search, the range of Tl⋯centroid-C angles was constrained to 85-95°, assuming only small ring slippage. For a larger ring slippage there appears to be no upper limit to the Tl⋯centroid distances.
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