Synthetic studies toward miroestrols: trials for elongation of the methyl group of 5-substituted 2-methyl-2-cyclohexanone to 3-methyl-2-butenyl function

Tetrahedron

Volumn 65, Issue 4, 2009, Pages 771-785

  Ito, Fumihiro ^a,b   Kumamoto, Takuya ^a   Yamaguchi, Kentaro ^b   Ishikawa, Tsutomu ^a  

^a CHIBA UNIVERSITY   (Japan)

^b TOKUSHIMA BUNRI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

2 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANYLOXY)PHENYL] 1 [(2 METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 7 METHYL 1,2,3,4 TETRAHYDRONAPHTHALENE; 3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANYLOXY)BENZYLIDENE] 6 METHYL 2,3,3A,7A TETRAHYDRO 4H BENZO[B]FURAN 7-ONE; 4 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANYLOXY)PHENYL] 1 [(2 METHOXYETHOXY) METHOXY] 2 PROPEN 2 YL] 1 (3 METHYL 3 BUTEN 1 YL) 5 CYCLOHEXEN 1,2 DIOL; 4 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANYLOXY)PHENYL] 1 [(2 METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 1 (3 METHYL 2 BUTEN 1 YL) CYCLOHEXANE 1,2 DIOL; 4 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANYLOXY)PHENYL] 1 [(2 METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 1 METHYL 6 (2 METHYL 2 PROPEN 1 YL) 6 TRIMETHYLSILANYLOXYCYCLOHEXENE; 4 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANYLOXY)PHENYL] 1 [(2 METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 1,2 (DIMETHYLMETHYLENEDIOXY) 1 (3 METHYL 3 BUTEN 1 YL) CYCLOHEXANE; 4 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANYLOXY)PHENYL] 1 [(2 METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 1,6 EPOXY 1 METHYL 2 (2 METHYL 2 PROPEN 1 YL) 2 TRIMETHYLSILANYLOXYLCYCLOHEXANE; 4 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANYLOXY)PHENYL] 1 [(2 METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 2,3 EPOXY 1 (3 METHYL 3 BUTEN 1 YL)CYCLOHEXAN 1,6 DIOL; 4 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANYLOXY)PHENYL] 1 [(2 METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 2,3 EPOXY 1 METHYLCYCLOHEXAN 1,6 DIOL; 4 ISOPROPENYL 1 METHYL 6 (2 METHYL 2 PROPEN 1 YL) 6 TRIMETHYLSILANLYLOXYCYCLOHEXENE; 5 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANOXY)PHENYL] 1 [(2 METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 2,3 EPOXY 2 METHYLCYCLOHEXANOL; 5 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANOXY)PHENYL] 1 [(2 METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 3 (2 METHYL 2 PROPEN 1 YL) 2 METHYLENE 3 TRIMETHYLSILANYLOXY 1 CYCLOHEXANOL; 5 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANOXY)PHENYL] 1 [(METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 2 METHYL1 (2 METHYL 2 PROPEN 1 YL) 3 CYCLOHEXEN 1,2 DIOL; 5 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANYLOXY) PHENYL] 1 [(METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 2 METHYLENE 1 (2 METHYL 2 PROPEN 1 YL) 1,3 CYCLOHEXADIOL; 5 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANYLOXY) PHENYL] 1 HYDROXY 2 PROPEN 2 YL] 2 HYDROXY 2 METHYLCYCLOHEXAN 1 ONE; 5 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANYLOXY)PHENYL] 1 [(2 METHOXYETHOXY) METHOXY] 2 PROPEN 2 YL] 2,3 EPOXY 2 METHYL 1 (2 METHYL 2 PROPEN 1 YL)CYCLOHEXANOL; 5 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANYLOXY)PHENYL] 1 [(2 METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 2 METHYL 1 (2 METHYL 2 PROPEN 1 YL) 2 CYCLOHEXENOL; 5 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANYLOXY)PHENYL] 1 [(2 METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 2,3 EPOXY 2 (3 METHYL 3 BUTEN 1 YL)CYCLOHEXANONE; 5 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANYLOXY)PHENYL] 1 [(2 METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 2,3 EPOXY 2 METHYLCYCLOHEXANONE; 5 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANYLOXY)PHENYL] 1 [(METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 2 ISOPROPYLOXYMETHYL 3 (2 METHYL 2 PROPEN 1 YL) 2 CYCLOHEXEN 1 OL; 5 [3 [2 BENZYLOXY 4 (TERT-BUTYLDIPHENYLSILANYLOXY)PHENYL] 1 [(2-METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 2METHYLENECYCLOHEXANE 1,3 DIOL; 5 [3 [2 BENZYLOXY 4 (TERTBBUTYLDIPHENYLSILANYLOXY) PHENYL] 1 [(2 METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 2 HYDROXY 2 METHYLCYCLOHEXAN 1 ONE; 5 [3 [2 BENZYLOXY 4 (TERTBUTYLDIPHENYLSILANYLOXY)PHENYL] 1 [(METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 2 METHYLENE 1 (2 METHYL 2 PROPEN 1 YL) 1,3 CYCLOHEXADIOL; 5 [3 [2 BENZYLOXY 4 HYDROXYPHENYL] 1 [(2 METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 2 METHYL 1 (2 METHYL 2 PROPEN 1 YL) 2 CYCLOHEXENOL; 5 ISOPROPENYL 2 METHYL 1 (2 METHYL 2 PROPEN 1 YL)2 CYCLOHEXEN 1 OL; 5 ISOPROPENYL 2 METHYL 3 (2 METHYL 2 PROPEN 1 YL) 1 TRIMETHYLSILANYLOXYCYCLOHEXENE; 5[3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANYLOXY) PHENYL] 1 [(2 METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 3 (2 METHYL 2 PROPEN 1 YL) 2 METHYLENE 3 TRIMETHYLSILANYLOXY 1 CYCLOHEXANOL; 6 [3 [2 BENZYLOXY 4 (TERT BUTYLDIPHENYLSILANOXY)PHENYL] 1 [(2 METHOXYETHOXY)METHOXY] 2 PROPEN 2 YL] 3 METHYL 1,4,4A,5,6,7 HEXAHYDRONAPHTHAEN- A OL; CYCLOHEXANONE DERIVATIVE; UNCLASSIFIED DRUG; UNINDEXED DRUG;

ARTICLE; ISOMERIZATION; PRIORITY JOURNAL; RING OPENING; SYNTHESIS;

EID: 57649216597     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2008.11.055     Document Type: Article

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