Diene-transmissive hetero-Diels-Alder cycloaddition using cross-conjugated dioxatrienes: A novel synthesis of tetrahydropyran-fused aza-and thia-heterocycles

Heterocycles

Volumn 76, Issue 1, 2008, Pages 227-235

  Saito, Takao ^a   Kobayashi, Satoru ^a   Otani, Takashi ^a   Iwanami, Hideoki ^a   Soda, Takayuki ^a  

^a TOKYO UNIVERSITY OF SCIENCE   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 57649112300     PISSN: 03855414     EISSN: 18810942     Source Type: Journal    
DOI: 10.3987/COM-08-S(N)55     Document Type: Article

References (59)

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52. 3: C, 74.70; H, 5.96; N, 4.36. Found: C, 74.39; H, 6.09; N, 4.45.
53. (Acyloxymethylene) propanedials (1b, c) were prepared by the reaction of triformylmethane with acyl anhydride in the presence of a small amount of pyridine.
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56. 2), 74.30 (CH), 98.90 (CH), 109.99 (C), 114.27 (CH×2), 124.71 (CH), 127.69 (CH×2), 129.09 (CH×2), 129.14 (CH×2), 131.77 (C), 136.38 (C), 144.38 (C), 147.49 (C), 158.85 (C), 169.27 (C).
57. +, 4).
58. 4S: C, 68.06; H, 5.95; N, 3.31. Found: C, 67.85; H, 6.08; N, 3.27.
59. + 457.1199, Found: 457.1207.