An ansa-heteroborabenzene divalent lanthanide amide through C-H bond cleavage

Angewandte Chemie - International Edition

Volumn 47, Issue 51, 2008, Pages 9944-9947

  Cui, Peng ^a   Chen, Yaofeng ^a   Li, Guangyu ^a   Xia, Wei ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

Amides; Boron; Bridging ligands; Heterocycles; Lanthanides

Indexed keywords

AMIDES; BORON; BORON COMPOUNDS;

BRIDGING LIGANDS; CARBODIIMIDE; H BONDS; HETEROCYCLES; INSERTION REACTIONS; LANTHANIDE AMIDES; LANTHANIDE IONS; LANTHANIDES; NITROGEN BONDS; STRUCTURAL FEATURES;

RARE EARTH ELEMENTS;

EID: 57549083829     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200803581     Document Type: Article

References (40)

1. G. E. Herberich, G. Greiss, H. F. Heil, Angew. Chem. 1970, 82, 838-839;
2. Angew. Chem. Int. Ed. Engl. 1970, 9, 805-806.
3. A. J. Ashe III, P. Shu, J. Am. Chem. Soc. 1971, 93, 1804-1805.
4. G. E. Herberich, H. Ohst, Adv. Organomet. Chem. 1986, 25, 199-236.
5. a) A. J. Ashe III, S. Al-Ahmad, X. G. Fang, J. Organomet. Chem. 1999, 581, 92-97;
6. b)G. C. Fu, Adv. Organomet. Chem. 2001, 47, 101-119;
7. c) G. C. Bazan, G. Rodriguez, A. J. Ashe III, S. Al-Ahmad, C. Müller, J. Am. Chem. Soc. 1996, 118, 2291-2292;
8. d) J. S. Rogers, X. H. Bu, G. C. Bazan, J. Am. Chem. Soc. 2000, 122, 730-731;
9. e) A. J. Ashe III, S. Al-Ahmad, X. D. Fang, J. W. Kampf, Organometallics 2001, 20, 468-473;
10. f) G. E. Herberich, T. S. Basu Baul, U. Englert, Eur. J. Inorg. Chem. 2002, 43-48;
11. g) N. Auvray, T. S. Basu Baul, P. Braunstein, P. Croizat, U. Englert, G. E. Herberich, R. Welter, Dalton Trans. 2006, 2950-2958.
12. a) R. Boese, N. Finke, T. Keil, P. Paetzold, G. Schmid, Z. Naturforsch. B 1985, 40, 1327-1332;
13. b) M. C. Amendola, K. E. Stockman, D. A. Hoic, W. M. Davis, G. C. Fu, Angew. Chem. 1997, 109, 278-281;
14. Angew. Chem. Int. Ed. Engl. 1997, 36, 267-269;
15. c) J. Tweddell, D. A. Hoic, G. C. Fu, J. Org. Chem. 1997, 62, 8286-8287.
16. a) H. Schumann, J. A. Meese-Marktscheffel, L. Esser, Chem. Rev. 1995, 95, 865-986;
17. b) S. Arndt, J. Okuda, Chem. Rev. 2002, 102, 1953-1976;
18. c) W. J. Evans, B. L. Davis, Chem. Rev. 2002, 102, 2119-2136.
19. a) S. Hong, T. J. Marks, Acc. Chem. Res. 2004, 37, 673-686;
20. b) G. A. Molander, J. A. C. Romero, Chem. Rev. 2002, 102, 2161-2185.
21. a) H. Yasuda, J. Organomet. Chem. 2002, 647, 128-138;
22. b) Z. Hou, Y. Wakatsuki, Coord. Chem. Rev. 2002, 231, 1-22.
23. W. J. Evans, Inorg. Chem. 2007, 46, 3435-3449.
24. a) B. Wang, X. L. Zheng, G. E. Herberich, Eur. J. Inorg. Chem. 2002, 31-41;
25. b) X. L. Zheng, B. Wang, U. Englert, G. E. Herberich, Inorg. Chem. 2001, 40, 3117-3123;
26. c) G. E. Herberich, U. Englert, A. Fischer, J. H. Ni, A. Schmitz, Organometallics 1999, 18, 5496-5501;
27. d) M. A. Putzer, J. Rogers, G. C. Bazan, J. Am. Chem. Soc. 1999, 121, 8112-8113.
28. P. Cui, Y. F. Chen, X. H. Zeng, J. Sun, G. Y. Li, W. Xia, Organometallics 2007, 26, 6519-6521.
29. P. Cui, Y. F. Chen, G. P. Wang, G. Y. Li, W. Xia, Organometallics 2008, 27, 4013-4016.
30. S. Qiao, D. A. Hoic, G. C. Fu, J. Am. Chem. Soc. 1996, 118, 6329-6330.
31. a) A. G. Avent, M. A. Edelman, M. F. Lappert, G. A. Lawless, J. Am. Chem. Soc. 1989, 111, 3423-3425;
32. b) A. Edelmann, S. Blaurock, V. Lorenz, L. Hilfert, F. T. Edelmann. Angew. Chem. 2007, 119, 6855-6857;
33. Angew. Chem. Int. Ed. 2007, 46, 6732-6734;
34. Angew. Chem. Int. Ed. 2007, 46, 6732-6734, and references therein.
35. D. A. Hoic, J. R. Wolf, W. M. Davis, G. C. Fu, Organometallics 1996, 15, 1315-1318.
36. a) G. B. Deacon, C. M. Forsyth, P. C. Junk, B.W. Skelton, A. H. White, Chem. Eur. J. 1999, 5, 1452-1459;
37. b) M. Niemeyer, Eur. J. Inorg. Chem. 2001, 1969-1981.
38. E. H. Sheng, S. W.Wang, G. S. Yang, S. L. Zhou, L. Cheng, K. H. Zhang, Z. X. Huang, Organometallics 2003, 22, 684-692.
39. J. Zhang, R. F. Cai, L. H. Weng, X. G. Zhou, J. Organomet. Chem. 2003, 672, 94-99.
40. CCDC-694328 (3) and CCDC-694329 (5) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.