Divalent ytterbium boratabenzene complex (C5H 5BNPh2)2Yb(THF)2: Synthesis, structure, and solvent-mediated redox transformation

Organometallics

Volumn 27, Issue 15, 2008, Pages 4013-4016

  Cui, Peng ^b   Chen, Yaofeng ^a   Wang, Guoping ^b   Li, Guangyu ^b   Xia, Wei ^b  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

^b ZHEJIANG UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

YTTERBIUM;

EID: 50549104544     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om800245u     Document Type: Article

References (31)

1. (a) Evans, W. J. Coord. Chem. Rev. 2000, 206-207, 263.
2. (b) Evans, W. J. Inorg. Chem. 2007, 46, 3435.
3. (a) Bochkarev, M. N.; Trifonov, A. A.; Cloke, F. G. N.; Dalby, C. I.; Matsunaga, P. T.; Andersen, R. A.; Schumann, H.; Loebel, J.; Hemling, H. J. Organomet. Chem. 1995, 486, 177.
4. (b) Trifonov, A. A. Eur. J. Inorg. Chem. 2007, 3151.
5. (c) Walter, M. D.; Berg, D. J.; Andersen, R. A. Organometallics. 2007, 26, 2296.
6. (d) Moore, J. A.; Cowley, A. H.; Gordon, J. C. Organometallics. 2006, 25, 5207.
7. General reduction potentials of Ln(III)/Ln(II) vs NHE: Eu (-0.35 V), Yb (-1.15 V), Sm (-1.55 V), Tm (-2.3 V), Nd (-2.6 V), Dy (-2.6 V), Pr (-2.7 V) and La (-3.1 V). See ref la and references therein.
8. (a) Trifonov, A. A.; Fedorova, E. A.; Fukin, G. K.; Druzhkov, N. O.; Bochkarev, M. N. Angew. Chem., Int. Ed. 2004, 43, 5045.
9. (b) Trifonov, A. A.; Borovkov, I. A.; Fedorova, E. A.; Fukin, G. K.; Larionova, J.; Druzhkov, N. O.; Cherkasov, V. K. Chenu-Eur. J. 2007, 13, 4981.
10. (c) Trifonov, A. A.; Fedorova, E. A.; Ikorskii, V. N.; Dechert, S.; Schumann, H.; Bochkarev, M. N. Eur. J. Inorg. Chem. 2005, 2812.
11. Herberich, G. E.; Holger, O. Adv. Organomet. Chem. 1986, 25, 199.
12. (a) Ashe, A. J., III; Al-Ahmad, S.; Fang, X. G. J. Organomet. Chem. 1999, 581, 92.
13. (b) Fu, G. C. Adv. Organomet. Chem. 2001, 47, 101.
14. (c) Bazan, G. C.; Rodriguez, G.; Ashe, A. J., III; Al-Ahmad, S.; Müller, C. J. Am. Chem. Soc. 1996, 118, 2291.
15. (d) Rogers, J. S.; Bu, X. H.; Bazan, G. C. J. Am. Chem. Soc. 2000, 122, 730.
16. (e) Ashe, A. J., III; Al-Ahmad, S.; Fang, X. D.; Kampf, J. W. Organometallics 2001, 20, 468.
17. (f) Herberich, G. E.; Basu Ba-l, T. S.; Englert, U. Eur. J. Inorg. Chem. 2002, 43.
18. (g) Auvray, N.; Basu Ba-l, T. S.; Braunstein, P.; Croizat, P.; Englert, U.; Herberich, G. E.; Welter, R. Dalton Trans. 2006, 2950.
19. For the reported boratabenzene lanthanide metal complexes, see: Wang, B.; Zheng, X. L.; Herberich, G. E. Eur. J. Inorg. Chem. 2002, 31.
20. For the reported boratabenzene Y and Sc complexes, see: (a) Zheng, X. L.; Wang, B.; Englert, U.; Herberich, G. E. Inorg. Chem. 2001, 40, 3117.
21. (b) Herberich, G. E.; Englert, U.; Fischer, A.; Ni, J. H.; Schmitz, A. Organometallics 1999, 18, 5496.
22. (c) Putzer, M. A.; Rogers, J.; Bazan, G. J. Am. Chem. Soc. 1999, 121, 8112.
23. Cui, P.; Chen, Y. F.; Zeng, X. H.; Sun, J.; Li, G. Y.; Xia, W. Organometallics 2007, 26, 6519.
24. Hoic, D. A.; DiMare, M.; Fu, G. C. J. Am. Chem. Soc. 1997, 119, 7155.
25. Lin, G. Y.; Wong, W. T. J. Organomet. Chem. 1995, 495, 203.
26. Lappert, M. F,; Yarrow, P. I. W.; Atwood, J. L.; Shakir, R.; Holton, J. ;. Chem. Soc. Chem. Commun. 1980, 987.
27. Wayda, A. L.; Dye, J. L.; Rogers, R. D. Organometallics. 1984, 3, 1605.
28. (a) Lemp, E.; Zanocco, A. L.; Günther, G.; Pizarro, N. Tetrahedron 2006, 62, 10734.
29. (b) Turkmen, H.; Çetinkaya, B. J. Organomet. Chem. 2006, 691, 3749.
30. Huige, C. J. M.; Spek, A. L.; de Boer, J. L. Acta Crystallogr. 1983, C41, 113.
31. Girard, P.; Namy, J. L.; Kagan, H. B. J. Am. Chem. Soc. 1980, 102, 2693.