Ion Calorimetry: Using Mass Spectrometry to Measure Melting Points

Journal of the American Society for Mass Spectrometry

Volumn 18, Issue 1, 2007, Pages 74-81

  Neal, Colleen M ^a   Starace, Anne K ^a   Jarrold, Martin F ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALUMINUM; DISSOCIATION; MASS SPECTROMETRY; MEASUREMENT THEORY; SPECIFIC HEAT;

CLUSTER CATIONS; ION CALORIMETRY; MELTING TRANSITION;

POSITIVE IONS;

ALUMINUM; ION;

ARTICLE; ATOM; CALORIMETRY; DISSOCIATION; HEAT; ION CALORIMETRY; MASS SPECTROMETRY; MELTING POINT; SOLID; TEMPERATURE;

EID: 33845954514     PISSN: 10440305     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jasms.2006.08.019     Document Type: Article

References (44)

1. In: Armentrout P.B. (Ed). Encyclopedia of Mass Spectrometry, Volume I: Theory and Ion Chemistry (2003), Elsevier Science, Amsterdam
2. Okamoto Y., and Hansmann U.H.E. Thermodynamics of Helix-Coil Transitions Studied by Multicanonical Algorithms. J. Phys. Chem. 99 (1995) 11276-11287
3. Kohtani M., Jones T.C., Sudha R., and Jarrold M.F. Proton Transfer Induced Conformational Changes and Melting in Designed Peptides in the Gas Phase. J. Am. Chem. Soc. (2006) in press.
4. Beck R.D., St. John P., Homer M.L., and Whetten R.L. Impact-Induced Cleaving and Melting of Alkali-Halide Nanocrystals. Science 253 (1991) 879-883
5. De Heer W.A. The Physics of Simple Metal Clusters-Experimental Aspects and Simple Models. Rev. Mod. Phys. 65 (1993) 611-676
6. Pawlow P. Über die Abhängigkeit des Schmelzpunktes von der Oberflächenenergie eines Festen Körpers. Z. Phys. Chem. 65 (1909) 1-35
7. Peppiatt S.J. The Melting Point of Small Particles. II. Bismuth. Proc. Roy. Soc. London A 345 (1975) 401-412
8. Buffat P., and Borel J.-P. Size Effect on the Melting Temperature of Gold Clusters. Phys. Rev. A 13 (1976) 2287-2298
9. Ross J., and Andres R.P. Melting Temperature of Small Clusters. Surf. Sci. 106 (1981) 11-17
10. Lai S.L., Guo J.Y., Petrova V., Ramanath G., and Allen L.H. Size-Dependent Melting Properties of Small Tin Particles: Nanocalorimetric Measurements. Phys. Rev. Lett. 77 (1996) 99-102
11. Bottani C.E., Bassi A.L., Tanner B.K., Stella A., Tognini P., Cheyssac P., and Kofman R. Melting in Metallic Sn Nanoparticles Studied by Surface Brillouin Scattering and Synchrotron X-Ray Diffraction. Phys. Rev. B 59 (1999) R15601-R15604
12. Schmidt M., Kusche R., Kronmüller W., von Issendorff B., and Haberland H. Experimental Determination of the Melting Point and Heat Capacity for a Free Cluster of 139 Sodium Atoms. Phys. Rev. Lett. 79 (1997) 99-102
13. Schmidt M., Kusche R., von Issendorff B., and Haberland H. Irregular Variation in the Melting Point of Size-Selected Atomic Clusters. Nature (London) 393 (1998) 238-240
14. Schmidt M., and Haberland H. Phase Transitions in Clusters. C. R. Physique 3 (2002) 327-340
15. Breaux G.A., Neal C.M., Cao B., and Jarrold M.F. Melting, Premelting, and Structural Transitions in Size-Selected Aluminum Clusters with Around 55 Atoms. Phys. Rev. Lett. 94 (2005) 173401
16. Shvartsburg A.A., and Jarrold M.F. Solid Clusters Above the Bulk Melting Point. Phys. Rev. Lett. 85 (2000) 2530-2532
17. Breaux G.A., Neal C.M., Cao B., and Jarrold M.F. Tin Clusters That Do Not Melt: Calorimetry Measurements up to 650 K. Phys. Rev. B 71 (2005) 073410
18. Jarrold M.F., and Honea E.C. Annealing of Silicon Clusters. J. Am. Chem. Soc. 114 (1992) 459-464
19. Jarrold M.F., and Honea E.C. Dissociation of Large Silicon Clusters-The Approach to Bulk Behavior. J. Phys. Chem. 95 (1991) 9181-9185
20. Jarrold M.F. Drift-Tube Studies of Atomic Clusters. J. Phys. Chem. 99 (1995) 11-21
21. Bohr J. Quantum Mode Phonon Forces Between Chain Molecules. Int. J. Quantum Chem. 84 (2001) 249-252
22. The Relevant Collision Energies are the High Energy Ones, When the Ions First Enter the Collision Cell. The Lower Collision Energies Are Not Impulsive, But They Are Experienced by All Ions.
23. Breaux G.A., Cao B., and Jarrold M.F. Second Order Phase Transitions in Amorphous Gallium Clusters. J. Phys. Chem. B 109 (2005) 16575-16578
24. Katayama Y., Mizutan T., Utsumi W., Shimomura O., Yamakata M., and Funakoshi K. A First-Order Liquid-Liquid Phase Transition in Phosphorus. Nature 403 (2000) 170-173
25. Monaco G., Falconi S., Crichton W.A., and Mezouar M. Nature of the First-Order Phase Transition in Fluid Phosphorus at High Temperature and Pressure. Phys. Rev. Lett. 90 (2003) 255701
26. Breaux G.A., Benirschke R.C., Sugai T., Kinnear B.S., and Jarrold M.F. Hot and Solid Gallium Clusters: Too Small to Melt. Phys. Rev. Lett. 91 (2003) 215508
27. n Clusters. Phys. Rev. B 57 (1998) 4730-4735
28. Aguado A., Molina L.M., Loez J.M., and Alonso J.A. Melting Behavior of Large Disordered Sodium Clusters. Eur. Phys. J. D. 15 (2001) 221-227
29. Westergren J., Nordholm S., and Rosen A. Melting of Palladium Clusters-Canonical and Microcanonical Monte Carlo Simulation. Phys. Chem., Chem. Phys. 5 (2003) 136-150
30. Nauchitel V.V., and Pertsin A.J. A Monte-Carlo Study of the Structure and Thermodynamic Behavior of Small Lennard-Jones Clusters. Mol. Phys. 40 (1980) 1341-1355
31. Cheng H.P., and Berry R.S. Surface Melting of Clusters and Implications for Bulk Matter. Phys. Rev. B 45 (1982) 7969-7980
32. 20: Melting in Steps. J. Chem. Phys. 111 (1999) 6026-6035
33. Calvo F., and Spiegelmann F. Mechanisms of Phase Transitions in Sodium Clusters: From Molecular to Bulk Behavior. J. Chem. Phys. 112 (2000) 2888-2908
34. Lee Y.J., Lee E.K., Kim S., and Nieminen R.M. Effect of Potential Energy Distribution on the Melting of Clusters. Phys. Rev. Lett. 86 (2001) 999-1002
35. Joshi K., Kanhere D.G., and Blundell S.A. Thermodynamics of Tin Clusters. Phys. Rev. B 67 (2003) 235413
36. Calvo F., and Spiegelman F. On the Premelting Features in Sodium Clusters. J. Chem. Phys. 120 (2004) 9684-9689
37. Aguado A., Lopez J.M., Alonso J.A., and Stott M.J. Melting in Large Sodium Clusters: An Orbital-Free Molecular Dynamics Study. J. Phys. Chem. B 105 (2001) 2386-2392
38. Manninen K., Rytkonen A., and Manninen M. Influence of Electronic and Geometric Properties on Melting of Sodium Clusters. Eur. Phys. J. D 29 (2004) 39-47
39. Haberland H., Hippler T., Donges J., Kostko O., Schmidt M., and von Issendorff B. Melting of Sodium Clusters: Where do the Magic Numbers Come From?. Phys. Rev. Lett. 94 (2005) 035701
40. Chacko S., Kanhere D.G., and Blundell S.A. First Principles Calculations of Melting Temperatures for Free Na Clusters. Phys. Rev. B 71 (2005) 155407
41. Joshi K., Kanhere D.G., and Blundell S.A. Thermodynamics of Tin Clusters. Phys. Rev. B 67 (2003) 235413
42. Chacko S., Joshi K., Kanhere D.G., and Blundell S.A. Why Do Gallium Clusters Have Higher Melting Points than the Bulk?. Phys. Rev. Lett. 92 (2004) 135506
43. Chuang F.-C., Wang C.Z., Öǧüt S., Chelikowsky J.R., and Ho K.M. Melting of Small Sn Clusters by Ab Initio Molecular Dynamics Simulations. Phys. Rev. B 69 (2004) 165408
44. Ercolessi F., Andreoni W., and Tosatti E. Melting of Gold Particles: Mechanism and Size Effects. Phys. Rev. Letts. 66 (1991) 911-914