Monitoring the quality of oils for biodiesel production using multivariate near infrared spectroscopy models

Journal of Near Infrared Spectroscopy

Volumn 16, Issue 5, 2008, Pages 445-454

  Baptista, Patrícia ^a   Felizardo, Pedro ^a   Menezes, José C ^b   Correia, M Joana Neiva ^a  

^a UNIVERSITY OF LISBON   (Portugal)

^b Instituto de Biotecnologia e Bioengenharia Lisboa   (Portugal)

Author keywords

Calibration models; Near infrared; Quality control; Vegetable oils

Indexed keywords

EID: 57449098406     PISSN: 09670335     EISSN: None     Source Type: Journal    
DOI: 10.1255/jnirs.814     Document Type: Article

References (27)

1. A. Demirbas, "Importance of biodiesel as transportation fuel", Energy Policy 35, 4661-4670 (2007). doi: 10.1016/j.enpol.2007.04. 003
2. F. Ma and M. Hanna, "Biodiesel production: a review", Bioresource Technol. 70, 1-15 (1999). doi: 10.1016/50960-8524(99) 00025-5
3. K. Bozbas, "Biodiesel as an alternative motor fuel: Production and policies in the European Union", Renew. Sustain. Energy Rev. 12, 542-552 (2008). doi: 10.1016/j.rser.2005.06.001
4. J.M. Encinar, J.F. González and A. Rodríguez-Reinares, "Ethanolysis of used frying oils: Biodiesel preparation and characterisation", Fuel Proc. Tech. 88, 513-522 (2007). doi: 10.1016/j.fuproc.2007.01.002
5. P. Felizardo, M.J. Neiva Correia, I. Raposo, J.F. Mendes, R. Berkemeier and J.M. Bordado, "Production of biodiesel from waste frying oils", Waste Manage. 26, 487-494 (2006). doi: 10.1016/j.wasman.2005.02. 025
6. Y. Ulusoy, Y. Tekin, M. Cetinkaya and F. Karaosmanoglu, "The engine tests of biodiesel from used frying oil", Energy Sources 26, 927-932 (2004). doi: 10.1080/00908310490473219
7. M.F. Askew, "Natural plant oils and fats as renewable resources: A sustainable option?", Lipid Technol. 19(11), 254-257 (2007). doi: 10.1002/lite.200700082
8. G. Knöthe, J. VanGerpen and J. Krahl, The biodiesel handbook. AOCS Press. Urbana, Illinois, USA (2005).
9. J. Marchetti, V. Miguel and A. Errazu, "Possible methods for biodiesel production", Renew. Sustain. Energy Rev. 11, 1300-1311 (2007). doi: 10.1016/j.rser.2005.08.006
10. European Standard EN 14214, Automotive fuels - fatty acid methyl esters (FAME) for diesel engines - Requirements and test methods. CEN - European Committee for Standardization, Brussels, Belgium (2002).
11. Y. Zhang, M.A. Dubé, D.D. McLean and M. Kates, "Biodiesel production from waste cooking oil: process design and technological assessment", Bioresour. Technol. 89, 1-16 (2003). doi: 10.1016/50960-8524(03)00040-3
12. R. Tesser, M. Di Serio, M. Guida, M. Nastasi and E. Santacesaria, "Kinetics of oleic acid esterification with methanol in the presence of triglycerides", Ind. Eng. Chem. Res. 44, 7978-7982 (2005). doi: 10.1021/ie050588o
13. A. Ramadhas, S. Jayaraj and C. Muraleedharan, "Biodiesel production from high FFA rubber seed oil", Fuel 84, 335-340 (2005). doi: 10.1016/j.fuel.2004.09.016
14. A.P. Ferreira, T.P. Alves and J.C. Menezes, "Monitoring complex media fermentations with near-infrared spectroscopy: Comparison of different variable selection methods", Biotechnol. Bioeng. 91, 474-481 (2005). doi: 10.1002/bit.20526
15. H. Martens and T. Næs, Multivariate calibration. John Wiley & Sons Ltd, Chichester, UK (1991).
16. M. Otto, Chemometrics: statistics and computer application in analytical chemistry. Wiley-VCH, Weinheim, Germany (1999).
17. O. Preisner, J. Lopes, R. Guiomar, J. Machado and J. Menezes, "Fourier transform infrared (FT-IR) spectroscopy in bacteriology: towards a reference method for bacteria discrimination", Anal. Bioanal. Chem. 387, 1739-1748 (2007). doi: 10.1007/s00216-006-0851-1
18. S. Armenta, S. Garrigues and M. de la Guardiã, Determination of edible oil parameters by near infrared spectrometry", Anal. Chim. Acta 596, 330-337 (2007). doi: 10.1016/j.aca.2007.06.028
19. H. Yang, J. Irudayaraj and M. Paradkar, "Discriminant analysis of edible oils and fats by FTIR, FT-NIR and FT-Raman spectroscopy", Food Chem. 93, 25-32 (2005). doi: 10.1016/j.foodchem.2004.08.039
20. P. Baptista, P. Felizardo, J.C. Menezes and J.N. Correia, "Multivariate near infrared spectroscopy models for predicting the methyl esters content in biodiesel", Anal. Chim. Acta 607, 153-159 (2008). doi: 10.1016/j.aca.2007.11.044
21. P. Felizardo, P. Baptista, M. Uva, J.C. Menezes and J.N. Correia, "Monitoring biodiesel fuel quality by near infrared spectroscopy", J. Near Infrared Spectrosc. 15(2), 97-105 (2007). doi: 10.1255/jnirs.714
22. P. Felizardo, P. Baptista, J.C. Menezes and J.N. Correia, "Multivariate near infrared spectroscopy models for predicting methanol and water content in biodiesel", Anal. Chim. Acta 595, 107-113 (2007). doi: 10.1016/j.aca.2007.02.050
23. European Standard EN 14111, Fat and oil derivatives - fatty acid methyl esters (FAME) - Determination of iodine value. CEN - European Committee for Standardization, Brussels, Belgium (2003).
24. International Organisation for Standardisation, International Standard ISO 12937 - Petroleum products - Determination of water - Coulometric Karl Fischer titration method. International Organisation for Standardisation, Geneva, Switzerland (2000).
25. Instituto Português da Qualidade, Portuguese Standard NP 903 - Gorduras e óleos comestíveis - Determinação do índice de acidez e da acidez, Método titrimétrico (Fats and edible oils - Acidity and acid number determination by titrimetric procedure). Instituto Português da Qualidade Caparica, Portugal (1998).
26. T. Naas, T. Isaksson, T. Fearn and T. Davies, A user friendly guide to multivariate calibration and classification, NIR Publications, Chichester, UK (2002).
27. nd Edn). Ed by P. C. Williams and K. Norris. American Association of Cereal Chemists, St Paul, MI, USA, p. 143 (2001).