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Laschat, S.; Baro, A.; Steinke, N.; Giesselmann, F.; Hägele, C.; Scalia, G.; Judele, R.; Kapatsina, E.; Sauer, S.; Schreivogel, A.; Tosoni, M. Angew. Chem., Int. Ed. 2007, 46, 4832-4887.
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57349101423
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Due to the presence of the stereogenic centers in the glycerol groups, the investigated systems represent mixtures of four distinct stereoisomers
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Due to the presence of the stereogenic centers in the glycerol groups, the investigated systems represent mixtures of four distinct stereoisomers.
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16
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57349115179
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The fact that there is no distinct central maximum in the electron density profile of a column corresponding to the aromatic core, surrounded by a low-density ring from the alkyl region, is in line with rotational averaging of ribbon-like cores
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The fact that there is no distinct central maximum in the electron density profile of a column corresponding to the aromatic core, surrounded by a low-density ring from the alkyl region, is in line with rotational averaging of ribbon-like cores.
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18
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0037120870
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This is similar to the LamN and LamSm phases of bolaamphiphiles with a linear lateral chain where rod-like units are parallel to the layer planes and not perpendicular as in SmA phases or tilted as in SmC phases: Prehm, M, Cheng, X. H, Diele, S, Das, M. K, Tschierske, C. J. Am. Chem. Soc. 2002, 124, 12072-12073
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Sm phases of bolaamphiphiles with a linear lateral chain where rod-like units are parallel to the layer planes and not perpendicular as in SmA phases or tilted as in SmC phases: Prehm, M.; Cheng, X. H.; Diele, S.; Das, M. K.; Tschierske, C. J. Am. Chem. Soc. 2002, 124, 12072-12073.
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19
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Prehm, M.; Diele, S.; Das, M. K.; Tschierske, C. J. Am. Chem. Soc. 2003, 125, 614-615.
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Prehm, M.1
Diele, S.2
Das, M.K.3
Tschierske, C.4
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Patel, N. M.; Syed, I. M.; Rosenblatt, C.; Prehm, M.; Tschierske, C. Liq. Cryst. 2005, 32, 55-61.
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22
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28444492377
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Hexagonal mesophases with an inverse structure, where fluid chains form the column core surrounded by rod-like mesogens arranged with or without register parallel to the columns, were reported recently: Chen, B.; Baumeister, U.; Pelzl, G.; Das, M. K.; Zeng, X. B.; Ungar, G.; Tschierske, C. J. Am. Chem. Soc. 2005, 127, 16578-16591.
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Hexagonal mesophases with an inverse structure, where fluid chains form the column core surrounded by rod-like mesogens arranged with or without register parallel to the columns, were reported recently: Chen, B.; Baumeister, U.; Pelzl, G.; Das, M. K.; Zeng, X. B.; Ungar, G.; Tschierske, C. J. Am. Chem. Soc. 2005, 127, 16578-16591.
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0026105445
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In this case the lock-in of longitudinal interchain register leads to a Colhex-to-crystal B transition which is first order
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hex-to-crystal B transition which is first order: Ungar, G.; Feijoo, J. L.; Percec, V.; Yourd, R. Macromolecules 1991, 24, 953-957.
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