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Volumn 47, Issue 50, 2008, Pages 9681-9684

Heterometallic rings made from chromium stick together easily

Author keywords

Chromium; EPR spectroscopy; Heterometallic complexes; Molecular magnetism; Supramolecular chemistry

Indexed keywords

CHROMIUM; CHROMIUM COMPOUNDS; ELECTRON SPIN RESONANCE SPECTROSCOPY; HYDRATES; NICKEL ALLOYS; PARAMAGNETIC RESONANCE; SUPRAMOLECULAR CHEMISTRY;

EID: 57149094317     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200803637     Document Type: Article
Times cited : (64)

References (28)
  • 6
    • 0142170260 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2003, 42, 101-105;
    • (2003) Angew. Chem. Int. Ed , vol.42 , pp. 101-105
  • 11
    • 27144518239 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2005, 44, 6496-6499;
    • (2005) Angew. Chem. Int. Ed , vol.44 , pp. 6496-6499
  • 12
    • 27144518239 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2005, 44, 6496-6499.
    • (2005) Angew. Chem. Int. Ed , vol.44 , pp. 6496-6499
  • 13
    • 57149103675 scopus 로고    scopus 로고
    • Crystal data for 1 (C93H174Cr 7F3NNiO37.5; Mr, 2385.6 gmol-1, purple needles, orthorhombic, space group P2 12121, a, 16.4250(5, b, 24.9950(5, c, 31.7760(11) Å, V, 13045.4(7) Å3, Z, 4, T, 100(2) K, ρ, 1.214 g cm -3, F(000, 5047, μ(MoKα, 0.773 mm -1. Crystal data for 2 (C100H174Cr 7F3N2NiO39; Mr, 2508.1 g mol-1, purple block, orthorhombic, space group P212121, a, 17.0600(2, b, 26.3540(3, c, 30.4220(4) Å, V, 13 677.7(3) Å3, Z, 4, T, 150(2) K, ρ, 1.218 g cm -3, F(000, 5292, μMoKα
    • 1 = 0.0939 (13166 reflections with I > 2σσ(I)). CCDC-696012 (1), -696014 (2), -696015 (3), -696016 (4), and -696017 (5) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.
  • 16
    • 0004150157 scopus 로고    scopus 로고
    • Bruker Analytical X-ray Systems, Madison, WI
    • SHELX-PC Package. Bruker Analytical X-ray Systems, Madison, WI, 1998.
    • (1998) SHELX-PC Package
  • 28
    • 57149101296 scopus 로고    scopus 로고
    • From modeling X- and Q-band spectra it is likely that there is slight non-coincidence between the principal axes of the g-matrix and D-tensor which we speculate may be relate to the deviation of the Ni⋯Ni vector from the best planes of the {Cr7Ni} rings. Single-crystal EPR studies will be reported later
    • 7Ni} rings. Single-crystal EPR studies will be reported later.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.