Homoleptic cuprates(II) with multiply deprotonated α-cyclodextrin ligands

Chemistry - A European Journal

Volumn 3, Issue 4, 1997, Pages 601-608

  Klüfers, Peter ^a   Piotrowski, Holger ^a   Uhlendorf, Jürgen ^a  

^a UNIVERSITY OF KARLSRUHE   (Germany)

Author keywords

copper; cuprates; cyclodextrins; structure elucidation

Indexed keywords

EID: 0040254925     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.19970030416     Document Type: Article

References (28)

1. W. Burchard, N. Habermann, P. Klüfers, B. Seger, U. Wilhelm, Angew. Chem. 1994, 106, 936-939; Angew. Chem. Int. Ed. Engl. 1994, 33, 884-887.
2. W. Burchard, N. Habermann, P. Klüfers, B. Seger, U. Wilhelm, Angew. Chem. 1994, 106, 936-939; Angew. Chem. Int. Ed. Engl. 1994, 33, 884-887.
3. N. Habermann, M. Klaassen, P. Klüfers, Carbohydr. Res. 1993, 241, 9-23; N. Habermann, G. Jung, M. Klaassen, P. Klüfers, Chem. Ber. 1992, 125, 809-814; M. Klaassen, P. Klüfers, Z. Anorg. Allg. Chem. 1993, 619, 661-666; M. Klaassen, P. Klüfers, Acta Crystallogr. Sect. C 1994, 50, 686-688; M. Klaassen, P. Klüfers, Z. Anorg. Allg. Chem. 1994, 620, 1631-1634.
4. N. Habermann, M. Klaassen, P. Klüfers, Carbohydr. Res. 1993, 241, 9-23; N. Habermann, G. Jung, M. Klaassen, P. Klüfers, Chem. Ber. 1992, 125, 809-814; M. Klaassen, P. Klüfers, Z. Anorg. Allg. Chem. 1993, 619, 661-666; M. Klaassen, P. Klüfers, Acta Crystallogr. Sect. C 1994, 50, 686-688; M. Klaassen, P. Klüfers, Z. Anorg. Allg. Chem. 1994, 620, 1631-1634.
5. N. Habermann, M. Klaassen, P. Klüfers, Carbohydr. Res. 1993, 241, 9-23; N. Habermann, G. Jung, M. Klaassen, P. Klüfers, Chem. Ber. 1992, 125, 809-814; M. Klaassen, P. Klüfers, Z. Anorg. Allg. Chem. 1993, 619, 661-666; M. Klaassen, P. Klüfers, Acta Crystallogr. Sect. C 1994, 50, 686-688; M. Klaassen, P. Klüfers, Z. Anorg. Allg. Chem. 1994, 620, 1631-1634.
6. N. Habermann, M. Klaassen, P. Klüfers, Carbohydr. Res. 1993, 241, 9-23; N. Habermann, G. Jung, M. Klaassen, P. Klüfers, Chem. Ber. 1992, 125, 809-814; M. Klaassen, P. Klüfers, Z. Anorg. Allg. Chem. 1993, 619, 661-666; M. Klaassen, P. Klüfers, Acta Crystallogr. Sect. C 1994, 50, 686-688; M. Klaassen, P. Klüfers, Z. Anorg. Allg. Chem. 1994, 620, 1631-1634.
7. N. Habermann, M. Klaassen, P. Klüfers, Carbohydr. Res. 1993, 241, 9-23; N. Habermann, G. Jung, M. Klaassen, P. Klüfers, Chem. Ber. 1992, 125, 809-814; M. Klaassen, P. Klüfers, Z. Anorg. Allg. Chem. 1993, 619, 661-666; M. Klaassen, P. Klüfers, Acta Crystallogr. Sect. C 1994, 50, 686-688; M. Klaassen, P. Klüfers, Z. Anorg. Allg. Chem. 1994, 620, 1631-1634.
8. C. Gack, P. Klüfers, Acta Crystallogr. Sect. C 1996, 52, 2972-2975.
9. P. Klüfers, H. Piotrowski, J. Schuhmacher, Z. Anorg. Allg. Chem. 1997, 623, 191-199.
10. Compare with the structures of the cuprates formed with the isomeric hexitols dulcitol (P. Klüfers, J. Schuhmacher, Angew. Chem. 1994, 106, 1839-1841; Angew. Chem. Int. Ed. Engl. 1994, 33, 1742-1744) and D-sorbitol (P. Klüfers. J. Schuhmacher. Angew. Chem. 1995, 107, 2290-2292; Angew. Chem. Int. Ed. Engl. 1995, 34, 2119-2121).
11. Compare with the structures of the cuprates formed with the isomeric hexitols dulcitol (P. Klüfers, J. Schuhmacher, Angew. Chem. 1994, 106, 1839-1841; Angew. Chem. Int. Ed. Engl. 1994, 33, 1742-1744) and D-sorbitol (P. Klüfers. J. Schuhmacher. Angew. Chem. 1995, 107, 2290-2292; Angew. Chem. Int. Ed. Engl. 1995, 34, 2119-2121).
12. Compare with the structures of the cuprates formed with the isomeric hexitols dulcitol (P. Klüfers, J. Schuhmacher, Angew. Chem. 1994, 106, 1839-1841; Angew. Chem. Int. Ed. Engl. 1994, 33, 1742-1744) and D-sorbitol (P. Klüfers. J. Schuhmacher. Angew. Chem. 1995, 107, 2290-2292; Angew. Chem. Int. Ed. Engl. 1995, 34, 2119-2121).
13. Compare with the structures of the cuprates formed with the isomeric hexitols dulcitol (P. Klüfers, J. Schuhmacher, Angew. Chem. 1994, 106, 1839-1841; Angew. Chem. Int. Ed. Engl. 1994, 33, 1742-1744) and D-sorbitol (P. Klüfers. J. Schuhmacher. Angew. Chem. 1995, 107, 2290-2292; Angew. Chem. Int. Ed. Engl. 1995, 34, 2119-2121).
14. G. v. Sengbusch, H. D. Lemke, J. Viencken, in Uremia Therapy (Ed.: H. J. Gurland), Springer, Berlin, 1987, pp. 111-124.
15. F. Hoelkeskamp, Papier (Darmstadt) 1962, 16, 102-105: ibid. 1964, 18, 201-204.
16. F. Hoelkeskamp, Papier (Darmstadt) 1962, 16, 102-105: ibid. 1964, 18, 201-204.
17. For an account of the difficulties in obtaining crystalline cellodextrins (K. Gessler, N. Kraus, T. Steimer, C. Betzel, C. Sandmann, W. Saenger, Science 1994, 266, 1027-1029).
18. a) R. Fuchs, N. Habermann, P. Klüfers, Angew. Chem. 1993, 105, 895-897; Angew. Chem. Int. Ed. Engl. 1993, 32, 852-854;
19. a) R. Fuchs, N. Habermann, P. Klüfers, Angew. Chem. 1993, 105, 895-897; Angew. Chem. Int. Ed. Engl. 1993, 32, 852-854;
20. b) for the structure of a lead(II) complex of γ-cyclodextrin see: P. Klüfers, J. Schuhmacher, ibid. 1994, 106, 1925-1927; 1994, 33, 1863-1865.
21. b) for the structure of a lead(II) complex of γ-cyclodextrin see: P. Klüfers, J. Schuhmacher, ibid. 1994, 106, 1925-1927; 1994, 33, 1863-1865.
22. Further details of the crystal structure investigation may be obtained from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen (Germany), on quoting the depository numbers CSD-405771 (1), CSD-405770 (2), CSD-405769 (3a) and CSD-405768 (3b).
23. K. B. Lipkowitz, J. Org. Chem. 1991, 56, 6357-6367.
24. 2] establishing O2⋯O2 hydrogen bonds: R. Fuchs, N. Habermann, P. Klüfers, Angew. Chem. 1993, 105, 895-897; Angew. Chem. Int. Ed. Engl. 1993, 32, 852-854.
25. 2] establishing O2⋯O2 hydrogen bonds: R. Fuchs, N. Habermann, P. Klüfers, Angew. Chem. 1993, 105, 895-897; Angew. Chem. Int. Ed. Engl. 1993, 32, 852-854.
26. G. A. Jeffrey, W. Saenger. Hydrogen Bonding in Biological Structures, Springer, Berlin, 1991, p. 312: the authors interpret structural changes of cyclodextrin hosts on forming inclusion compounds in terms of an induced-fit mechanism exhibited by enzymes.
27. D. Philp, J. F. Stoddart, Angew. Chem. 1996, 108, 1243-1286; Angew. Chem. Int. Ed. Engl. 1996, 35, 1154-1196.
28. D. Philp, J. F. Stoddart, Angew. Chem. 1996, 108, 1243-1286; Angew. Chem. Int. Ed. Engl. 1996, 35, 1154-1196.