[Ru(PPh3)3Cl2]-mediated transformation of -CH3 into =CHPHPh3 in biacetylmonoxime acetyl-/aroylhydrazones: Ruthenium(III) complexes with the transformed ligands

European Journal of Inorganic Chemistry

Volumn , Issue 35, 2008, Pages 5540-5546

  Raveendran, Raji ^a   Pal, Samudranil ^a  

^a UNIVERSITY OF HYDERABAD   (India)

Author keywords

Ligand transformation; Redox properties; Ruthenium

Indexed keywords

DICHLOROMETHANE; DIMETHYLFORMAMIDE; ELECTRON SPIN RESONANCE SPECTROSCOPY; RUTHENIUM COMPOUNDS;

AROYLHYDRAZONES; BIACETYL; GENERAL FORMULAS; LIGAND TRANSFORMATION; METHYL GROUP; REDOX PROPERTY; RUTHENIUM(III) COMPLEX; TRIDENTATE SCHIFF-BASE; X-RAY STRUCTURE;

LIGANDS;

EID: 57149089466     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200800765     Document Type: Article

References (66)

1. a) E. A. Seddon, K. R. Seddon, The Chemistry of Ruthenium, Elsevier, New York, 1984;
2. b) G. Wilkinson, R. D. Gillard, J. A. McCleverty, Comprehensive Coordination Chemistry, Pergamon, Oxford, 1987, vol. 4, p. 277;
3. c) B. K. Ghosh, A. Chakravorty, Coord. Chem. Rev. 1989, 95, 239;
4. d) S.-M. Lee, W.-T. Wong, Coord. Chem. Rev. 1997, 164, 415;
5. e) B.-Z. Shan, Q. Zhao, N. Goswami, D. M. Eichhorn, D. P. Rillema, Coord. Chem. Rev. 2001, 211, 117;
6. f) C. E. Housecroft, Comprehensive Coordination Chemistry II, Elsevier Pergamon, Amsterdam, 2004, vol. 5, p. 555;
7. g) C.-M. Che, T.-C. Lau, Comprehensive Coordination Chemistry II, Elsevier Pergamon, Amsterdam, 2004, vol. 5, p. 733.
8. a) C. W. Cady, R. H. Crabtree, G. W. Brudvig, Coord. Chem. Rev. 2008, 252, 444;
9. b) L. Sun, L. Hammarström, B. Åkermark, S. Styring, Chem. Soc. Rev. 2001, 30, 36;
10. c) J. N. Demas, B. A. DeGraff, Coord. Chem. Rev. 2001, 211, 317;
11. d) S. E. Angell, C. W. Rogers, Y. Zhang, M. O. Wolf, W. E. Jones Jr., Coord. Chem. Rev. 2006, 250, 1829;
12. e) C. Joachim, J. K. Gimzewski, A. Aviram, Nature 2000, 408, 541;
13. f) H. Tributsch, Coord. Chem. Rev. 2004, 248, 1511;
14. g) N. Sardesai, S. C. Lin, K. Zimmermann, J. K. Barton, Bioconjugate Chem. 1995, 6, 302;
15. h) H. B. Gray, J. R. Winkler, Annu. Rev. Biochem. 1996, 65, 537;
16. i) D. B. Grotjahn, Coord. Chem. Rev. 1999, 190-192, 1125;
17. j) M. J. Clarke, Coord. Chem. Rev. 2003, 236, 209;
18. k) J. K. Hurst, Coord. Chem. Rev. 2005, 249, 313;
19. l) C.-M. Che, Pure Appl. Chem. 1995, 67, 225;
20. m) R. Zong, R. P. Thummel, J. Am. Chem. Soc. 2005, 127, 12802;
21. n) T. Naota, H. Takaya, S.-I. Murahashi, Chem. Rev. 1998, 98, 2599;
22. o) W. W. Y. Lam, W.-L. Man, T.-C. Lau, Coord. Chem. Rev. 2007, 251, 2238;
23. p) R. Drozdzak, B. Allaert, N. Ledoux, I. Dragutan, V. Dargutan, F. Verpoort, Coord. Chem. Rev. 2005, 249, 3055.
24. a) S. N. Pal, S. Pal, J. Chem. Soc., Dalton Trans. 2002, 2102;
25. b) S. N. Pal, S. Pal, Eur. J. Inorg. Chem. 2003, 4244;
26. c) R. Raveendran, S. Pal, Polyhedron 2005, 24, 57;
27. d) R. Raveendran, S. Pal, Inorg. Chim. Acta 2006, 359, 3212;
28. e) R. Raveendran, S. Pal, J. Organomet. Chem. 2007, 692, 824;
29. f) R. Raveendran, S. Pal, Polyhedron 2008, 27, 655.
30. a) D. W. Margerum, Pure Appl. Chem. 1983, 55, 23;
31. b) L. Kotska, B. G. Fox, M. P. Hendrich, T. J. Collins, C. E. Pickard, L. J. Wright, E. Münck, J. Am. Chem. Soc. 1993, 115, 6746.
32. a) N. R. Sangeetha, C. K. Pal, P. Ghosh, S. Pal, J. Chem. Soc., Dalton Trans. 1996, 3293;
33. b) S. Pal, Proc. Indian Acad. Sci. (Chem. Sci.) 2002, 114, 417;
34. c) S. Das, S. Pal, J. Organomet. Chem. 2004, 689, 352;
35. d) S. Das, S. Pal, J. Organomet. Chem. 2006, 691, 2575.
36. a) A. Chakravorty, Coord. Chem. Rev. 1974, 13, 1;
37. b) K. Nag, A. Chakravorty, Coord. Chem. Rev. 1980, 33, 87;
38. c) A. Chakravorty, Commun. Inorg. Chem. 1985, 4, 1;
39. d) A. Chakravorty, Isr. J. Chem. 1985, 25, 99.
40. a) D. Datta, A. Chakravorty, Inorg. Chem. 1982, 21, 363;
41. b) S. Pal, A. Chakravorty, Inorg. Chem. 1987, 26, 4331;
42. c) P. Basu, S. Pal, A. Chakravorty, J. Chem. Soc., Dalton Trans. 1990, 9;
43. d) S. Chattopadhyay, P. Basu, D. Ray, S. Pal, A. Chakravorty, Proc. Indian Acad. Sci. (Chem. Sci.) 1990, 102, 195;
44. e) S. Chattopadhyay, P. Basu, S. Pal, A. Chakravorty, J. Chem. Soc., Dalton Trans. 1990, 3829;
45. f) S. G. Sreerama, S. Pal, Inorg. Chem. 2002, 41, 4843;
46. g) P. Chaudhuri, Coord. Chem. Rev. 2003, 243, 143;
47. h) S. G. Sreerama, S. Pal, Eur. J. Inorg. Chem. 2004, 4718.
48. S. Bhattacharya, A. Chakravorty, Proc. Indian Acad. Sci. (Chem. Sci.) 1985, 95, 159.
49. S. G. Sreerama, S. Pal, Inorg. Chem. 2005, 44, 6299.
50. th ed., Wiley, New York, 1992, p. 280.
51. a) V. Manivannan, B. K. Dirghangi, C. K. Pal, A. Chakravorty, Inorg. Chem. 1997, 36, 1526;
52. b) S. Ferlay, H. W. Schmalle, G. Francese, H. Stoeckli-Evans, Inorg. Chem. 2004, 43, 3500;
53. c) S. H. Hong, M. W. Day, R. H. Grubbs, J. Am. Chem. Soc. 2004, 126, 7414.
54. A. Lopez-Harnandez, R. Muller, H. Kopf, N. Burzlaff, Eur. J. Inorg. Chem. 2002, 671.
55. A. K. Das, S.-M. Peng, S. Bhattacharya, Polyhedron 2001, 20, 327.
56. R. R. Holmes, Acc. Chem. Res. 2004, 37, 746.
57. R. Acharyya, S.-M. Peng, G.-H. Lee, S. Bhattacharya, Inorg. Chem. 2003, 42, 7378.
58. N. N. Bhuvan Kumar, M. Chakravarty, K. C. Kumara Swamy, New J. Chem. 2006, 30, 1614.
59. K. Dey, K. Mandal, D. Bandyopadhyay, Indian J. Chem. Sect. A 1992, 31, 937.
60. T. A. Stephenson, G. Wilkinson, J. Inorg. Nucl. Chem. 1966, 28, 945.
61. W. E. Hatfield, Theory and Applications of Molecular Paramagnetism (Eds.: E. A. Boudreaux, L. N. Mulay), Wiley, New York, 1976, p. 491.
62. SMART 5.630 and SAINT-plus 6.45, Bruker-Nonius Analytical X-ray Systems, Inc., Madison, WI, USA, 2003.
63. G. M. Sheldrick, SADABS Program for area detector absorption correction, University of Göttingen, Göttingen, Germany, 1997.
64. G. M. Sheldrick, SHELX-97 Programs for Crystal Structure Analysis, University of Göttingen, Göttingen, Germany, 1997.
65. L. J. Farrugia, J. Appl. Crystallogr. 1999, 32, 837.
66. P. McArdle, J. Appl. Crystallogr. 1995, 28, 65.