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Volumn 47, Issue 22, 2008, Pages 10199-10201

Nickel dithiolene chelate rings in a new role as η5- coordinating ligands: Synthesis, structural characterization, and redox reactivity of an "Fe2Ni" bis-double-decker

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Indexed keywords


EID: 57149089464     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic801487f     Document Type: Article
Times cited : (9)

References (35)
  • 21
    • 30944466633 scopus 로고    scopus 로고
    • Donation of rhodium, iridium, and ruthenium dithiolenes toward cobalt clusters: (a) Nakagawa, N.; Yamada, T.; Murata, M.; Sugimoto, M.; Nishihara, H. Inorg. Chem. 2006, 45, 14.
    • Donation of rhodium, iridium, and ruthenium dithiolenes toward cobalt clusters: (a) Nakagawa, N.; Yamada, T.; Murata, M.; Sugimoto, M.; Nishihara, H. Inorg. Chem. 2006, 45, 14.
  • 22
    • 0034513242 scopus 로고    scopus 로고
    • Rhodium/iridium bimetallic complexes involving tetrathiooxalate ligands: (b) Holloway, G. A.; Klausmeyer, K. K.; Wilson, S. R.; Rauchfuss, T. B. Organometallics 2000, 19, 5370.
    • Rhodium/iridium bimetallic complexes involving tetrathiooxalate ligands: (b) Holloway, G. A.; Klausmeyer, K. K.; Wilson, S. R.; Rauchfuss, T. B. Organometallics 2000, 19, 5370.
  • 25
    • 33947483721 scopus 로고    scopus 로고
    • Synthesis of Ni(S2C2Me2)2: Schrauzer, G. N, Mayweg, V. P. J. Am. Chem. Soc. 1965, 87, 1483. Na2[Ni(S2C2Me2)2] was made by reduction, using excess sodium metal; Na[Ni(S2C 2Me2)2] was obtained by reduction, using NaBH4 see the Supporting Information
    • 4 (see the Supporting Information).
  • 29
    • 57149114854 scopus 로고    scopus 로고
    • Experimental details on X-ray crystallography: data collection on a Nonius-Kappa CCD diffractometer using Mo Kα (0.710 73 Å) at 150(1) K, structure solution with direct methods, refinement on F2 against all reflections. Crystal data and structure refinement for 1 +PF6, dark-green block, crystal size, 0.23 x 0.16 x 0.11 mm, C28H42F6Fe2Ni 1P1S4, M, 822.24, triclinic, space group P1, a, 8.3214(7) Å, b, 8.4045(6) Å c, 13.0294(11) Å, α, 105.575(5)°, β, 101.908(4)°,γ, 103.120(4)°, Z, 1, V, 819.43(11) Å3. Dcalc, 1.666 g cm-3, 7216 reflections collected, of which 3646 were independent, GOF, 1.040, R1, 0.0492 [data with I > 2σ(I, wR2, 0.1308 all data, Crystal data and s
    • -3, 10 562 reflections collected, of which 3599 were independent, GOF = 1.047, R1 = 0.0369 [data with I > 2σ(I)], wR2 = 0.0886 (all data).
  • 31
    • 57149111823 scopus 로고    scopus 로고
    • For a discussion of η5 versus η4 donation in structures of rhodium/ruthenium tetrathiooxalate chelate rings, see ref 12 b
    • 4 donation in structures of rhodium/ruthenium tetrathiooxalate chelate rings, see ref 12 b.
  • 32
    • 0000629392 scopus 로고    scopus 로고
    • Regarding valence-trapping/rapid exchange/delocalization in somewhat related substituted biferrocenium cations: Dong, T.-Y, Ho, P.-H, Lai, X.-Q, Lin, Z.-W, Lin, K.-J. Organometallics 2000, 19, 1096
    • Regarding valence-trapping/rapid exchange/delocalization in somewhat related substituted biferrocenium cations: Dong, T.-Y.; Ho, P.-H.; Lai, X.-Q.; Lin, Z.-W.; Lin, K.-J. Organometallics 2000, 19, 1096.
  • 33
    • 57149110133 scopus 로고    scopus 로고
    • Frisch, M. J.; et al. (see the Supporting Information for a full author list) Gaussian 03, revision D.01; Gaussian, Inc.: Wallingford, CT, 2004.
    • Frisch, M. J.; et al. (see the Supporting Information for a full author list) Gaussian 03, revision D.01; Gaussian, Inc.: Wallingford, CT, 2004.
  • 34
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    • 2).
    • 2).
  • 35
    • 57149112877 scopus 로고    scopus 로고
    • + is oxidized by ferrocenium hexafluorophosphate, in a stoichiometric chemical oxidation experiment.
    • + is oxidized by ferrocenium hexafluorophosphate, in a stoichiometric chemical oxidation experiment.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.