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Rhodium/iridium bimetallic complexes involving tetrathiooxalate ligands: (b) Holloway, G. A.; Klausmeyer, K. K.; Wilson, S. R.; Rauchfuss, T. B. Organometallics 2000, 19, 5370.
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33947483721
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Synthesis of Ni(S2C2Me2)2: Schrauzer, G. N, Mayweg, V. P. J. Am. Chem. Soc. 1965, 87, 1483. Na2[Ni(S2C2Me2)2] was made by reduction, using excess sodium metal; Na[Ni(S2C 2Me2)2] was obtained by reduction, using NaBH4 see the Supporting Information
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4 (see the Supporting Information).
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27
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0041365835
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(a) Szilagyi, R. K.; Lim, B. S.; Glaser, T.; Holm, R. H.; Hedman, B.; Hodgson, K. O.; Solomon, E. I. J. Am. Chem. Soc. 2003, 125, 9158.
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Lim, B.S.1
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57149114854
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Experimental details on X-ray crystallography: data collection on a Nonius-Kappa CCD diffractometer using Mo Kα (0.710 73 Å) at 150(1) K, structure solution with direct methods, refinement on F2 against all reflections. Crystal data and structure refinement for 1 +PF6, dark-green block, crystal size, 0.23 x 0.16 x 0.11 mm, C28H42F6Fe2Ni 1P1S4, M, 822.24, triclinic, space group P1, a, 8.3214(7) Å, b, 8.4045(6) Å c, 13.0294(11) Å, α, 105.575(5)°, β, 101.908(4)°,γ, 103.120(4)°, Z, 1, V, 819.43(11) Å3. Dcalc, 1.666 g cm-3, 7216 reflections collected, of which 3646 were independent, GOF, 1.040, R1, 0.0492 [data with I > 2σ(I, wR2, 0.1308 all data, Crystal data and s
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-3, 10 562 reflections collected, of which 3599 were independent, GOF = 1.047, R1 = 0.0369 [data with I > 2σ(I)], wR2 = 0.0886 (all data).
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0142088980
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Della Pergola, R.; Diana, E.; Garlaschelli, L.; Peli, G.; Manassero, M.; Sansoni, M.; Strumolo, D. Inorg. Chim. Acta 2003, 350, 107.
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Manassero, M.5
Sansoni, M.6
Strumolo, D.7
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31
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57149111823
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For a discussion of η5 versus η4 donation in structures of rhodium/ruthenium tetrathiooxalate chelate rings, see ref 12 b
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4 donation in structures of rhodium/ruthenium tetrathiooxalate chelate rings, see ref 12 b.
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32
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0000629392
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Regarding valence-trapping/rapid exchange/delocalization in somewhat related substituted biferrocenium cations: Dong, T.-Y, Ho, P.-H, Lai, X.-Q, Lin, Z.-W, Lin, K.-J. Organometallics 2000, 19, 1096
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Regarding valence-trapping/rapid exchange/delocalization in somewhat related substituted biferrocenium cations: Dong, T.-Y.; Ho, P.-H.; Lai, X.-Q.; Lin, Z.-W.; Lin, K.-J. Organometallics 2000, 19, 1096.
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33
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57149110133
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Frisch, M. J.; et al. (see the Supporting Information for a full author list) Gaussian 03, revision D.01; Gaussian, Inc.: Wallingford, CT, 2004.
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Frisch, M. J.; et al. (see the Supporting Information for a full author list) Gaussian 03, revision D.01; Gaussian, Inc.: Wallingford, CT, 2004.
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34
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57149101243
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2).
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2).
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35
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57149112877
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+ is oxidized by ferrocenium hexafluorophosphate, in a stoichiometric chemical oxidation experiment.
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+ is oxidized by ferrocenium hexafluorophosphate, in a stoichiometric chemical oxidation experiment.
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