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The numbering of carbons in glycoside moiety is described in Scheme 1. Glc2-Bu (3a, 1H NMR δH (CD 3OD, 0.83 (3H, t, J, 7:4 Hz, CH3, 1.31 (2H, m, CH2CH3, 1.50 (2H, m, CH2CH 2CH3, 3.16-3.81 (14H, OCH2, and protons on the carbons of the maltose, 4.16 (1H, d, J, 8:1 Hz, 1-H, 5.08 (1H, d, J, 3:9 Hz, 1′-H, ESI-MS [M, NH4, m/z 416.3. Calcd. for [M, NH4, 416.2. Glc 3-Bu (4, 1H NMR δH (CD 3OD, 0.93 (3H, t, J, 7:6 Hz, CH3, 1.40 (2H, m, CH2CH3, 1.59 (2H, m, CH2CH 2CH3, 3.22-3.39 (20H, OCH2, and protons on the sugar carbons, 4.28 (1H, d, J, 7:8, 1-H, 5.13 1H, d, J, 3:8
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+, 852.4.
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