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Volumn 11, Issue 12, 2008, Pages 1430-1432

The syntheses of 3d-3d mixed heterometallic coordination polymers with magnetic properties

Author keywords

Heterometallic; Hydrothermal condition; Magnetism; Metal organic framework

Indexed keywords


EID: 56449092783     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2008.10.008     Document Type: Article
Times cited : (7)

References (32)
  • 20
    • 56449114933 scopus 로고    scopus 로고
    • note
    • 2O (0.1542 g, 0.5 mmol) for 2, oxalic acid (0.0189 g, 0.15 mmol) and 4,4-bipyridine (0.0288 g, 0.15 mmol) were dissolved in 3 ml of ethylene alcohol and 5 ml of distilled water upon oscillating in the ultrasonic oscillator for 30 min. The mixture was then sealed in a 15 ml Teflon-lined autoclave, and kept in the oven at 120 °C for 7 days. After the autoclave was cooled at room temperature, red rhombic crystals were filtered off, washed with distilled water, and dried in a desiccator at room temperature. Yield: 30.5% for 1, and 28.2% for 2 (based on Co).
  • 21
    • 56449097034 scopus 로고    scopus 로고
    • note
    • -1, F(0 0 0) = 307. Final residuals with R1 = 0.0354 and wR2 = 0.1220 with [I > 2 δ(I)], and R1 = 0.0360 and wR2 = 0.0978 for all data. The single-crystal X-ray data was collected on a Bruker SMART CCD diffractometer with graphite-monochromated Mo Kα radiation (λ = 0.71073 Å) at room temperature. Data reductions and absorption corrections were performed using the SAINT and SADABS software packages, respectively. The structure was solved by direct methods and refined by full matrix least-squares methods on F2 using the SHELXS-97 and SHELXL-97 programs, using atomic scattering factors for neutral atoms. Anisotropic displacement parameters were refined for all non-hydrogen atoms. The hydrogen atoms were located from difference Fourier maps.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.