EtN=P(NMe2)N=P(NMe2)3: An efficient non-ionic base catalyst for the isomerization of allylic compounds and methylene-interrupted dienes

Arkivoc

Volumn 2004, Issue 9, 2004, Pages 88-95

  Wu, Wei ^a   Verkade, John G ^a  

^a IOWA STATE UNIVERSITY   (United States)

Author keywords

Allylic aromatics; Conjugation; Isomerization; Non ionic base; Phosphazene base

Indexed keywords

1,4 DIHYDRONAPHTHALENE; ACETONITRILE; ALKADIENE; ALLYL COMPOUND; ALLYLIMIDAZOLE; ALLYLPHENYLSULFIDE; BASE; BENZENE DERIVATIVE; CARBENE; ION; NAPHTHALENE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; ISOMERIZATION; METHODOLOGY;

EID: 5644255989     PISSN: 14246376     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (42)

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34. For phosphazene bases and examples of their applications, see: (a) Schwesinger, R.; Schlemper, H. Angew. Chem. 1987, 99, 1212. (b) Schwesinger, P.; Hasenfratz, C.; Schemper, H.; Walz, L.; Peters, E.M.; Peters, K.; Schnering, H.G. Angew. Chem. Int. Ed. Engl. 1993, 32, 1361. (c) Costa, A.; Najera, C.; Sansano, J. Synlett. 2001, 12, 1881. (d) Lash, T.; Werner, T.; Thompson, M.; Manley, J. J. Org. Chem. 2001, 66, 3152. (e) Baxendale, I.; Lee, A.; Ley, S. Synlett. 2001, 9, 1482. (f) Brain, C.; Brunton, S. Synlett., 2001, 3, 382. (g) Clark, A.; Yasair, S.; Patel, D.; Boradhurst, M. Tetrahedron Lett. 2001, 42, 2007. (h) Koppel, I. A.; Schwesinger, R.; Breuer, T.; Burk, P.; Herodes, K.; Koppel, I.; Leito, I.; Mishima, M. J. Phys. Chem. A, 2001 105, 9575.
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37. For phosphazene bases and examples of their applications, see: (a) Schwesinger, R.; Schlemper, H. Angew. Chem. 1987, 99, 1212. (b) Schwesinger, P.; Hasenfratz, C.; Schemper, H.; Walz, L.; Peters, E.M.; Peters, K.; Schnering, H.G. Angew. Chem. Int. Ed. Engl. 1993, 32, 1361. (c) Costa, A.; Najera, C.; Sansano, J. Synlett. 2001, 12, 1881. (d) Lash, T.; Werner, T.; Thompson, M.; Manley, J. J. Org. Chem. 2001, 66, 3152. (e) Baxendale, I.; Lee, A.; Ley, S. Synlett. 2001, 9, 1482. (f) Brain, C.; Brunton, S. Synlett., 2001, 3, 382. (g) Clark, A.; Yasair, S.; Patel, D.; Boradhurst, M. Tetrahedron Lett. 2001, 42, 2007. (h) Koppel, I. A.; Schwesinger, R.; Breuer, T.; Burk, P.; Herodes, K.; Koppel, I.; Leito, I.; Mishima, M. J. Phys. Chem. A, 2001 105, 9575.
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